Organic Layers Bonded to Industrial, Coinage, and Noble Metals through Electrochemical Reduction of Aryldiazonium Salts
- Marie-Claude Bernard
- ,
- Annie Chaussé
- ,
- Eva Cabet-Deliry
- ,
- Mohamed M. Chehimi
- ,
- Jean Pinson
- ,
- Fetah Podvorica
- , and
- Christine Vautrin-Ul
Abstract

The reduction of diazonium salts in an aprotic medium permits the attachment of substituted aryl groups to a variety of metals: Co, Ni, Cu, Zn, Pt, and Au. These aryl groups are strongly bonded to the metal as they resist sustained rinsing under sonication in organic solvents. The organic layers have been characterized by cyclic voltammetry, infrared reflection absorption spectroscopy, X-ray photoelectron spectroscopy, Rutherford backscattering, electrochemical impedance spectroscopy, and atomic force microscopy. From these data it is possible to propose a structure for these grafted layers.
‖
Unité Propre de Recherche CNRS 15.
§
Unité Mixte de Recherche Université d'Evry-CNRS-CEA 8587.
†
Unité Mixte de Recherche Université Paris 7-CNRS 7591.
‡
Unité Mixte de Recherche Université Paris 7-CNRS 7086.
*
To whom correspondence should be addressed.
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