ACS Publications. Most Trusted. Most Cited. Most Read
My Activity

Enhancement in Aerobic Alcohol Oxidation Catalysis of Au25 Clusters by Single Pd Atom Doping

View Author Information
Catalysis Research Center, Hokkaido University, Nishi10, Kita21, Sapporo 001-0021, Japan,
Department of Applied Chemistry, Faculty of Science, Tokyo University of Science, 1-3 Kagurazaka, Shinjuku-ku, Tokyo 162-8601, Japan,
§ Department of Chemistry, School of Science, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-0033, Japan.
Cite this: ACS Catal. 2012, 2, 7, 1519–1523
Publication Date (Web):June 15, 2012
Copyright © 2012 American Chemical Society

    Article Views





    Other access options
    Supporting Info (1)»


    Abstract Image

    Au25 and Pd1Au24 clusters on multiwalled carbon nanotubes were developed via adsorption of Au25(SC12H25)18 and Pd1Au24(SC12H25)18, respectively, on the nanotubes, followed by calcination. Comparison of their catalysis for the aerobic oxidation of benzyl alcohol showed that single Pd atom doping significantly improved the catalytic performance of Au25 for the first time.

    Read this article

    To access this article, please review the available access options below.

    Get instant access

    Purchase Access

    Read this article for 48 hours. Check out below using your ACS ID or as a guest.


    Access through Your Institution

    You may have access to this article through your institution.

    Your institution does not have access to this content. You can change your affiliated institution below.

    Supporting Information

    Jump To

    Details of experimental procedures and characterization results. This material is available free of charge via the Internet at

    Terms & Conditions

    Most electronic Supporting Information files are available without a subscription to ACS Web Editions. Such files may be downloaded by article for research use (if there is a public use license linked to the relevant article, that license may permit other uses). Permission may be obtained from ACS for other uses through requests via the RightsLink permission system:

    Cited By

    This article is cited by 354 publications.

