ACS Publications. Most Trusted. Most Cited. Most Read
Observation of Dominant Ferromagnetic Interaction in Fumarate-Bridged 1-D Polymer of Cu(II)

OR SEARCH CITATIONS

My Activity
Publications

Figure 1Loading Img
Download Hi-Res ImageDownload to MS-PowerPointCite This:Inorg. Chem. 2001, 40, 5, 928-931
    Article

    Observation of Dominant Ferromagnetic Interaction in Fumarate-Bridged 1-D Polymer of Cu(II)
    Click to copy article linkArticle link copied!

    View Author Information
    Department of Inorganic Chemistry, Indian Association for the Cultivation of Science, Calcutta-700032, India, Department of Physics, Krishnath College, Berhampur 742109, India, and Departament de Quimica Inorganica, Universitat de Barcelona, Diagonal 647, 08028-Barcelona, Spain
    Other Access OptionsSupporting Information (1)

    Inorganic Chemistry

    Cite this: Inorg. Chem. 2001, 40, 5, 928–931
    Click to copy citationCitation copied!
    https://doi.org/10.1021/ic000949m
    Published January 24, 2001
    Copyright © 2001 American Chemical Society
    Request reuse permissions

    Abstract

    Click to copy section linkSection link copied!
    Abstract Image

    The reaction of CuCl2·2H2O and Na2C4H2O4 (disodium fumarate) in dilute ammonia solution produces 1-D polymeric chain [Cu(μ-C4H2O4)(NH3)2]n(H2O)n. The crystal structure of the compound has been solved. The compound crystallizes in the monoclinic system, space group C2/m (No. 12), with chemical formula C4H10N2O5Cu, a = 13.955(5) Å, b = 7.330(3) Å, c = 8.927(2) Å, β = 102.39(3)°, Z = 4. The interesting feature of the complex is that one of the carboxylic acid groups acts as a monodentate coordinating ligand whereas the remaining carboxylate moiety acts as a monoatomic bridging bidentate ligand. This unusual coordination behavior of fumarate anion produces a chain with alternate repetition of 4- and 14-member rings. The magnetic properties of the compound have been studied from room temperature to 4 K, which reveal the existence of a dominant ferromagnetic interaction with exchange coupling parameter values of JF = +12 cm-1 and JAF = −3.8 cm-1, using an alternating ferro- and antiferromagnetic chain model for S = 1/2 local spin. The ferromagnetic interaction arises from the alkoxo-bridged dimeric part of the chain. The fitting of the χMT vs T data continued until the maximum in the experimental data using a single dinuclear model resulted in J = +7.8 cm-1.

    Copyright © 2001 American Chemical Society

    Subjects

    what are subjects

    Read this article

    To access this article, please review the available access options below.

    Get instant access

    Purchase Access

    Read this article for 48 hours. Check out below using your ACS ID or as a guest.

    Recommended

    Access through Your Institution

    You may have access to this article through your institution.

    Your institution does not have access to this content. Add or change your institution or let them know you’d like them to include access.

    †

     Indian Association for the Cultivation of Science.

    ‡

     Krishnath College.

    *

     To whom correspondence should be addressed.

    §

     Universitat de Barcelona.

    ‖

     E-mail:  [email protected]. Fax:  34-93-4907725.

    ⊥

     E-mail:  [email protected]. Fax:  91-33-473 2805.

    Supporting Information Available

    Click to copy section linkSection link copied!

    An X-ray crystallographic data file, in CIF format, giving data and details of the structure determination, bond lengths, bond angles, atomic and hydrogen coordinates, equivalent displacement parameters, and anisotropic parameters. This material is available free of charge via the Internet at http://pubs.acs.org.

    Terms & Conditions

    Most electronic Supporting Information files are available without a subscription to ACS Web Editions. Such files may be downloaded by article for research use (if there is a public use license linked to the relevant article, that license may permit other uses). Permission may be obtained from ACS for other uses through requests via the RightsLink permission system: http://pubs.acs.org/page/copyright/permissions.html.

