ACS Publications. Most Trusted. Most Cited. Most Read
My Activity
CONTENT TYPES

Shape Control in Iron Oxide Nanocrystal Synthesis, Induced by Trioctylammonium Ions

View Author Information
Departamento de Química Física and Unidad Asociada CSIC, Universidade de Vigo, 36310 Vigo, Spain, and Fachbereich Physik and Center for Nanointegration (CeNIDE), Universität Duisburg-Essen, Lotharstrasse 1, 47048, Duisburg, Germany
* Fax: (+34)986812556. E-mail: [email protected] (A.S.); [email protected] (L.M.L.-M.).
†Universidade de Vigo.
‡Universität Duisburg-Essen.
Cite this: Chem. Mater. 2009, 21, 7, 1326–1332
Publication Date (Web):March 6, 2009
https://doi.org/10.1021/cm803201p
Copyright © 2009 American Chemical Society

    Article Views

    3124

    Altmetric

    -

    Citations

    LEARN ABOUT THESE METRICS
    Read OnlinePDF (1 MB)
    Supporting Info (1)»

    Abstract

    Abstract Image

    Faceted iron oxide nanoparticles with octahedral shape were synthesized through controlled modification of the iron oleate decomposition method. The key to this novel shape control is the “in situ” formation of trioctylammonium bromide (TOAHB) during the process, through decomposition of quaternary ammonium salts. This hypothesis was confirmed by carrying out the synthesis in the presence of preformed TOAHB, which again resulted in the formation of iron oxide octahedra. A detailed high-resolution transmission electron microscopy (HRTEM) analysis of the nanooctahedra was performed for shape analysis and structural characterization. X-ray photoelectron spectroscopy (XPS) indicates the presence of both metallic iron and iron oxide within the nanooctahedra. The results obtained by HRTEM and XPS are in agreement with magnetic analysis, which revealed the presence of several magnetic phases in the samples.

    Supporting Information

    ARTICLE SECTIONS
    Jump To

    Additional figures (PDF). This material is available free of charge via the Internet at http://pubs.acs.org.

    Terms & Conditions

    Most electronic Supporting Information files are available without a subscription to ACS Web Editions. Such files may be downloaded by article for research use (if there is a public use license linked to the relevant article, that license may permit other uses). Permission may be obtained from ACS for other uses through requests via the RightsLink permission system: http://pubs.acs.org/page/copyright/permissions.html.

    Cited By

    This article is cited by 71 publications.