    1. Teera Butburee, Jitprabhat Ponchai, Pongtanawat Khemthong, Poobodin Mano, Pongkarn Chakthranont, Saran Youngjan, Jakkapop Phanthasri, Supawadee Namuangruk, Kajornsak Faungnawakij, Xingya Wang, Yu Chen, Lijuan Zhang. General Pyrolysis for High-Loading Transition Metal Single Atoms on 2D-Nitro-Oxygeneous Carbon as Efficient ORR Electrocatalysts. ACS Applied Materials & Interfaces 2024, 16 (8) , 10227-10237.
    2. Xianwei Wang, Jiangtao Zhao, Henrik Eliasson, Rolf Erni, Abolfazl Ziarati, Siobhan Mckeown Walker, Thomas Bürgi. Very Low Temperature CO Oxidation over Atomically Precise Au25 Nanoclusters on MnO2. Journal of the American Chemical Society 2023, 145 (50) , 27273-27281.
    3. Shinya Masuda, Tatsuya Tsukuda. Partially Thiolated Aun (n = 25, 102) Clusters on Layered Double Hydroxides Anchored by Electrostatic Interactions: Size Effect on 5-Hydroxymethylfurfural Oxidation Catalysis. ACS Catalysis 2023, 13 (24) , 16179-16187.
    4. Qiang Yuan, Shuangshuang Huang, Hongqiao Lin, Govindarajan Saranya, Weigang Hu, Guangjun Li, Xiao Cai, Xu Liu, Mingyang Chen, Weiping Ding, Yan Zhu. Atomically Precise AgCu Clusters Affixed to SiO2 Aerogel for N-Formylation of Amines. ACS Catalysis 2023, 13 (24) , 16188-16194.
    5. Tongxin Song, Zhen Yao, Guangjun Li, Xiao Cai, Xu Liu, Yang-Gang Wang, Weiping Ding, Yan Zhu. Catalytic Activity Coupled with Structural Stability within a Heterodimeric Au29(SR)19 Cluster. ACS Catalysis 2023, 13 (16) , 10878-10886.
    6. Xu Liu, Xiao Cai, Yan Zhu. Catalysis Synergism by Atomically Precise Bimetallic Nanoclusters Doped with Heteroatoms. Accounts of Chemical Research 2023, 56 (12) , 1528-1538.
    7. Siqiang Xiao, Caiyun Wei, Rui Li, Yueming Qiu, Kok Bing Tan, Yichen Zhang, Jiale Huang, Qingbiao Li. Supported AgCuCl Nanoclusters as Bimetal Catalysts for Propylene Epoxidation with Molecular Oxygen. ACS Applied Nano Materials 2023, 6 (11) , 9687-9696.
    8. Stefan Knoppe, Alvaro Muñoz-Castro. Intermediate Silver Doping of Au25(SR)18: Variation of Electronic, Optical, and Chiroptical Properties along Au25–xAgx(SH)18– (x = 0–12) Stoichiometry from DFT Calculations. Inorganic Chemistry 2023, 62 (18) , 7079-7086.
    9. Yingwei Li, Hong Ki Kim, Ryan D. McGillicuddy, Shao-Liang Zheng, Kevin J. Anderton, Grant J. Stec, Jaehyeong Lee, Dongtao Cui, Jarad A. Mason. A Double Open-Shelled Au43 Nanocluster with Increased Catalytic Activity and Stability. Journal of the American Chemical Society 2023, 145 (16) , 9304-9312.
    10. Abhiroop Mishra, Junyoung Kim, Michelle Zorigt, Adolfo I.B. Romo, Raghuram Gaddam, James E. Braun, Davide Ziviani, Joaquín Rodríguez-López. Highly Selective TEMPO Catalyzed Bulk Electrooxidation of Isopropanol to Acetone for Application in Electrochemical Heat Pumping. ACS Sustainable Chemistry & Engineering 2023, 11 (16) , 6241-6249.
    11. Kosuke Sakamoto, Shinya Masuda, Shinjiro Takano, Tatsuya Tsukuda. Partially Thiolated Au25 Cluster Anchored on Carbon Support via Noncovalent Ligand–Support Interactions: Active and Robust Catalyst for Aerobic Oxidation of Alcohols. ACS Catalysis 2023, 13 (5) , 3263-3271.
    12. Jun Zha, Xiangfu Meng, Wentao Fan, Qing You, Nan Xia, Wanmiao Gu, Yan Zhao, Lin Hu, Jin Li, Haiteng Deng, Hui Wang, Nan Yan, Zhikun Wu. Surface Site-Specific Replacement for Catalysis Selectivity Switching. ACS Applied Materials & Interfaces 2023, 15 (3) , 3985-3992.
    13. Gao Wu, Qiao-Ling Mo, Yang Xiao, Kun Wang, Xing-Zu Ge, Shu-Ran Xu, Jia-Le Li, Yan-Qun Shao, Fang-Xing Xiao. Alloy Metal Nanocluster: A Robust and Stable Photosensitizer for Steering Solar Water Oxidation. Inorganic Chemistry 2023, 62 (1) , 520-529.
    14. Hussein Fakhouri, Estelle Salmon, Xiao Wei, Stéphane Joly, Christophe Moulin, Isabelle Russier-Antoine, Pierre-François Brevet, Xi Kang, Manzhou Zhu, Rodolphe Antoine. Effects of Single Platinum Atom Doping on Stability and Nonlinear Optical Properties of Ag29 Nanoclusters. The Journal of Physical Chemistry C 2022, 126 (49) , 21094-21100.