    Cited By

    Click to copy section linkSection link copied!

    This article is cited by 53 publications.

    1. Jayanta K. Nath, Abhishake Mondal, Annie K. Powell, and Jubaraj B. Baruah . Structures, Magnetic Properties, and Photoluminescence of Dicarboxylate Coordination Polymers of Mn, Co, Ni, Cu Having N-(4-Pyridylmethyl)-1,8-naphthalimide. Crystal Growth & Design 2014, 14 (9) , 4735-4748. https://doi.org/10.1021/cg500882z
    2. Min-Min Liu, Juan-Juan Hou, Zhi-kai Qi, Li−Na Duan, Wen-Juan Ji, Cai-yun Han, and Xian-Ming Zhang . Tuning of Valence States, Bonding Types, Hierarchical Structures, and Physical Properties in Copper/Halide/Isonicotinate System. Inorganic Chemistry 2014, 53 (8) , 4130-4143. https://doi.org/10.1021/ic5001232
    3. Guoqi Zhang,, Guoqiang Yang, and, Jin Shi Ma. Hydrothermal Syntheses and Characterization of Novel 3D Open-Framework and 2D Grid Lanthanide Fumarates:  Ln2(fum)3(H2fum)(H2O)2 (Ln = Ce or Nd), [Sm2(fum)3(H2O)4](H2O)3, and [Yb2(fum)3(H2O)4](H2O)2. Crystal Growth & Design 2006, 6 (4) , 933-939. https://doi.org/10.1021/cg050488l
    4. Vladimír Zeleňák,, Alžbeta Orendáčová,, Ivana Císařová,, Juraj Černák,, Oxana V. Kravchyna,, Ju-Hyun Park,, Martin Orendáč,, Alexander G. Anders,, Alexander Feher, and, Mark W. Meisel. Magneto-Structural Correlations in Cu(tn)Cl2 (tn = 1,3-Diaminopropane):  Two-Dimensional Spatially Anisotropic Triangular Magnet Formed by Hydrogen Bonds. Inorganic Chemistry 2006, 45 (4) , 1774-1782. https://doi.org/10.1021/ic0516109
    5. A. K. Ghosh,, D. Ghoshal,, E. Zangrando,, J. Ribas, and, N. Ray Chaudhuri. Rare Azido-Bridged Manganese(II) Systems:  Syntheses, Crystal Structures, and Magnetic Properties. Inorganic Chemistry 2005, 44 (6) , 1786-1793. https://doi.org/10.1021/ic048466w
    6. Christian Serre,, Jérôme Marrot, and, Gérard Férey. An Open-Framework Rare-Earth Acetylenedicarboxylate:  MIL-95, EuIII2(H2O)2(CO3)2·{O2C−C2−CO2}·{H2O}x. Inorganic Chemistry 2005, 44 (3) , 654-657. https://doi.org/10.1021/ic0487373
    7. Sanjit Konar,, Partha Sarathi Mukherjee,, Michael G. B. Drew,, Joan Ribas, and, Nirmalendu Ray Chaudhuri. Syntheses of Two New 1D and 3D Networks of Cu(II) and Co(II) Using Malonate and Urotropine as Bridging Ligands: Crystal Structures and Magnetic Studies. Inorganic Chemistry 2003, 42 (8) , 2545-2552. https://doi.org/10.1021/ic020549u
    8. Tapas Kumar Maji,, Saugata Sain,, Golam Mostafa,, Tian-Huey Lu,, Joan Ribas,, Montserrat Monfort, and, Nirmalendu Ray Chaudhuri. Magneto−Structural Correlations in 2D and 3D Extended Structures of Manganese(II)−Malonate Systems. Inorganic Chemistry 2003, 42 (3) , 709-716. https://doi.org/10.1021/ic020238j
    9. Panagiotis A. Angaridis,, Peter Baran,, R. Boča,, Francisco Cervantes-Lee,, W. Haase,, Gellert Mezei,, Raphael G. Raptis, and, R. Werner. Synthesis and Structural Characterization of Trinuclear CuII−Pyrazolato Complexes Containing μ3-OH, μ3-O, and μ3-Cl Ligands. Magnetic Susceptibility Study of [PPN]2[(μ3-O)Cu3(μ-pz)3Cl3]. Inorganic Chemistry 2002, 41 (8) , 2219-2228. https://doi.org/10.1021/ic010670l