    1. Rajpreet Kaur, Gurinder Kaur Ahluwalia, Mandeep Singh Bakshi. Lignin-Induced Click Synthesis of Au, Ag, Pd, and Iron Oxide Nanoparticles and Their Nanocomposites in Aqueous Bulk and at the Solid–Liquid Interface. ACS Sustainable Chemistry & Engineering 2023, 11 (32) , 11819-11833. https://doi.org/10.1021/acssuschemeng.3c01471
    2. Yaser Hadadian, Hajar Masoomi, Ali Dinari, Chiseon Ryu, Seong Hwang, Seokjae Kim, Beong ki Cho, Jae Young Lee, Jungwon Yoon. From Low to High Saturation Magnetization in Magnetite Nanoparticles: The Crucial Role of the Molar Ratios Between the Chemicals. ACS Omega 2022, 7 (18) , 15996-16012. https://doi.org/10.1021/acsomega.2c01136
    3. L. Kenyon Plummer, James E. Hutchison. Understanding the Effects of Iron Precursor Ligation and Oxidation State Leads to Improved Synthetic Control for Spinel Iron Oxide Nanocrystals. Inorganic Chemistry 2020, 59 (20) , 15074-15087. https://doi.org/10.1021/acs.inorgchem.0c02040
    4. Rajpreet Kaur, Mandeep Singh Bakshi. Mechanistic Aspects of Simultaneous Extraction of Silver and Gold Nanoparticles across Aqueous–Organic Interfaces by Surface Active Iron Oxide Nanoparticles. Langmuir 2020, 36 (26) , 7505-7516. https://doi.org/10.1021/acs.langmuir.0c01102
    5. Junfeng Liu, Michaela Meyns, Ting Zhang, Jordi Arbiol, Andreu Cabot, Alexey Shavel. Triphenyl Phosphite as the Phosphorus Source for the Scalable and Cost-Effective Production of Transition Metal Phosphides. Chemistry of Materials 2018, 30 (5) , 1799-1807. https://doi.org/10.1021/acs.chemmater.8b00290
    6. Bharati Debnath, Hemant G. Salunke, Sonnada M. Shivaprasad, and Sayan Bhattacharyya . Surfactant-Mediated Resistance to Surface Oxidation in MnO Nanostructures. ACS Omega 2017, 2 (6) , 3028-3035. https://doi.org/10.1021/acsomega.7b00622
    7. Sham Rampersaud, Justin Fang, Zengyan Wei, Kristina Fabijanic, Stefan Silver, Trisha Jaikaran, Yuleisy Ruiz, Murielle Houssou, Zhiwei Yin, Shengping Zheng, Ayako Hashimoto, Ayuko Hoshino, David Lyden, Shahana Mahajan, and Hiroshi Matsui . The Effect of Cage Shape on Nanoparticle-Based Drug Carriers: Anticancer Drug Release and Efficacy via Receptor Blockade Using Dextran-Coated Iron Oxide Nanocages. Nano Letters 2016, 16 (12) , 7357-7363. https://doi.org/10.1021/acs.nanolett.6b02577
    8. Lenaic Lartigue, Claudia Innocenti, Thangavel Kalaivani, Azzam Awwad, Maria del Mar Sanchez Duque, Yannick Guari, Joulia Larionova, Christian Guérin, Jean-Louis Georges Montero, Véronique Barragan-Montero, Paolo Arosio, Alessandro Lascialfari, Dante Gatteschi, and Claudio Sangregorio . Water-Dispersible Sugar-Coated Iron Oxide Nanoparticles. An Evaluation of their Relaxometric and Magnetic Hyperthermia Properties. Journal of the American Chemical Society 2011, 133 (27) , 10459-10472. https://doi.org/10.1021/ja111448t
    9. Stefan Franzen and Donovan N. Leonard . Analysis of RNA-Mediated Materials Synthesis Using Magnetic Selection. The Journal of Physical Chemistry C 2011, 115 (19) , 9335-9343. https://doi.org/10.1021/jp108689v
    10. Fang-hsin Lin and Ruey-an Doong . Bifunctional Au−Fe3O4 Heterostructures for Magnetically Recyclable Catalysis of Nitrophenol Reduction. The Journal of Physical Chemistry C 2011, 115 (14) , 6591-6598. https://doi.org/10.1021/jp110956k
    11. Soubantika Palchoudhury, Wei An, Yaolin Xu, Ying Qin, Zhongtao Zhang, Nitin Chopra, Robert A. Holler, C. Heath Turner, and Yuping Bao . Synthesis and Growth Mechanism of Iron Oxide Nanowhiskers. Nano Letters 2011, 11 (3) , 1141-1146. https://doi.org/10.1021/nl200136j