    15. He Wang, Xiyuan Liu, Weijie Yang, Guangyang Mao, Zheng Meng, Zhikun Wu, Hai-Long Jiang. Surface-Clean Au25 Nanoclusters in Modulated Microenvironment Enabled by Metal–Organic Frameworks for Enhanced Catalysis. Journal of the American Chemical Society 2022, 144 (48) , 22008-22017.
    16. Haiming Gao, Zhaojian Qin, Yihan Wang, Hongjie Xiong, Xuemei Wang, Hui Jiang. Hydrophilic Cyclodextrin Derivative Directed Lateral Recombination of 1-D Dipeptide Protected Gold Nanoclusters Assembly for Lysosomal Localization. ACS Materials Letters 2022, 4 (11) , 2244-2251.
    17. Shingo Hasegawa, Shinya Masuda, Shinjiro Takano, Koji Harano, Jun Kikkawa, Tatsuya Tsukuda. Synergistically Activated Pd Atom in Polymer-Stabilized Au23Pd1 Cluster. ACS Nano 2022, 16 (10) , 16932-16940.
    18. Xiaowen Chen, Mi Peng, Dequan Xiao, Hongyang Liu, Ding Ma. Fully Exposed Metal Clusters: Fabrication and Application in Alkane Dehydrogenation. ACS Catalysis 2022, 12 (20) , 12720-12743.
    19. Muhammad A. Abbas, Minwook Jeon, Jin Ho Bang. Understanding the Photoelectrochemical Behavior of Metal Nanoclusters: A Perspective. The Journal of Physical Chemistry C 2022, 126 (40) , 16928-16942.
    20. Kazeem O. Sulaiman, Andrew Bueckert, Ahmed Abdellah, Sudheesh Kumar Veeranmaril, Drew C. Higgins, Robert W. J. Scott. Atom-Precise Ag Clusters as Precursors for Selective Bimetallic AgPd Heterogeneous Catalysts. The Journal of Physical Chemistry C 2022, 126 (38) , 16117-16126.
    21. Xiao Cai, Guangjun Li, Weigang Hu, Yan Zhu. Catalytic Conversion of CO2 over Atomically Precise Gold-Based Cluster Catalysts. ACS Catalysis 2022, 12 (17) , 10638-10653.
    22. Wei Jiang, Xin An, Jin Xiao, Zhenzhen Yang, Jixing Liu, Hao Chen, Hongping Li, Wenshuai Zhu, Huaming Li, Sheng Dai. Enhanced Oxygen Activation Achieved by Robust Single Chromium Atom-Derived Catalysts in Aerobic Oxidative Desulfurization. ACS Catalysis 2022, 12 (14) , 8623-8631.
    23. Arunachalam Sagadevan, Atanu Ghosh, Partha Maity, Omar F. Mohammed, Osman M. Bakr, Magnus Rueping. Visible-Light Copper Nanocluster Catalysis for the C–N Coupling of Aryl Chlorides at Room Temperature. Journal of the American Chemical Society 2022, 144 (27) , 12052-12061.
    24. Jin Li, Qinglin Wang, Shudi Yu, Zhuojun Wei, Hui Zhang. Highly Dispersed Pd Nanoclusters on Layered Double Hydroxides with Proper Calcination Improving Solvent-Free Oxidation of Benzyl Alcohol. ACS Sustainable Chemistry & Engineering 2022, 10 (22) , 7223-7233.
    25. Nisha Mammen, Sami Malola, Karoliina Honkala, Hannu Häkkinen. Selective Acrolein Hydrogenation over Ligand-Protected Gold Clusters: A Venus Flytrap Mechanism. ACS Catalysis 2022, 12 (4) , 2365-2374.
    26. Kaiyuan Zheng, Jianping Xie. Cluster Materials as Traceable Antibacterial Agents. Accounts of Materials Research 2021, 2 (11) , 1104-1116.
    27. Xiang-Yu Xiao, Zong-Yin Song, Pei-Hua Li, Shi-Hua Chen, Li-Na Li, Meng Yang, Chu-Hong Lin, Xing-Jiu Huang. Au25 Nanoclusters Exhibit Superhigh Catalytic Activity in Electrochemical Detection of As(III). Analytical Chemistry 2021, 93 (41) , 14014-14023.
    28. Fuqin Zheng, Youjun Fan, Wei Chen. Homogeneous Distribution of Pt16(C4O4SH5)26 Clusters in ZIF-67 for Efficient Hydrogen Generation and Oxygen Reduction. ACS Applied Materials & Interfaces 2021, 13 (32) , 38170-38178.
    29. Sanghwa Lee, Megalamane S. Bootharaju, Guocheng Deng, Sami Malola, Hannu Häkkinen, Nanfeng Zheng, Taeghwan Hyeon. [Pt2Cu34(PET)22Cl4]2–: An Atomically Precise, 10-Electron PtCu Bimetal Nanocluster with a Direct Pt–Pt Bond. Journal of the American Chemical Society 2021, 143 (31) , 12100-12107.
