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Enhancement in Aerobic Alcohol Oxidation Catalysis of Au25 Clusters by Single Pd Atom Doping

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Catalysis Research Center, Hokkaido University, Nishi10, Kita21, Sapporo 001-0021, Japan,
Department of Applied Chemistry, Faculty of Science, Tokyo University of Science, 1-3 Kagurazaka, Shinjuku-ku, Tokyo 162-8601, Japan,
§ Department of Chemistry, School of Science, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-0033, Japan.
Cite this: ACS Catal. 2012, 2, 7, 1519–1523
Publication Date (Web):June 15, 2012
https://doi.org/10.1021/cs300252g
Copyright © 2012 American Chemical Society

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    Abstract

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    Au25 and Pd1Au24 clusters on multiwalled carbon nanotubes were developed via adsorption of Au25(SC12H25)18 and Pd1Au24(SC12H25)18, respectively, on the nanotubes, followed by calcination. Comparison of their catalysis for the aerobic oxidation of benzyl alcohol showed that single Pd atom doping significantly improved the catalytic performance of Au25 for the first time.

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