    10. Amal Das, Pranay Sharma, Antonio Frontera, Miquel Barcelo-Oliver, Akalesh K. Verma, Ruksana Sultana Ahmed, Sahid Hussain, Manjit K. Bhattacharyya. Supramolecular assemblies involving biologically relevant antiparallel π-stacking and unconventional solvent driven structural topology in maleato and fumarato bridged Zn( ii ) coordination polymers: antiproliferative evaluation and theoretical studies. New Journal of Chemistry 2021, 45 (29) , 13040-13055. https://doi.org/10.1039/D1NJ00619C
    11. M. Narsimhulu. Crystal growth, spectral, optical, thermal, luminescence and magnetic properties of blue light emitting diaquabis(hydrogenmalonato)cobalt(II). Molecular Crystals and Liquid Crystals 2020, 703 (1) , 23-31. https://doi.org/10.1080/15421406.2020.1744337
    12. Firas Krichen, Siwar Walha, Jérôme Lhoste, François Goutenoire, Ahlem Kabadou. Design of lanthanide metal organic frameworks incorporating dicarboxylate ligands. Journal of Porous Materials 2019, 26 (6) , 1679-1689. https://doi.org/10.1007/s10934-019-00768-0
    13. Anshuman Gogoi, Amal Das, Antonio Frontera, Akalesh K. Verma, Manjit K. Bhattacharyya. Energetically significant unconventional π-π contacts involving fumarate in a novel coordination polymer of Zn(II): In-vitro anticancer evaluation and theoretical studies. Inorganica Chimica Acta 2019, 493 , 1-13. https://doi.org/10.1016/j.ica.2019.04.047
    14. Aparup Paul, Albert Figuerola, Valerio Bertolasi, Subal Chandra Manna. DNA/protein binding and magnetic properties of a 1D Cu(II) complex containing fumarate and tridentate Schiff base ligands. Polyhedron 2016, 119 , 460-470. https://doi.org/10.1016/j.poly.2016.09.028
    15. Amit Adhikary, Soumyabrata Goswami, Javeed Ahmad Sheikh, Sanjit Konar. Formation of a Magnetically Coupled Neutral [4×4] Square Grid from a 2,6‐Pyridinedicarbaldehyde Bis(hydrazone) Ligand. European Journal of Inorganic Chemistry 2014, 2014 (6) , 963-967. https://doi.org/10.1002/ejic.201301536
    16. Amit Adhikary, Javeed Ahmad Sheikh, Anita Dutt Konar, Sanjit Konar. Synthesis, crystal structure, magnetic study and magneto-structural correlation of three Cu(ii) complexes formed via pyridine bis(hydrazone) based ligand. RSC Advances 2014, 4 (24) , 12408. https://doi.org/10.1039/c3ra45928d
    17. Yuliya M. Davydenko, Serhiy Demeshko, Vadim A. Pavlenko, Sebastian Dechert, Franc Meyer, Igor O. Fritsky. Synthesis, Crystal Structure, Spectroscopic and Magnetically Study of Two Copper(II) Complexes with Pyrazole Ligand. Zeitschrift für anorganische und allgemeine Chemie 2013, 639 (8-9) , 1472-1476. https://doi.org/10.1002/zaac.201300078
    18. V. Lozan. Dinuclear Complexes as Building Blocks for Tetra-Nuclear Macrocyclic Complexes with Dithiolate Macrocyclic Ligand. Chemistry Journal of Moldova 2013, 8 (1) , 58-77. https://doi.org/10.19261/cjm.2013.08(1).08