    30. Jia-qi Bai, Masazumi Tamura, Akira Nakayama, Yoshinao Nakagawa, Keiichi Tomishige. Comprehensive Study on Ni- or Ir-Based Alloy Catalysts in the Hydrogenation of Olefins and Mechanistic Insight. ACS Catalysis 2021, 11 (6) , 3293-3309.
    31. Nianqiao Qin, An Pan, Jun Yuan, Fei Ke, Xiaoyan Wu, Jing Zhu, Jianqiang Liu, Junfa Zhu. One-Step Construction of a Hollow Au@Bimetal–Organic Framework Core–Shell Catalytic Nanoreactor for Selective Alcohol Oxidation Reaction. ACS Applied Materials & Interfaces 2021, 13 (10) , 12463-12471.
    32. Rongchao Jin, Gao Li, Sachil Sharma, Yingwei Li, Xiangsha Du. Toward Active-Site Tailoring in Heterogeneous Catalysis by Atomically Precise Metal Nanoclusters with Crystallographic Structures. Chemical Reviews 2021, 121 (2) , 567-648.
    33. Esma Khatun, Thalappil Pradeep. New Routes for Multicomponent Atomically Precise Metal Nanoclusters. ACS Omega 2021, 6 (1) , 1-16.
    34. Minseok Kim, K. L. Dimuthu M. Weerawardene, Woojun Choi, Sang Myeong Han, Juwon Paik, Younghun Kim, Moon-Gun Choi, Christine M. Aikens, Dongil Lee. Insights into the Metal-Exchange Synthesis of MAg24(SR)18 (M = Ni, Pd, Pt) Nanoclusters. Chemistry of Materials 2020, 32 (23) , 10216-10226.
    35. Rui Lang, Xiaorui Du, Yike Huang, Xunzhu Jiang, Qian Zhang, Yalin Guo, Kaipeng Liu, Botao Qiao, Aiqin Wang, Tao Zhang. Single-Atom Catalysts Based on the Metal–Oxide Interaction. Chemical Reviews 2020, 120 (21) , 11986-12043.
    36. Clara Garcia, Vera Truttmann, Irene Lopez, Thomas Haunold, Carlo Marini, Christoph Rameshan, Ernst Pittenauer, Peter Kregsamer, Klaus Dobrezberger, Michael Stöger-Pollach, Noelia Barrabés, Günther Rupprechter. Dynamics of Pd Dopant Atoms inside Au Nanoclusters during Catalytic CO Oxidation. The Journal of Physical Chemistry C 2020, 124 (43) , 23626-23636.
    37. Site Li, Dominic Alfonso, Anantha Venkataraman Nagarajan, Stephen D. House, Judith C. Yang, Douglas R. Kauffman, Giannis Mpourmpakis, Rongchao Jin. Monopalladium Substitution in Gold Nanoclusters Enhances CO2 Electroreduction Activity and Selectivity. ACS Catalysis 2020, 10 (20) , 12011-12016.
    38. Chunyang Dong, Yinlong Li, Danyang Cheng, Mengtao Zhang, Jinjia Liu, Yang-Gang Wang, Dequan Xiao, Ding Ma. Supported Metal Clusters: Fabrication and Application in Heterogeneous Catalysis. ACS Catalysis 2020, 10 (19) , 11011-11045.
    39. Kaiyuan Zheng, Jianping Xie. Composition-Dependent Antimicrobial Ability of Full-Spectrum AuxAg25–x Alloy Nanoclusters. ACS Nano 2020, 14 (9) , 11533-11541.
    40. Xi Kang, Xiao Wei, Shuxin Wang, Manzhou Zhu. Controlling the Phosphine Ligands of Pt1Ag28(S-Adm)18(PR3)4 Nanoclusters. Inorganic Chemistry 2020, 59 (13) , 8736-8743.
    41. Jing Zheng, Jianping Wang, Dandan Song, Jingli Xu, Min Zhang. Electrochemical Aptasensor of Carcinoembryonic Antigen Based on Concanavalin A-Functionalized Magnetic Copper Silicate Carbon Microtubes and Gold-Nanocluster-Assisted Signal Amplification. ACS Applied Nano Materials 2020, 3 (4) , 3449-3458.
    42. Xiao Cai, Weigang Hu, Shun Xu, Dan Yang, Mingyang Chen, Miao Shu, Rui Si, Weiping Ding, Yan Zhu. Structural Relaxation Enabled by Internal Vacancy Available in a 24-Atom Gold Cluster Reinforces Catalytic Reactivity. Journal of the American Chemical Society 2020, 142 (9) , 4141-4153.
    43. Tumpa Sadhukhan, Anchalee Junkaew, Pei Zhao, Hiroki Miura, Tetsuya Shishido, Masahiro Ehara. Importance of the Pd and Surrounding Sites in Hydrosilylation of Internal Alkynes by Palladium–Gold Alloy Catalyst. Organometallics 2020, 39 (4) , 528-537.
    44. Yuanxin Du, Hongting Sheng, Didier Astruc, Manzhou Zhu. Atomically Precise Noble Metal Nanoclusters as Efficient Catalysts: A Bridge between Structure and Properties. Chemical Reviews 2020, 120 (2) , 526-622.