    12. Guoliang Zhen, Benjamin W. Muir, Bradford A. Moffat, Peter Harbour, Keith S. Murray, Boujemaa Moubaraki, Kiyonori Suzuki, Ian Madsen, Nicki Agron-Olshina, Lynne Waddington, Paul Mulvaney, and Patrick G. Hartley . Comparative Study of the Magnetic Behavior of Spherical and Cubic Superparamagnetic Iron Oxide Nanoparticles. The Journal of Physical Chemistry C 2011, 115 (2) , 327-334. https://doi.org/10.1021/jp104953z
    13. Gyu Leem, Shishan Zhang, Andrew C. Jamison, Eduard Galstyan, Irene Rusakova, Bernd Lorenz, Dmitri Litvinov, and T. Randall Lee . Light-Induced Covalent Immobilization of Monolayers of Magnetic Nanoparticles on Hydrogen-Terminated Silicon. ACS Applied Materials & Interfaces 2010, 2 (10) , 2789-2796. https://doi.org/10.1021/am100457v
    14. Chi-Yen Lin, Andres Garcia, Peter Zalar, Jacek Z. Brzezinski, and Thuc-Quyen Nguyen . Effect of Thermal Annealing on Polymer Light-Emitting Diodes Utilizing Cationic Conjugated Polyelectrolytes as Electron Injection Layers. The Journal of Physical Chemistry C 2010, 114 (37) , 15786-15790. https://doi.org/10.1021/jp103184z
    15. Xuzhen Wang, Zongbin Zhao, Jiangying Qu, Zhiyu Wang and Jieshan Qiu. Shape-Control and Characterization of Magnetite Prepared via a One-Step Solvothermal Route. Crystal Growth & Design 2010, 10 (7) , 2863-2869. https://doi.org/10.1021/cg900472d
    16. Ling Li, Yang Yang, Jun Ding and Junmin Xue. Synthesis of Magnetite Nanooctahedra and Their Magnetic Field-Induced Two-/Three-Dimensional Superstructure. Chemistry of Materials 2010, 22 (10) , 3183-3191. https://doi.org/10.1021/cm100289d
    17. Xiaolong Zhao, Yizhong Zhao, Zenglin Wang, Bin Chen, Shenwen Fang, Peng Li, Gang Chen, Xiaqing Li, Wei Liang, XueFeng Gao, QingCai Wei. Insight into the influence of morphology and structure of Fe 3 O 4 nanoparticles on demulsification efficiencies. Journal of Dispersion Science and Technology 2023, 44 (9) , 1562-1573. https://doi.org/10.1080/01932691.2022.2025822
    18. Sherif Okeil, Julian Ungerer, Hermann Nirschl, Georg Garnweitner. Synthesis of Anisotropic Metal Oxide Nanoparticles via Non‑Aqueous and Non-Hydrolytic Routes. KONA Powder and Particle Journal 2023, 2011 https://doi.org/10.14356/kona.2024014
    19. Juan Chang, Erbing Wang, Trey Oldham, Wenlu Li, John Fortner. Tuning Iron Oxide-based Nanomaterials as Next Generation Adsorbents for Environmental Applications. 2021, 117-152. https://doi.org/10.1039/9781839165092-00117
    20. Helena Gavilán, Sahitya Kumar Avugadda, Tamara Fernández-Cabada, Nisarg Soni, Marco Cassani, Binh T. Mai, Roy Chantrell, Teresa Pellegrino. Magnetic nanoparticles and clusters for magnetic hyperthermia: optimizing their heat performance and developing combinatorial therapies to tackle cancer. Chemical Society Reviews 2021, 50 (20) , 11614-11667. https://doi.org/10.1039/D1CS00427A
    21. Geoffrey Cotin, Cristina Blanco-Andujar, Francis Perton, Laura Asín, Jesus M. de la Fuente, Wilfried Reichardt, Denise Schaffner, Dinh-Vu Ngyen, Damien Mertz, Céline Kiefer, Florent Meyer, Simo Spassov, Ovidiu Ersen, Michael Chatzidakis, Gianluigi A. Botton, Céline Hénoumont, Sophie Laurent, Jean-Marc Greneche, Francisco J. Teran, Daniel Ortega, Delphine Felder-Flesch, Sylvie Begin-Colin. Unveiling the role of surface, size, shape and defects of iron oxide nanoparticles for theranostic applications. Nanoscale 2021, 13 (34) , 14552-14571. https://doi.org/10.1039/D1NR03335B
