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A Bulk Boron-Based Photocatalyst for Efficient Dechlorination: K3B6O10Br

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† Laboratory of Environmental Sciences and Technology, Xinjiang Technical Institute of Physics & Chemistry, and Key Laboratory of Functional Materials and Devices for Special Environments, Chinese Academy of Sciences, Urumqi 830011, China
‡ Department of Materials Science and Engineering, University of Utah, 122 South Central Campus Drive, Salt Lake City, Utah 84112, United States
*E-mail: [email protected]
*E-mail: [email protected]
Cite this: Chem. Mater. 2014, 26, 10, 3169–3174
Publication Date (Web):April 30, 2014
https://doi.org/10.1021/cm500597e
Copyright © 2014 American Chemical Society
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Abstract

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Nanoparticles of a borate nonlinear optical material, K3B6O10Br (KBB), have been fabricated and demonstrated excellent catalytic activity in UV-induced dechlorination of chlorophenols, which are typical persistent organic pollutants. The obtained dechlorination efficiency is 2 orders of magnitude higher than that of a commercial P25 TiO2 catalyst under UV (λ > 254 nm) light irradiation. The noncentrosymmetric structure of KBB gives rise to an intrinsic large polarization effect as evidenced by Kelvin probe force microscopy, and the polarization promotes separation of photogenerated electron–hole pairs, leading to efficient cleavage of chlorophenols into small molecular fragments and dissociative Cl– anions. This work suggests that nonlinear materials open a new window for designing efficient photocatalysts.

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Hydroxyl radical measurement, ORTEP structures of B6O13 and KO6Br2, HPLC, and UV absorption spectrum of the 4-CP solutions from dechlorination and repeated degradation by KBB powders. This material is available free of charge via the Internet at http://pubs.acs.org.

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