    45. Yujing Guo, Lipeng Fan, Mengran Liu, Lan Yang, Guoli Fan, Feng Li. Nitrogen-Doped Carbon Quantum Dots-Decorated Mg-Al Layered Double Hydroxide-Supported Gold Nanocatalysts for Efficient Base-Free Oxidation of Benzyl Alcohol. Industrial & Engineering Chemistry Research 2020, 59 (2) , 636-646.
    46. Yan Zhao, Shengli Zhuang, Lingwen Liao, Chengming Wang, Nan Xia, Zibao Gan, Wanmiao Gu, Jin Li, Haiteng Deng, Zhikun Wu. A Dual Purpose Strategy to Endow Gold Nanoclusters with Both Catalysis Activity and Water Solubility. Journal of the American Chemical Society 2020, 142 (2) , 973-977.
    47. Esma Khatun, Papri Chakraborty, Betsy Rachel Jacob, Ganesan Paramasivam, Mohammad Bodiuzzaman, Wakeel Ahmed Dar, Thalappil Pradeep. Intercluster Reactions Resulting in Silver-Rich Trimetallic Nanoclusters. Chemistry of Materials 2020, 32 (1) , 611-619.
    48. Amala Dass, Naga Arjun Sakthivel, Vijay Reddy Jupally, Chanaka Kumara, Milan Rambukwella. Plasmonic Nanomolecules: Electrochemical Resolution of 22 Electronic States in Au329(SR)84. ACS Energy Letters 2020, 5 (1) , 207-214.
    49. Teera Butburee Aniwat Pengsawang Kajornsak Faungnawakij . Roles of Coordination Geometry in Single-Atom Catalysts. 2020, 37-76.
    50. Yonggang Yao, Zhennan Huang, Pengfei Xie, Tangyuan Li, Steven D. Lacey, Miaolun Jiao, Hua Xie, Kun Kelvin Fu, Rohit Jiji Jacob, Dylan Jacob Kline, Yong Yang, Michael R. Zachariah, Chao Wang, Reza Shahbazian-Yassar, Liangbing Hu. Ultrafast, Controllable Synthesis of Sub-Nano Metallic Clusters through Defect Engineering. ACS Applied Materials & Interfaces 2019, 11 (33) , 29773-29779.
    51. Xi Kang, Hadi Abroshan, Shuxin Wang, Manzhou Zhu. Free Valence Electron Centralization Strategy for Preparing Ultrastable Nanoclusters and Their Catalytic Application. Inorganic Chemistry 2019, 58 (16) , 11000-11009.
    52. Ming-Ming Zhu, Xian-Long Du, Yi Zhao, Bing-Bao Mei, Qi Zhang, Fan-Fei Sun, Zheng Jiang, Yong-Mei Liu, He-Yong He, Yong Cao. Ring-Opening Transformation of 5-Hydroxymethylfurfural Using a Golden Single-Atomic-Site Palladium Catalyst. ACS Catalysis 2019, 9 (7) , 6212-6222.
    53. M. Mozammel Hoque, Amala Dass, Kathryn M. Mayer, Robert L. Whetten. Protein-Like Large Gold Clusters Based on the ω-Aminothiolate DMAET: Precision Thermal and Reaction Control Leading to Selective Formation of Cationic Gold Clusters in the Critical Size Range, n = 130–144 Gold Atoms. The Journal of Physical Chemistry C 2019, 123 (23) , 14871-14879.
    54. Fahri Alkan, Pratima Pandeya, Christine M. Aikens. Understanding the Effect of Doping on Energetics and Electronic Structure for Au25, Ag25, and Au38 Clusters. The Journal of Physical Chemistry C 2019, 123 (14) , 9516-9527.
    55. Zhihua Zhuang, Qin Yang, Wei Chen. One-Step Rapid and Facile Synthesis of Subnanometer-Sized Pd6(C12H25S)11 Clusters with Ultra-High Catalytic Activity for 4-Nitrophenol Reduction. ACS Sustainable Chemistry & Engineering 2019, 7 (3) , 2916-2923.
    56. Xiaomei Zhao, Pu Wang, Zhongyun Ma, Yong Pei. Phenyl Ring Transfer Mechanism of Styrene Selective Oxidation to Phenyl Acetaldehyde on Gold Catalysts from Density Functional Theory (DFT) Studies. The Journal of Physical Chemistry C 2019, 123 (3) , 1710-1719.
    57. Atanu Ghosh, Omar F. Mohammed, Osman M. Bakr. Atomic-Level Doping of Metal Clusters. Accounts of Chemical Research 2018, 51 (12) , 3094-3103.
    58. Shuxin Wang, Qi Li, Xi Kang, Manzhou Zhu. Customizing the Structure, Composition, and Properties of Alloy Nanoclusters by Metal Exchange. Accounts of Chemical Research 2018, 51 (11) , 2784-2792.
    59. Leigh Sumner, Naga Arjun Sakthivel, Hayley Schrock, Kateryna Artyushkova, Amala Dass, Saumen Chakraborty. Electrocatalytic Oxygen Reduction Activities of Thiol-Protected Nanomolecules Ranging in Size from Au28(SR)20 to Au279(SR)84. The Journal of Physical Chemistry C 2018, 122 (43) , 24809-24817.