    22. Birgitte H. McDonagh, Christoph Staudinger, Peter S. Normile, Jose A. De Toro, Sulalit Bandyopadhyay, Wilhelm R. Glomm, Gurvinder Singh. New insights into controlling the twin structure of magnetic iron oxide nanoparticles. Applied Materials Today 2021, 24 , 101084. https://doi.org/10.1016/j.apmt.2021.101084
    23. Lucía Gutiérrez, María del Puerto Morales, Alejandro G. Roca. Synthesis and Applications of Anisotropic Magnetic Iron Oxide Nanoparticles. 2021, 65-89. https://doi.org/10.1007/978-3-030-74073-3_3
    24. N Jović Orsini, M M Milić, T E Torres. Zn- and (Mn, Zn)-substituted versus unsubstituted magnetite nanoparticles: structural, magnetic and hyperthermic properties. Nanotechnology 2020, 31 (22) , 225707. https://doi.org/10.1088/1361-6528/ab76e7
    25. Elvira Fantechi, Alessandro Ponti, Anna M. Ferretti. Synthesis and design of ferro- and ferrimagnetic NPs. 2020, 333-379. https://doi.org/10.1016/B978-0-12-816865-3.00012-3
    26. Mohamed I. Said, Mervat Ibrahim. Controlled synthesis of iron oxide NPs derived from conventionally and ultrasonically prepared iron(III) coordination polymer: Potential remediation and catalytic degradation of methylene blue. Materials Chemistry and Physics 2019, 233 , 329-338. https://doi.org/10.1016/j.matchemphys.2019.05.044
    27. Mackenzie Ann Hemauer, Sojeong Lee, Mandeep Singh Bakshi. Nanorod morphology control of iron oxide nanoparticles induced by ionic surfactants and their solid – liquid interfacial adsorption. Journal of Crystal Growth 2019, 508 , 34-41. https://doi.org/10.1016/j.jcrysgro.2018.12.013
    28. David A. Brewster, Dominick J. Sarappa, Kathryn E. Knowles. Role of aliphatic ligands and solvent composition in the solvothermal synthesis of iron oxide nanocrystals. Polyhedron 2019, 157 , 54-62. https://doi.org/10.1016/j.poly.2018.09.063
    29. Do Kyung Kim, Jae Won Lee. Synthesis of Non-hydrate Iron Oleate for Eco-friendly Production of Monodispersed Iron Oxide Nanoparticles. Journal of the Korean Ceramic Society 2018, 55 (6) , 625-634. https://doi.org/10.4191/kcers.2018.55.6.07
    30. Aidin Lak, Marco Cassani, Binh T. Mai, Naomi Winckelmans, David Cabrera, Elaheh Sadrollahi, Sergio Marras, Hilke Remmer, Sergio Fiorito, Lucia Cremades-Jimeno, Fred Jochen Litterst, Frank Ludwig, Liberato Manna, Francisco J. Teran, Sara Bals, Teresa Pellegrino. Fe 2+ Deficiencies, FeO Subdomains, and Structural Defects Favor Magnetic Hyperthermia Performance of Iron Oxide Nanocubes into Intracellular Environment. Nano Letters 2018, 18 (11) , 6856-6866. https://doi.org/10.1021/acs.nanolett.8b02722
    31. A. A. Nikitin, M. A. Khramtsov, A. G. Savchenko, M. A. Abakumov, A. G. Mazhuga. Anisotropic Iron-Oxide Nanoparticles for Diagnostic MRI: Synthesis and Contrast Properties. Pharmaceutical Chemistry Journal 2018, 52 (3) , 231-235. https://doi.org/10.1007/s11094-018-1796-3
    32. Qianqian Dou, Ka Wai Wong, Yang Li, Ka Ming Ng. Novel nanosheets of ferrite nanoparticle arrays in carbon matrix from single source precursors: an anode material for lithium-ion batteries. Journal of Materials Science 2018, 53 (6) , 4456-4466. https://doi.org/10.1007/s10853-017-1848-1
    33. Igor E. Uflyand, Gulzhian I. Dzhardimalieva. Thermolysis of Low Molecular Weight Metal Chelates. 2018, 71-245. https://doi.org/10.1007/978-3-319-93405-1_3
    34. Yuxue Wei, Chenghua Zhang, Qiang Chang, Xianzhou Wang, Liwei Niu, Jian Xu, Yong Yang, Yongwang Li. Synthesis of monodisperse iron oxide nanoparticles: Effect of temperature, time, solvent, and surfactant. Inorganic and Nano-Metal Chemistry 2017, 47 (10) , 1375-1379. https://doi.org/10.1080/24701556.2017.1284124
