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Teaching Three-Dimensional Structural Chemistry Using Crystal Structure Databases. 2. Teaching Units That Utilize an Interactive Web-Accessible Subset of the Cambridge Structural Database

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Cambridge Crystallographic Data Center, 12 Union Road, Cambridge CB2 1EZ, United Kingdom
Department of Chemistry, Illinois State University, Normal, Illinois 61790-4160
Cite this: J. Chem. Educ. 2010, 87, 8, 813–818
Publication Date (Web):June 9, 2010
https://doi.org/10.1021/ed100257t
Copyright © 2010 The American Chemical Society and Division of Chemical Education, Inc.
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Abstract

A series of online interactive teaching units have been developed that illustrate the use of experimentally measured three-dimensional (3D) structures to teach fundamental chemistry concepts. The units integrate a 500-structure subset of the Cambridge Structural Database specially chosen for their pedagogical value. The units span a number of key chemical concepts (aromaticity, ring strain and conformation, stereochemistry and chirality, VSEPR, and hapticity) and guide students via a Web-based interface to visualize and interact with a diverse range of molecules. The units were designed to help students develop a visual understanding of 3D chemical structure and gain an appreciation of the unique advantages afforded by working with experimentally measured data.

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