    60. Guoliang Xu, Ran Wang, Yingchun Ding, Zhansheng Lu, Dongwei Ma, Zongxian Yang. First-Principles Study on the Single Ir Atom Embedded Graphdiyne: An Efficient Catalyst for CO Oxidation. The Journal of Physical Chemistry C 2018, 122 (41) , 23481-23492.
    61. Matthew T. Darby, Michail Stamatakis, Angelos Michaelides, E. Charles. H. Sykes. Lonely Atoms with Special Gifts: Breaking Linear Scaling Relationships in Heterogeneous Catalysis with Single-Atom Alloys. The Journal of Physical Chemistry Letters 2018, 9 (18) , 5636-5646.
    62. Shridevi Bhat, Raghu Pradeep Narayanan, Ananya Baksi, Papri Chakraborty, Ganesan Paramasivam, Rabin Rajan J. Methikkalam, Abhijit Nag, Ganapati Natarajan, Thalappil Pradeep. Detection of [Au25(PET)18(O2)n]− (n = 1, 2, 3) Species by Mass Spectrometry. The Journal of Physical Chemistry C 2018, 122 (34) , 19455-19462.
    63. Mohamad El-Roz, Igor Telegeiev, Natalia E. Mordvinova, Oleg I. Lebedev, Nicolas Barrier, Asma Behilil, Moussa Zaarour, Louwanda Lakiss, Valentin Valtchev. Uniform Generation of Sub-nanometer Silver Clusters in Zeolite Cages Exhibiting High Photocatalytic Activity under Visible Light. ACS Applied Materials & Interfaces 2018, 10 (34) , 28702-28708.
    64. Tanya C. Jones, Leigh Sumner, Guda Ramakrishna, Mohammad bin Hatshan, Abubkr Abuhagr, Saumen Chakraborty, Amala Dass. Bulky t-Butyl Thiolated Gold Nanomolecular Series: Synthesis, Characterization, Optical Properties, and Electrocatalysis. The Journal of Physical Chemistry C 2018, 122 (31) , 17726-17737.
    65. Meng Zhou, Chuanhao Yao, Matthew Y. Sfeir, Tatsuya Higaki, Zhikun Wu, Rongchao Jin. Excited-State Behaviors of M1Au24(SR)18 Nanoclusters: The Number of Valence Electrons Matters. The Journal of Physical Chemistry C 2018, 122 (25) , 13435-13442.
    66. Shuo Zhao, Natalie Austin, Mo Li, Yongbo Song, Stephen D. House, Stefan Bernhard, Judith C. Yang, Giannis Mpourmpakis, Rongchao Jin. Influence of Atomic-Level Morphology on Catalysis: The Case of Sphere and Rod-Like Gold Nanoclusters for CO2 Electroreduction. ACS Catalysis 2018, 8 (6) , 4996-5001.
    67. Lichen Liu, Avelino Corma. Metal Catalysts for Heterogeneous Catalysis: From Single Atoms to Nanoclusters and Nanoparticles. Chemical Reviews 2018, 118 (10) , 4981-5079.
    68. Megalamane S. Bootharaju, Sergey M. Kozlov, Zhen Cao, Aleksander Shkurenko, Ahmed M. El-Zohry, Omar F. Mohammed, Mohamed Eddaoudi, Osman M. Bakr, Luigi Cavallo, Jean-Marie Basset. Tailoring the Crystal Structure of Nanoclusters Unveiled High Photoluminescence via Ion Pairing. Chemistry of Materials 2018, 30 (8) , 2719-2725.
    69. Mahendra R. Patil, Anant R. Kapdi, A. Vijay Kumar. Recyclable Supramolecular Ruthenium Catalyst for the Selective Aerobic Oxidation of Alcohols on Water: Application to Total Synthesis of Brittonin A. ACS Sustainable Chemistry & Engineering 2018, 6 (3) , 3264-3278.
    70. Jinglin Shen, Zhi Wang, Di Sun, Congxin Xia, Shiling Yuan, Panpan Sun, and Xia Xin . pH-Responsive Nanovesicles with Enhanced Emission Co-Assembled by Ag(I) Nanoclusters and Polyethyleneimine as a Superior Sensor for Al3+. ACS Applied Materials & Interfaces 2018, 10 (4) , 3955-3963.
    71. Xi Kang, Lin Xiong, Shuxin Wang, Yong Pei, and Manzhou Zhu . Combining the Single-Atom Engineering and Ligand-Exchange Strategies: Obtaining the Single-Heteroatom-Doped Au16Ag1(S-Adm)13 Nanocluster with Atomically Precise Structure. Inorganic Chemistry 2018, 57 (1) , 335-342.
    72. Jinsong Chai, Ying Lv, Sha Yang, Yongbo Song, Xiaofeng Zan, Qinzhen Li, Haizhu Yu, Mingzai Wu, and Manzhou Zhu . X-ray Crystal Structure and Optical Properties of Au38–xCux(2,4-(CH3)2C6H3S)24 (x = 0–6) Alloy Nanocluster. The Journal of Physical Chemistry C 2017, 121 (39) , 21665-21669.
    73. Indranath Chakraborty and Thalappil Pradeep . Atomically Precise Clusters of Noble Metals: Emerging Link between Atoms and Nanoparticles. Chemical Reviews 2017, 117 (12) , 8208-8271.