    35. Yan Lu, Eileen Fong. Botanic chemistry enabled synthesis of 3D hollow metal oxides/carbon hybrids for ultra-high performance metal-ion batteries. Materials Today Energy 2017, 4 , 89-96. https://doi.org/10.1016/j.mtener.2017.04.001
    36. Fernando B Effenberger, Ricardo A Couto, Pedro K Kiyohara, Giovanna Machado, Sueli H Masunaga, Renato F Jardim, Liane M Rossi. Economically attractive route for the preparation of high quality magnetic nanoparticles by the thermal decomposition of iron(III) acetylacetonate. Nanotechnology 2017, 28 (11) , 115603. https://doi.org/10.1088/1361-6528/aa5ab0
    37. Zheheng Xu, Zengyan Wei, Peigang He, Xiaoming Duan, Zhihua Yang, Yu Zhou, Dechang Jia. Seed-mediated growth of ultra-thin triangular magnetite nanoplates. Chem. Commun. 2017, 53 (80) , 11052-11055. https://doi.org/10.1039/C7CC05723G
    38. P. Guardia, S. Nitti, M. E. Materia, G. Pugliese, N. Yaacoub, J.-M. Greneche, C. Lefevre, L. Manna, T. Pellegrino. Gold–iron oxide dimers for magnetic hyperthermia: the key role of chloride ions in the synthesis to boost the heating efficiency. Journal of Materials Chemistry B 2017, 5 (24) , 4587-4594. https://doi.org/10.1039/C7TB00968B
    39. Wenlu Li, Seung Soo Lee, Jiewei Wu, Carl H Hinton, John D Fortner. Shape and size controlled synthesis of uniform iron oxide nanocrystals through new non-hydrolytic routes. Nanotechnology 2016, 27 (32) , 324002. https://doi.org/10.1088/0957-4484/27/32/324002
    40. Shaobo Huang, Wangxi Zhang, Shizhong Cui, Wutao Wei, Weihua Chen, Liwei Mi. Large-scale Uniform 3D composite Fe 3 O 4 @CF for High-performance Supercapacitors Design. ChemistrySelect 2016, 1 (11) , 2909-2915. https://doi.org/10.1002/slct.201600480
    41. Alberto Pardo, Rosa Pujales, Mateo Blanco, Eva M. Villar-Alvarez, Silvia Barbosa, Pablo Taboada, Víctor Mosquera. Analysis of the influence of synthetic paramaters on the structure and physico-chemical properties of non-spherical iron oxide nanocrystals and their biological stability and compatibility. Dalton Transactions 2016, 45 (2) , 797-810. https://doi.org/10.1039/C5DT03923A
    42. Antonino Rizzuti, Michele Dassisti, Piero Mastrorilli, Maria C. Sportelli, Nicola Cioffi, Rosaria A. Picca, Elisabetta Agostinelli, Gaspare Varvaro, Rocco Caliandro. Shape-control by microwave-assisted hydrothermal method for the synthesis of magnetite nanoparticles using organic additives. Journal of Nanoparticle Research 2015, 17 (10) https://doi.org/10.1007/s11051-015-3213-0
    43. Zhigang Jia, Jianhong Liu, Qiuze Wang, Shengbiao Li, Qin Qi, Rongsun Zhu. Synthesis of 3D hierarchical porous iron oxides for adsorption of Congo red from dye wastewater. Journal of Alloys and Compounds 2015, 622 , 587-595. https://doi.org/10.1016/j.jallcom.2014.10.125
    44. Guixin Yang, Fei He, Ruichan Lv, Shili Gai, Ziyong Cheng, Yunlu Dai, Piaoping Yang. A cheap and facile route to synthesize monodisperse magnetic nanocrystals and their application as MRI agents. Dalton Transactions 2015, 44 (1) , 247-253. https://doi.org/10.1039/C4DT02425G
    45. Matthew Worden, Michael A. Bruckman, Min-Ho Kim, Nicole F. Steinmetz, James M. Kikkawa, Catherine LaSpina, Torsten Hegmann. Aqueous synthesis of polyhedral “brick-like” iron oxide nanoparticles for hyperthermia and T 2 MRI contrast enhancement. Journal of Materials Chemistry B 2015, 3 (34) , 6877-6884. https://doi.org/10.1039/C5TB01138H
