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Emission of Titanium Dioxide Nanoparticles from Building Materials to the Environment by Wear and Weather
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    Emission of Titanium Dioxide Nanoparticles from Building Materials to the Environment by Wear and Weather
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    Institut National de l’Environnement Industriel et des Risques, Parc Technologique Alata BP 2, 60550 Verneuil-en-Halatte, France
    Sorbonne Universités, Université de Technologie de Compiègne, Laboratoire TIMR, Centre de recherche Royallieu, CS 60 319, 60 203 Compiègne, Cedex, France
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    Environmental Science & Technology

    Cite this: Environ. Sci. Technol. 2015, 49, 4, 2163–2170
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    https://doi.org/10.1021/es504710p
    Published January 15, 2015
    Copyright © 2015 American Chemical Society

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    In the present work, we investigate the effect of weathering duration on a commercial photocatalytic nanocoating on the basis of its nanoparticle emission tendency into two media, air and water. It is found that increased weathering duration results in stepwise structural deterioration of the nanocoating, which in turn decreases the nanocoating life, changes the nanocoating removal mechanism, and increases the particle emission concentration. Emission of free TiO2 nanoparticles is found to be weathering duration dependent. Three quantities are introduced: emission transition pace (ETP), stable emission level (SEL), and stable emission duration (SED). By linear extrapolation of these quantities from short weathering durations, complete failure of the nanocoatings can be predicted and, moreover, the potential increase of nanoparticles release into the air.

    Copyright © 2015 American Chemical Society

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    Additional text and three figures, describing microscopic analysis of nanocoating solution, uncoated brick, and Taber H38 abradant; microscopic analysis of leachate water; effect of weathering on uncoated brick reference; and drop deposition technique. This material is available free of charge via the Internet at http://pubs.acs.org/.

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    Environmental Science & Technology

    Cite this: Environ. Sci. Technol. 2015, 49, 4, 2163–2170
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    https://doi.org/10.1021/es504710p
    Published January 15, 2015
    Copyright © 2015 American Chemical Society

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