    19. E. N. Nfor, E. A. Eno, J. N. Foba-Tendo, G. E. Iniama, E. O. Duke, O. E. Offiong. Copper(II) malonate coordination frameworks with amino-1,2,4-triazole: Crystal structures and magnetic properties of [Cu2(mal)2(datz)2(H2O)]·5H2O and [Cu2(mal)2(atz)2(H2O)]·3H2O. Journal of Structural Chemistry 2012, 53 (6) , 1118-1124. https://doi.org/10.1134/S0022476612060157
    20. Junghwan Do, Yumi Lee, Jaeun Kang, Allan J. Jacobson. A twofold interpenetrating network constructed from silver ions coordinated to fumaric acid and pyrazine: Ag2(fum)(H2fum)(pyz)2 (fum=fumarate, pyz=pyrazine). Inorganica Chimica Acta 2012, 382 , 191-194. https://doi.org/10.1016/j.ica.2011.11.061
    21. Suzhi Li, Pengtao Ma, Haizhu Niu, Junwei Zhao, Jingyang Niu. {[Cu(phen)]3Cl4}2[GeMo12O40]: Synthesis, crystal structure and magnetic property of a new trinuclear copper complex based on germanomolybdate. Inorganic Chemistry Communications 2010, 13 (7) , 805-808. https://doi.org/10.1016/j.inoche.2010.03.028
    22. Pallab Mondal, Abhishake Mondal, Enrique Colacio, Atanu Banerjee. Binuclear terephthalato-bridged copper(II) complex with N 2 O 2 coordinating tripodal ligand: synthesis, structure, magnetic properties, and DFT study. Journal of Coordination Chemistry 2010, 63 (11) , 1893-1903. https://doi.org/10.1080/00958972.2010.494723
    23. Anatolii D. Pomogailo, Vladimir N. Kestelman, Gulzhian I. Dzhardimalieva. Spectral Characteristics and Molecular Structure of Unsaturated Carboxylic Acid Salts. 2010, 57-104. https://doi.org/10.1007/978-3-642-10574-6_4
    24. Anatolii D. Pomogailo, Vladimir N. Kestelman, Gulzhian I. Dzhardimalieva. Synthesis of Unsaturated Carboxylic Acid Salts. 2010, 27-55. https://doi.org/10.1007/978-3-642-10574-6_3
    25. Xiao-Hong Geng, Yun-Long Feng, You-Zhao Lan, Li-Chun Kong. Coordination polymers with adamantanediacetate bridges: syntheses, structures, and magnetic properties. Structural Chemistry 2009, 20 (5) , 877-882. https://doi.org/10.1007/s11224-009-9486-0
    26. Ming-Li Liu, Wei Shi, Hai-Bin Song, Peng Cheng, Dai-Zheng Liao, Shi-Ping Yan. Open and closed copper chain coordination polymers with alternating ferromagnetic and antiferromagnetic interactions. CrystEngComm 2009, 11 (1) , 102-108. https://doi.org/10.1039/B816161P
    27. M. Padmanabhan, James C. Joseph, Xiaoying Huang, Jing Li. Diamine incorporated compounds derived from polymeric nickel(II) fumarates and oxalates: Crystal structure, spectral and thermal properties of [Ni(en)3](O2CCHCHCO2)·3H2O and [Ni(en)3](O2CCO2). Journal of Molecular Structure 2008, 885 (1-3) , 36-44. https://doi.org/10.1016/j.molstruc.2007.10.012
    28. Franz A. Mautner, Ramon Vicente, Febee R.Y. Louka, Salah S. Massoud. Dinuclear fumarato- and terephthalato-bridged copper(II) complexes: Structural characterization and magnetic properties. Inorganica Chimica Acta 2008, 361 (5) , 1339-1348. https://doi.org/10.1016/j.ica.2007.08.026