    74. Annelies Sels, Giovanni Salassa, Stephan Pollitt, Clara Guglieri, Günther Rupprechter, Noelia Barrabés, and Thomas Bürgi . Structural Investigation of the Ligand Exchange Reaction with Rigid Dithiol on Doped (Pt, Pd) Au25 Clusters. The Journal of Physical Chemistry C 2017, 121 (20) , 10919-10926.
    75. Cong-Qiao Xu, Mal-Soon Lee, Yang-Gang Wang, David C. Cantu, Jun Li, Vassiliki-Alexandra Glezakou, and Roger Rousseau . Structural Rearrangement of Au–Pd Nanoparticles under Reaction Conditions: An ab Initio Molecular Dynamics Study. ACS Nano 2017, 11 (2) , 1649-1658.
    76. Zhixun Luo, A. W. Castleman, Jr., and Shiv N. Khanna . Reactivity of Metal Clusters. Chemical Reviews 2016, 116 (23) , 14456-14492.
    77. Johanna Camacho Gonzalez and Alvaro Muñoz-Castro . Doping the Superatom with p-Elements: The Role of p-Block Endohedral Atoms in Bonding and Optical Properties of E@Au24(SR)18 (E = Si, Ge, Sn, and Pb) from Relativistic DFT Calculations. The Journal of Physical Chemistry C 2016, 120 (47) , 27019-27026.
    78. Yong Yu, Qiaofeng Yao, Tiankai Chen, Guo Xing Lim, and Jianping Xie . The Innermost Three Gold Atoms Are Indispensable To Maintain the Structure of the Au18(SR)14 Cluster. The Journal of Physical Chemistry C 2016, 120 (38) , 22096-22102.
    79. Weili Li, Chao Liu, Hadi Abroshan, Qingjie Ge, Xiujuan Yang, Hengyong Xu, and Gao Li . Catalytic CO Oxidation Using Bimetallic MxAu25–x Clusters: A Combined Experimental and Computational Study on Doping Effects. The Journal of Physical Chemistry C 2016, 120 (19) , 10261-10267.
    80. Yu Wang, Xian-Kai Wan, Liting Ren, Haifeng Su, Gang Li, Sami Malola, Shuichao Lin, Zichao Tang, Hannu Häkkinen, Boon K Teo, Quan-Ming Wang, and Nanfeng Zheng . Atomically Precise Alkynyl-Protected Metal Nanoclusters as a Model Catalyst: Observation of Promoting Effect of Surface Ligands on Catalysis by Metal Nanoparticles. Journal of the American Chemical Society 2016, 138 (10) , 3278-3281.
    81. Masaru Urushizaki, Hirokazu Kitazawa, Shinjiro Takano, Ryo Takahata, Seiji Yamazoe, and Tatsuya Tsukuda . Synthesis and Catalytic Application of Ag44 Clusters Supported on Mesoporous Carbon. The Journal of Physical Chemistry C 2015, 119 (49) , 27483-27488.
    82. Yizhong Lu and Wei Chen . Application of Mass Spectrometry in the Synthesis and Characterization of Metal Nanoclusters. Analytical Chemistry 2015, 87 (21) , 10659-10667.
    83. Atal Shivhare, Kee Eun Lee, Yongfeng Hu, and Robert W. J. Scott . Following the Reactivity of Au25(SC8H9)18– Clusters with Pd2+ and Ag+ Ions Using in Situ X-ray Absorption Spectroscopy: A Tale of Two Metals. The Journal of Physical Chemistry C 2015, 119 (40) , 23279-23284.
    84. Juanzhu Yan, Haifeng Su, Huayan Yang, Sami Malola, Shuichao Lin, Hannu Häkkinen, and Nanfeng Zheng . Total Structure and Electronic Structure Analysis of Doped Thiolated Silver [MAg24(SR)18]2– (M = Pd, Pt) Clusters. Journal of the American Chemical Society 2015, 137 (37) , 11880-11883.
    85. Saumen Chakraborty, Sofia Babanova, Reginaldo C. Rocha, Anil Desireddy, Kateryna Artyushkova, Amy E. Boncella, Plamen Atanassov, and Jennifer S. Martinez . A Hybrid DNA-Templated Gold Nanocluster For Enhanced Enzymatic Reduction of Oxygen. Journal of the American Chemical Society 2015, 137 (36) , 11678-11687.
    86. Kyuju Kwak, Qing Tang, Minseok Kim, De-en Jiang, and Dongil Lee . Interconversion between Superatomic 6-Electron and 8-Electron Configurations of M@Au24(SR)18 Clusters (M = Pd, Pt). Journal of the American Chemical Society 2015, 137 (33) , 10833-10840.
    87. Kenichi Koizumi, Katsuyuki Nobusada, and Mauro Boero . Reaction Pathway and Free Energy Landscape of Catalytic Oxidation of Carbon Monoxide Operated by a Novel Supported Gold–Copper Alloy Cluster. The Journal of Physical Chemistry C 2015, 119 (27) , 15421-15427.
