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Photoinduced Topotactic Growth of Bismuth Nanoparticles from Bulk SrBi2Ta2O9

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† Laboratory of Eco-Materials and Sustainable Technology (LEMST), Xinjiang Technical Institute of Physics and Chemistry; Key Laboratory of Functional Materials and Devices for Special Environments, Chinese Academy of Sciences, Urumqi, Xinjiang 830011, China
‡ University of Chinese Academy of Sciences, Beijing 100049, P.R. China
§ Department of Materials Science and Engineering, The University of Utah, Salt Lake City, Utah 84108, United States
⊥ Key Laboratory of Photochemical Conversion and Optoelectronic Materials, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, China
*E-mail: [email protected] (Y.L.); [email protected] (C.W.).
Cite this: Chem. Mater. 2013, 25, 10, 2045–2050
Publication Date (Web):April 25, 2013
https://doi.org/10.1021/cm400065x
Copyright © 2013 American Chemical Society
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Abstract

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In situ growth of bismuth (Bi) nanoparticles on bulk SrBi2Ta2O9 (SBT) platelet is achieved by UV light illumination of SBT in aqueous glucose solutions. Interestingly, the as-produced Bi nanoparticles (NPs) are uniformly oriented with the epitaxial relationship of [001]Bi//[110]SBT, appearing as meso-single-crystal phase despite spatial separation between the NPs. Systematic investigations indicate that Bi(III) at the (110)SBT plane is topotactically reduced by photogenerated electrons, producing Bi atoms serving as nucleation seeds oriented from the (003) plane. Further growth of these oriented nuclei leads to formation of Bi NPs arranged laterally in mesocrystalline superstructure. The reported finding presents a simple, environmentally friendly approach toward preparation of highly organized, surface supported metal NPs through direct photoreduction of bulk metal oxides.

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Experimental details, UV–vis spectrum, additional TEM and SEM images, EDX spectrum, N2 adsorption–desorption isotherms and pore size distributions, and TG analysis. This material is available free of charge via the Internet at http://pubs.acs.org.

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