    29. He-Dong Bian, Xiao-E Yang, Qing Yu, Zi-Lu Chen, Hong Liang, Shi-Ping Yan, Dai-Zheng Liao. Synthesis, structure, and magnetic properties of two 1-D helical coordination polymeric Cu(II) complexes. Journal of Molecular Structure 2008, 872 (1) , 40-46. https://doi.org/10.1016/j.molstruc.2007.02.009
    30. M. Padmanabhan, James C. Joseph, A. Thirumurugan, C. N. R. Rao. Maleate–fumarate conversion and other novel aspects of the reaction of a Co(ii) maleate with pyridine and bipyridine. Dalton Transactions 2008, 120 (21) , 2809. https://doi.org/10.1039/b718623a
    31. Julia Klingele, Marco H. Klingele, Oliver Baars, Vasile Lozan, Axel Buchholz, Guido Leibeling, Winfried Plass, Franc Meyer, Berthold Kersting. Tetranuclear Nickel(II) Complexes Composed of Pairs of Dinuclear LNi 2 Fragments Linked by Acetylenedicarboxylate, Terephthalate, and Isophthalate Dianions: Synthesis, Structures and Magnetic Properties. European Journal of Inorganic Chemistry 2007, 2007 (33) , 5277-5285. https://doi.org/10.1002/ejic.200700748
    32. Subal Chandra Manna, Sanjit Konar, Ennio Zangrando, Joan Ribas, Nirmalendu Ray Chaudhuri. 3D Heterometallic (3d–4f) coordination polymers: A ferromagnetic interaction in a Gd(III)–Cu(II) couple. Polyhedron 2007, 26 (12) , 2507-2516. https://doi.org/10.1016/j.poly.2006.12.042
    33. Guoqi Zhang, Qian Wang, Yan Qian, Guoqiang Yang, Jin Shi Ma. Synthesis, characterization and photoluminescence properties of two new europium(III) coordination polymers with 3D open framework. Journal of Molecular Structure 2006, 796 (1-3) , 187-194. https://doi.org/10.1016/j.molstruc.2006.01.048
    34. Subal Chandra Manna, Ennio Zangrando, Joan Ribas, Nirmalendu Ray Chaudhuri. Carboxylato-bridged 3D polymeric networks of Gd(III): Synthesis, crystal structure, magnetic property and thermal behavior. Polyhedron 2006, 25 (8) , 1779-1786. https://doi.org/10.1016/j.poly.2005.11.034
    35. Subal Chandra Manna, Ennio Zangrando, Michael G. B. Drew, Joan Ribas, Nirmalendu Ray Chaudhuri. Syntheses, Crystal Structures and Magnetic Properties of Carboxylato‐Bridged Polymeric Networks of Mn II. European Journal of Inorganic Chemistry 2006, 2006 (2) , 481-490. https://doi.org/10.1002/ejic.200500568
    36. Subal Chandra Manna, Ennio Zangrando, Joan Ribas, Nirmalendu Ray Chaudhuri. Squarato-bridged polymeric networks of iron(II) with N-donor coligands: Syntheses, crystal structures and magnetic properties. Inorganica Chimica Acta 2005, 358 (15) , 4497-4504. https://doi.org/10.1016/j.ica.2005.07.014
    37. Subal Chandra Manna, Sanjit Konar, Ennio Zangrando, Ken‐ichi Okamoto, Joan Ribas, Nirmalendu Ray Chaudhuri. Mn II /Co II ‐Terephthalate Frameworks Containing Dipyridine Coligands: Syntheses, Crystal Structures, Magnetic Behaviors, and Thermal Studies. European Journal of Inorganic Chemistry 2005, 2005 (22) , 4646-4654. https://doi.org/10.1002/ejic.200500258