    46. Pablo Guardia, Andreas Riedinger, Hamilton Kakwere, Florence Gazeau, Teresa Pellegrino. Magnetic Nanoparticles for Magnetic Hyperthermia and Controlled Drug Delivery. 2014, 139-172. https://doi.org/10.1002/9783527675821.ch06
    47. K. Mandel, C. Kolb, M. Straßer, S. Dembski, G. Sextl. Size controlled iron oxide nano octahedra obtained via sonochemistry and natural ageing. Colloids and Surfaces A: Physicochemical and Engineering Aspects 2014, 457 , 27-32. https://doi.org/10.1016/j.colsurfa.2014.05.046
    48. Xiangui Ding, Liu Bao, Jiang Jiang, Hongwei Gu. Colloidal synthesis of ultrathin γ-Fe2O3 nanoplates. RSC Advances 2014, 4 (18) , 9314. https://doi.org/10.1039/c3ra46728g
    49. Guo‐Rong Xu, Jiao‐Na Wang, Cong‐Ju Li. A New Strategy for the Synthesis of Iron‐Oxide Nanocrystals by Using a Single‐Spinneret Electrospinning Technique. Chemistry – An Asian Journal 2013, 8 (10) , 2453-2458. https://doi.org/10.1002/asia.201300508
    50. Chih-Jung Chen, Ray-Kuang Chiang, Jiun-Sheng Wang, Sue-Lein Wang. Synthesis and magnetic properties of octahedral magnetite nanoparticles in 20–110 nm range. Journal of Nanoparticle Research 2013, 15 (8) https://doi.org/10.1007/s11051-013-1845-5
    51. Geetu Sharma, Pethaiyan Jeevanandam. Synthesis of self-assembled prismatic iron oxide nanoparticles by a novel thermal decomposition route. RSC Adv. 2013, 3 (1) , 189-200. https://doi.org/10.1039/C2RA22004K
    52. Buhe Bateer, Chungui Tian, Yang Qu, Shichao Du, Taixing Tan, Ruihong Wang, Guohui Tian, Honggang Fu. Facile synthesis and shape control of Fe3O4 nanocrystals with good dispersion and stabilization. CrystEngComm 2013, 15 (17) , 3366. https://doi.org/10.1039/c3ce40123e
    53. Hafsa Khurshid, Wanfeng Li, Sayan Chandra, Manh-Huong Phan, George C. Hadjipanayis, Pritish Mukherjee, Hariharan Srikanth. Mechanism and controlled growth of shape and size variant core/shell FeO/Fe3O4 nanoparticles. Nanoscale 2013, 5 (17) , 7942. https://doi.org/10.1039/c3nr02596a
    54. Peter Zalar, Thuc‐Quyen Nguyen. Charge Injection Mechanism in PLEDs and Charge Transport in Conjugated Polyelectrolytes. 2012, 315-344. https://doi.org/10.1002/9783527655700.ch10
    55. H. Maleki, A. Simchi, M. Imani, B.F.O. Costa. Size-controlled synthesis of superparamagnetic iron oxide nanoparticles and their surface coating by gold for biomedical applications. Journal of Magnetism and Magnetic Materials 2012, 324 (23) , 3997-4005. https://doi.org/10.1016/j.jmmm.2012.06.045
    56. . Nanostructures Classified as Polyhedra. 2012, 431-475. https://doi.org/10.1201/b11801-14
    57. Hyunjoo Lee, Cheonghee Kim, Sungeun Yang, Joung Woo Han, Jiyeon Kim. Shape-Controlled Nanocrystals for Catalytic Applications. Catalysis Surveys from Asia 2012, 16 (1) , 14-27. https://doi.org/10.1007/s10563-011-9130-z
    58. Soubantika Palchoudhury, Yaolin Xu, Amanda Rushdi, Robert A. Holler, Yuping Bao. Controlled synthesis of iron oxide nanoplates and nanoflowers. Chemical Communications 2012, 48 (85) , 10499. https://doi.org/10.1039/c2cc35945f
    59. C. N. R. Rao, H. S. S. Ramakrishna Matte, Rakesh Voggu, A. Govindaraj. Recent progress in the synthesis of inorganic nanoparticles. Dalton Transactions 2012, 41 (17) , 5089. https://doi.org/10.1039/c2dt12266a
    60. Liu Bao, Wai-Leong Low, Jiang Jiang, Jackie Y. Ying. Colloidal synthesis of magnetic nanorods with tunable aspect ratios. Journal of Materials Chemistry 2012, 22 (15) , 7117. https://doi.org/10.1039/c2jm16401a
    61. Gorka Salas, Cintia Casado, Francisco J. Teran, Rodolfo Miranda, Carlos J. Serna, M. Puerto Morales. Controlled synthesis of uniform magnetite nanocrystals with high-quality properties for biomedical applications. Journal of Materials Chemistry 2012, 22 (39) , 21065. https://doi.org/10.1039/c2jm34402e