    88. Yuxiang Chen, Chenjie Zeng, Douglas R. Kauffman, and Rongchao Jin . Tuning the Magic Size of Atomically Precise Gold Nanoclusters via Isomeric Methylbenzenethiols. Nano Letters 2015, 15 (5) , 3603-3609.
    89. Shuxin Wang, Yongbo Song, Shan Jin, Xia Liu, Jun Zhang, Yong Pei, Xiangming Meng, Man Chen, Peng Li, and Manzhou Zhu . Metal Exchange Method Using Au25 Nanoclusters as Templates for Alloy Nanoclusters with Atomic Precision. Journal of the American Chemical Society 2015, 137 (12) , 4018-4021.
    90. Atal Shivhare, Lisa Wang, and Robert W. J. Scott . Isolation of Carboxylic Acid-Protected Au25 Clusters Using a Borohydride Purification Strategy. Langmuir 2015, 31 (5) , 1835-1841.
    91. Sami Malola, Michael J. Hartmann, and Hannu Häkkinen . Copper Induces a Core Plasmon in Intermetallic Au(144,145)–xCux(SR)60 Nanoclusters. The Journal of Physical Chemistry Letters 2015, 6 (3) , 515-520.
    92. Christopher E. Angevine, Amy E. Chavis, Nuwan Kothalawala, Amala Dass, and Joseph E. Reiner . Enhanced Single Molecule Mass Spectrometry via Charged Metallic Clusters. Analytical Chemistry 2014, 86 (22) , 11077-11085.
    93. Noelia Barrabés, Bei Zhang, and Thomas Bürgi . Racemization of Chiral Pd2Au36(SC2H4Ph)24: Doping Increases the Flexibility of the Cluster Surface. Journal of the American Chemical Society 2014, 136 (41) , 14361-14364.
    94. Tatchamapan Yoskamtorn, Seiji Yamazoe, Ryo Takahata, Jun-ichi Nishigaki, Anawat Thivasasith, Jumras Limtrakul, and Tatsuya Tsukuda . Thiolate-Mediated Selectivity Control in Aerobic Alcohol Oxidation by Porous Carbon-Supported Au25 Clusters. ACS Catalysis 2014, 4 (10) , 3696-3700.
    95. Hideya Kawasaki, Santosh Kumar, Gao Li, Chenjie Zeng, Douglas R. Kauffman, Junya Yoshimoto, Yasuhiko Iwasaki, and Rongchao Jin . Generation of Singlet Oxygen by Photoexcited Au25(SR)18 Clusters. Chemistry of Materials 2014, 26 (9) , 2777-2788.
    96. Aleksandar Staykov, Yuuki Ooishi, and Tatsumi Ishihara . Immobilizing Metal Nanoparticles on Single Wall Nanotubes. Effect of Surface Curvature. The Journal of Physical Chemistry C 2014, 118 (17) , 8907-8916.
    97. Zili Wu, De-en Jiang, Amanda K. P. Mann, David R. Mullins, Zhen-An Qiao, Lawrence F. Allard, Chenjie Zeng, Rongchao Jin, and Steven H. Overbury . Thiolate Ligands as a Double-Edged Sword for CO Oxidation on CeO2 Supported Au25(SCH2CH2Ph)18 Nanoclusters. Journal of the American Chemical Society 2014, 136 (16) , 6111-6122.
    98. Seiji Yamazoe, Kiichirou Koyasu, and Tatsuya Tsukuda . Nonscalable Oxidation Catalysis of Gold Clusters. Accounts of Chemical Research 2014, 47 (3) , 816-824.
    99. Ruirui Dun, Xueguang Wang, Mingwu Tan, Zhen Huang, Xuemin Huang, Weizhong Ding, and Xionggang Lu . Quantitative Aerobic Oxidation of Primary Benzylic Alcohols to Aldehydes Catalyzed by Highly Efficient and Recyclable P123-Stabilized Pd Nanoclusters in Acidic Aqueous Solution. ACS Catalysis 2013, 3 (12) , 3063-3066.
    100. Atal Shivhare, Daniel M. Chevrier, Randy W. Purves, and Robert W. J. Scott . Following the Thermal Activation of Au25(SR)18 Clusters for Catalysis by X-ray Absorption Spectroscopy. The Journal of Physical Chemistry C 2013, 117 (39) , 20007-20016.
    Load more citations

    Pair your accounts.

    Export articles to Mendeley

    Get article recommendations from ACS based on references in your Mendeley library.

    Pair your accounts.

    Export articles to Mendeley

    Get article recommendations from ACS based on references in your Mendeley library.

    You’ve supercharged your research process with ACS and Mendeley!

    STEP 1:
    Click to create an ACS ID

    Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

    Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

    Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

    Your Mendeley pairing has expired. Please reconnect