    38. Subal Chandra Manna, Sanjit Konar, Ennio Zangrando, Michael G. B. Drew, Joan Ribas, Nirmalendu Ray Chaudhuri. Two New μ‐(1,3‐Azido)‐Bridged Polymers: Alternating Single and Double Bridges in a 1D Nickel( II ) Complex and Uniform Bridge in a 2D Copper( II ) Complex: Syntheses, Single‐Crystal Structures and Magnetic Studies. European Journal of Inorganic Chemistry 2005, 2005 (9) , 1751-1758. https://doi.org/10.1002/ejic.200400930
    39. Q.M. Liu, K.L. Yao, Z.L. Liu. A two-leg spin ladder model for fumarate-bridged chain-like polymer of Cu(II). Solid State Communications 2005, 133 (9) , 599-603. https://doi.org/10.1016/j.ssc.2004.11.039
    40. Wei Zhao, Jian Fan, You Song, Hiroyuki Kawaguchi, Taka-aki Okamura, Wei-Yin Sun, Norikazu Ueyama. Syntheses, crystal structures and properties of novel copper(ii) complexes obtained by reactions of copper(ii) sulfate pentahydrate with tripodal ligands. Dalton Transactions 2005, 101 (8) , 1509. https://doi.org/10.1039/b419418g
    41. Sanjit Konar, Subal Chandra Manna, Ennio Zangrando, Talal Mallah, Joan Ribas, Nirmalendu Ray Chaudhuri. Structural and Magnetic Properties of Two Carboxylato‐Bridged Manganese( II ) Complexes with N‐Donor Coligands. European Journal of Inorganic Chemistry 2004, 2004 (21) , 4202-4208. https://doi.org/10.1002/ejic.200400148
    42. Mao Liang, Qing-Lun Wang, Li-Hua Yu, Dai-Zheng Liao, Zong-Hui Jiang, Shi-Ping Yan, Peng Cheng. A novel 3D malonato-bridged compound Cu(mal)(pz)2: synthesis, spectroscopy, crystal structure and magnetism. Polyhedron 2004, 23 (14) , 2203-2208. https://doi.org/10.1016/j.poly.2004.06.027
    43. K. L. Yao, L. Zhu, Z. L. Liu. First-principles study of the ferromagnetic and half-metallic properties of the fumarate-bridged polymer. The European Physical Journal B 2004, 39 (3) , 283-286. https://doi.org/10.1140/epjb/e2004-00192-y
    44. Kou-Lin Zhang, Zheng Wang, Hui Huang, Yu Zhu, Xiao-Zeng You. Synthesis, crystal structure and magnetic properties of a novel dinuclear cobalt(II) complex based on the mixed N- and O-donor ligands: [Co2(pyrazine)(fumarato)2(H2O)8]·7H2O. Journal of Molecular Structure 2004, 693 (1-3) , 193-197. https://doi.org/10.1016/j.molstruc.2004.03.001
    45. Maria Vanda Marinho, Maria Irene Yoshida, Kassilio J. Guedes, Klaus Krambrock, Adailton J. Bortoluzzi, Manfredo Hörner, Flávia C. Machado, Wagner M. Teles. Synthesis, Crystal Structure, and Spectroscopic Characterization of trans -Bis[(μ-1,3-bis(4-pyridyl)propane)(μ-(3-thiopheneacetate- O ))(3-thiopheneacetate- O )]dicopper(II), {[Cu 2 (O 2 CCH 2 C 4 H 3 S) 4 μ-(BPP) 2 ]} n :  From a Dinuclear Paddle-Wheel Copper(II) Unit to a 2-D Coordination Polymer Involving Monatomic Carboxylate Bridges. Inorganic Chemistry 2004, 43 (4) , 1539-1544. https://doi.org/10.1021/ic035251y