    62. Fang-hsin Lin, Wei Chen, Yu-Hsiang Liao, Reuy-an Doong, Yadong Li. Effective approach for the synthesis of monodisperse magnetic nanocrystals and M-Fe3O4 (M = Ag, Au, Pt, Pd) heterostructures. Nano Research 2011, 4 (12) , 1223-1232. https://doi.org/10.1007/s12274-011-0173-2
    63. Caixia Song, Yang Zhang, Yusheng Lin, Debao Wang. Preparation and magnetic property of Fe2O3 parallelepiped nanocrystals. Materials Letters 2011, 65 (21-22) , 3195-3198. https://doi.org/10.1016/j.matlet.2011.06.115
    64. Matthew B. Boucher, Simone Goergen, Nan Yi, Maria Flytzani-Stephanopoulos. ‘Shape effects’ in metal oxide supported nanoscale gold catalysts. Physical Chemistry Chemical Physics 2011, 13 (7) , 2517. https://doi.org/10.1039/c0cp02009e
    65. Petra Krystek, Andrea Ulrich, Carmen Cecilia Garcia, Srirang Manohar, Rob Ritsema. Application of plasma spectrometry for the analysis of engineered nanoparticles in suspensions and products. Journal of Analytical Atomic Spectrometry 2011, 26 (9) , 1701. https://doi.org/10.1039/c1ja10071h
    66. Goutam Sheet, Alexandra R. Cunliffe, Erik J. Offerman, Chad M. Folkman, Chang-Beom Eom, Venkat Chandrasekhar. dc and high frequency magnetic properties of nanopatterned CoFe2O4 arrays fabricated using sol-gel precursors. Journal of Applied Physics 2010, 107 (10) https://doi.org/10.1063/1.3393745
    67. Yunfeng Shi, Linzhu Zhou, Ruibin Wang, Yan Pang, Wangchuan Xiao, Huiqin Li, Yue Su, Xiaoliang Wang, Bangshang Zhu, Xinyuan Zhu, Deyue Yan, Hongchen Gu. In situ preparation of magnetic nonviral gene vectors and magnetofection in vitro. Nanotechnology 2010, 21 (11) , 115103. https://doi.org/10.1088/0957-4484/21/11/115103
    68. Anatolii D. Pomogailo, Vladimir N. Kestelman, Gulzhian I. Dzhardimalieva. Monomeric and Polymeric Metal Carboxylates as Precursors of Nanocomposite Materials. 2010, 257-288. https://doi.org/10.1007/978-3-642-10574-6_9
    69. Maryna I. Bodnarchuk, Maksym V. Kovalenko, Heiko Groiss, Roland Resel, Michael Reissner, Günter Hesser, Rainer T. Lechner, Walter Steiner, Friedrich Schäffler, Wolfgang Heiss. Exchange-Coupled Bimagnetic Wüstite/Metal Ferrite Core/Shell Nanocrystals: Size, Shape, and Compositional Control. Small 2009, 5 (20) , 2247-2252. https://doi.org/10.1002/smll.200900635
    70. Fahui Song, Jianguo Guan, Xian Fan, Gongqin Yan. Single-crystal star-like arrayed particles of hematite: Synthesis, formation mechanism and magnetic properties. Journal of Alloys and Compounds 2009, 485 (1-2) , 753-758. https://doi.org/10.1016/j.jallcom.2009.06.075
    71. Alexey Shavel, Luis M. Liz-Marzán. Shape control of iron oxide nanoparticles. Physical Chemistry Chemical Physics 2009, 11 (19) , 3762. https://doi.org/10.1039/b822733k

    Pair your accounts.

    Export articles to Mendeley

    Get article recommendations from ACS based on references in your Mendeley library.

    Pair your accounts.

    Export articles to Mendeley

    Get article recommendations from ACS based on references in your Mendeley library.

    You’ve supercharged your research process with ACS and Mendeley!

    STEP 1:
    Click to create an ACS ID

    Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

    Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

    Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

    MENDELEY PAIRING EXPIRED
    Your Mendeley pairing has expired. Please reconnect