    46. Sanjit Konar, Ennio Zangrando, Michael G. B. Drew, Joan Ribas, Nirmalendu Ray Chaudhuri. Synthesis, structural analysis, and magnetic behaviour of three fumarate bridged coordination polymers: five-fold interpenetrated diamond-like net of Ni II , sheets of Ni II and Co II. Dalton Trans. 2004, 38 (2) , 260-266. https://doi.org/10.1039/B311988B
    47. Mau Sinha Ray, Ashutosh Ghosh, Ansuman Das, Michael G. B. Drew, Jordi Ribas-Ariño, Juan Novoa, Joan Ribas. A new tetrameric Cu II cluster with square topology exhibiting ferro- and antiferromagnetic magnetic pathways : which is which?. Chem. Commun. 2004, 126 (9) , 1102-1103. https://doi.org/10.1039/B401061B
    48. Debajyoti Ghoshal, Tapas Kumar Maji, Golam Mostafa, Saugata Sain, Tian-Huey Lu, Joan Ribas, Ennio Zangrando, Nirmalendu Ray Chaudhuri. Polymeric networks of copper( ii ) using succinate and aromatic N–N donor ligands: synthesis, crystal structure, magnetic behaviour and the effect of weak interactions on their crystal packing. Dalton Trans. 2004, 37 (11) , 1687-1695. https://doi.org/10.1039/B401738B
    49. Hong-Zhen Xie, Yue-Qing Zheng, Ke-Qin Shou. Synthesis and crystal structure of [Zn(H 2 O) 4 (C 4 H 2 O 4 )]·H 2 O. Journal of Coordination Chemistry 2003, 56 (15) , 1291-1297. https://doi.org/10.1080/00958970310001628966
    50. Sudipta Dalai, Partha Sarathi Mukherjee, Talal Mallah, Michael G.B. Drew, Nirmalendu Ray Chaudhuri. A doubly end-to-end azido bridged 1D ferromagnetic chain. Inorganic Chemistry Communications 2002, 5 (7) , 472-474. https://doi.org/10.1016/S1387-7003(02)00452-5
    51. Sudipta Dalai, Partha Sarathi Mukherjee, Michael G.B Drew, Tian-Huey Lu, Nirmalendu Ray Chaudhuri. Azido bridged two new ferromagnetic Cu(II) chains: synthesis, structure and magnetic behaviour. Inorganica Chimica Acta 2002, 335 , 85-90. https://doi.org/10.1016/S0020-1693(02)00815-0
    52. Nathalie Guillou, Sybille Pastre, Carine Livage, Gérard Férey. The first 3-D ferrimagnetic nickel fumarate with an open framework: [Ni 3 (OH) 2 (O 2 C–C 2 H 2 –CO 2 )(H 2 O) 4 ]·2H 2 O. Chem. Commun. 2002, 13 (20) , 2358-2359. https://doi.org/10.1039/B207133A
    53. Sudipta Dalai, Partha Sarathi Mukherjee, Ennio Zangrando, Francesc Lloret, Nirmalendu Ray Chaudhuri. A novel class of interpenetrated 3-D network of a dimeric cupric-tetracarboxylate unit. Journal of the Chemical Society, Dalton Transactions 2002, 112 (6) , 822. https://doi.org/10.1039/b110015g
    Download PDF
    Go to Inorganic Chemistry
    Get e-Alerts
    Get e-Alerts

    Inorganic Chemistry

    Cite this: Inorg. Chem. 2001, 40, 5, 928–931
    Click to copy citationCitation copied!
    https://doi.org/10.1021/ic000949m
    Published January 24, 2001
    Copyright © 2001 American Chemical Society
    Request reuse permissions

    Article Views

    400

    Altmetric

    -

    Citations

    53
    Learn about these metrics

    Article Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.

    Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.

    The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated.