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Steric contributions to the solid-state structures of bis(phosphine) derivatives of molybdenum carbonyl. X-ray structural studies of cis-Mo(CO)4[PPh3-nMen]2 (n = 0, 1, 2)

Cite this: Inorg. Chem. 1982, 21, 1, 294–299
Publication Date (Print):January 1, 1982
https://doi.org/10.1021/ic00131a055
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Cited By

This article is cited by 33 publications.

  1. Joseph Becica, Owen D. Glaze, Derek I. Wozniak, and Graham E. Dobereiner . Selective Isomerization of Terminal Alkenes to (Z)-2-Alkenes Catalyzed by an Air-Stable Molybdenum(0) Complex. Organometallics 2018, 37 (3) , 482-490. https://doi.org/10.1021/acs.organomet.7b00914
  2. Richard M. Mampa, Manuel A. Fernandes, and Laurence Carlton . Iron-57 NMR and Structural Study of [Fe(η5-Cp)(SnPh3)(CO)(PR3)] (PR3 = Phosphine, Phosphite). Separation of Steric and Electronic σ and π Effects. Organometallics 2014, 33 (13) , 3283-3299. https://doi.org/10.1021/om4011593
  3. Donald J. Darensbourg, Jeremy R. Andreatta, Sarah M. Stranahan and Joseph H. Reibenspies. What is the Real Steric Impact of Triphenylphosphite? Solid-State and Solution Structural Studies of cis- and trans-Isomers of M(CO)4[P(OPh)3]2 (M = Mo and W). Organometallics 2007, 26 (27) , 6832-6838. https://doi.org/10.1021/om700761q
  4. Schirin Hanf, Annie L. Colebatch, Philipp Stehr, Raúl García-Rodríguez, Evamarie Hey-Hawkins, Dominic S. Wright. An experimental and theoretical study of the coordination and donor properties of tris-2-pyridyl-phosphine ligands. Dalton Transactions 2020, 49 (16) , 5312-5322. https://doi.org/10.1039/D0DT00609B
  5. Jennifer L. Harkreader, Brian J. Frost. Solid State Structure of cis-[W(CO)4(pip)(PPh3)]. Journal of Chemical Crystallography 2019, 49 (2) , 125-129. https://doi.org/10.1007/s10870-018-0743-1
  6. Greyson W. Waldhart, Neal P. Mankad. trans -Tetracarbonylbis(triphenylphosphane-κ P )molybdenum(0). Acta Crystallographica Section E Structure Reports Online 2014, 70 (2) , m36-m36. https://doi.org/10.1107/S1600536814000300
  7. . Publications. 2014,,, 361-487. https://doi.org/10.1016/B978-0-12-801216-1.50022-4
  8. Pablo J. Baricelli, Luis G. Melean, Santiago Ricardes, Victor Guanipa, Mariandry Rodriguez, Carlos Romero, Alvaro J. Pardey, Sergio Moya, Merlin Rosales. Mo(CO)3(NCMe)(PPh3)2: Synthesis, X-ray structure and evaluation of its catalytic activity for the homogeneous hydrogenation of olefins and their mixtures. Journal of Organometallic Chemistry 2009, 694 (21) , 3381-3385. https://doi.org/10.1016/j.jorganchem.2009.06.042
  9. Olalere G. Adeyemi, Ling-Kang Liu. Electron-transfer chain catalysis in phosphine replacement reaction: Determination of relative donor capability of arylpyridylphosphines. Inorganica Chimica Acta 2007, 360 (7) , 2464-2470. https://doi.org/10.1016/j.ica.2006.12.051
  10. Martin A. Bennett, Matthew J. Byrnes, Guandolina Chung, Alison J. Edwards, Anthony C. Willis. Bis(acetylacetonato)ruthenium(II) complexes containing bulky tertiary phosphines. Formation and redox behaviour of Ru(acac)2 (PR3) (R=iPr, Cy) complexes with ethene, carbon monoxide, and bridging dinitrogen. Inorganica Chimica Acta 2005, 358 (5) , 1692-1708. https://doi.org/10.1016/j.ica.2004.07.062
  11. Jian Bao, Steven J. Geib, N.John Cooper. Facile displacement of cyclohexadienide ligand from K[Cr(η5-C6H7)(CO)3] to give crystallographically characterized trans-[Cr(CO)4(PPh3)2]. Journal of Organometallic Chemistry 2001, 631 (1-2) , 188-192. https://doi.org/10.1016/S0022-328X(01)00929-9
  12. Christina L Bergstrom, Rudy L Luck. Direct photolytic route to trans-Cr(CO)4(AsPh3)2 and crystal structures of cis-Mo(CO)4(AsPh3)2 and cis-W(CO)4(AsPh3)2. Inorganica Chimica Acta 2001, 318 (1-2) , 77-83. https://doi.org/10.1016/S0020-1693(01)00404-2
  13. Kenneth W Muir, François Y Pétillon, René Rumin, Philippe Schollhammer, Jean Talarmin. cis- and trans-Bis(1-phenyl-2,3,4,5-tetramethylphosphole)tetracarbonylmolybdenum(0), [Mo(CO)4(tmpPh)2]. Syntheses and structures. Journal of Organometallic Chemistry 2001, 622 (1-2) , 297-301. https://doi.org/10.1016/S0022-328X(00)00874-3
  14. Olaf Kühl, Steffen Blaurock, Joachim Sieler, Evamarie Hey-Hawkins. Molybdenum tetracarbonyl complexes with functionalised aminophosphine ligands: cis-[Mo(CO)4(PPh2NHR)2] (R=Ph, But)—molecular structures of PMes2NHPh (Mes=2,4,6-Me3C6H2), PPh2NHBut and cis-[Mo(CO)4(PPh2NHBut)2]. Polyhedron 2001, 20 (1-2) , 111-117. https://doi.org/10.1016/S0277-5387(00)00599-4
  15. Leeni Hirsivaara, Matti Haukka, Jouni Pursiainen. Intramolecular hydrogen bonding and cation π-interactions affecting cis–trans isomerization in tungsten hexacarbonyl derivatives of 2-pyridyldiphenylphosphane and triphenylphosphane. Inorganic Chemistry Communications 2000, 3 (10) , 508-510. https://doi.org/10.1016/S1387-7003(00)00131-3
  16. Volker Plack, Peyman Sakhaii, Matthias Freytag, Peter G. Jones, Reinhard Schmutzler. Preparation, NMR studies, and X-ray analysis of cis-L2Mo(CO)4 complexes (L=tritylated phosphines) with sterically demanding ligands. Journal of Fluorine Chemistry 2000, 101 (1) , 125-130. https://doi.org/10.1016/S0022-1139(99)00213-4
  17. Khalil J. Asali, Hani H. Awad, Gerard R. Dobson. KINETICS AND MECHANISM OF REACTIONS OF cis-(PIPERIDINE)(L)Mo(CO) 4 COMPLEXES WITH PHOSPHINES AND PHOSPHITES. Journal of Coordination Chemistry 1999, 47 (1) , 121-134. https://doi.org/10.1080/00958979908024547
  18. Viktor P. Balema, Fernando Somoza, Jr., Evamarie Hey-Hawkins. Reactions and Coordination Properties of the First Secondary Carbaboranyldiphosphane: 1,2-Bis(phenylphosphanyl)-1,2-dicarba-closo-dodecaborane(12). European Journal of Inorganic Chemistry 1998, 1998 (5) , 651-656. https://doi.org/10.1002/(SICI)1099-0682(199805)1998:5<651::AID-EJIC651>3.0.CO;2-D
  19. Khalil J Asali, Jaap P Smit, Santino Ladogana, Gerard R Dobson. Fast non-dissociative cis-to-trans isomerization in the cis-(P(O-i-Pr)3)2Cr(CO)4 intermediate. Inorganic Chemistry Communications 1998, 1 (3) , 87-89. https://doi.org/10.1016/S1387-7003(98)00022-7
  20. Christian Ganter, Lutz Brassat, Beate Ganter. Phosphanyl-Substituted Phosphaferrocenes asp,p-Chelate Ligands. Chemische Berichte 1997, 130 (12) , 1771-1776. https://doi.org/10.1002/cber.19971301211
  21. Graeme Hogarth, Tim Norman. Crystal structures of trans-[Mo(CO)4(PPh3)2] and 1,4-bis (diphenylphosphino)-2,5-difluorobenzene. Inorganica Chimica Acta 1997, 254 (1) , 167-171. https://doi.org/10.1016/S0020-1693(96)05133-X
  22. Graeme Hogarth, Tim Norman. Linking metal centres with bis(diphenylphosphino)acetylene (DPPA): Syntheses and molecular structures of [{Mo(CO)4(μ-DPPA)}2] and [{Mo(CO)3}2(μ-DPPA)3]. Polyhedron 1996, 15 (17) , 2859-2867. https://doi.org/10.1016/0277-5387(95)00568-4
  23. James A. S. Howell, Paul C. Yates, Neil F. Ashford, Denis T. Dixon, Richard Warren. Kinetics and mechanism of ligand substitution in [Cr(π-ligand)(CO) 3 ] complexes (ligand = naphthalene, pyrene, thiophene, 2,6-dimethylpyridine, or cycloheptatriene) and of fac/mer isomerization in [M(CO) 3 L 3 ](M = Cr, Mo or W; L = phosphite, phosphine or isocyanide). J. Chem. Soc., Dalton Trans. 1996, 464 (20) , 3959-3966. https://doi.org/10.1039/DT9960003959
  24. Marcus Watson, Simon Woodward, Gráinne Conole, Margalith Kessler, Georgia Sykara. A case of severe steric aggravation: X-ray structural analysis of cis-Mo(CO)4(PCy3)2 (CY = cyclo-C6H11). Polyhedron 1994, 13 (15-16) , 2455-2458. https://doi.org/10.1016/S0277-5387(00)88162-0
  25. Robert B. Jordan. Mechanismen metallorganischer Reaktionen. 1994,,, 124-174. https://doi.org/10.1007/978-3-322-92783-5_5
  26. Dubravka Matković-Čalogović, Henrika Meider, Pavica Planinić. Synthesis, characterization and crystal structures of [Mo(CO)4]2TPTA and [W(CO)4]2TPTA (TPTA = 1,4,8,11-tetrakis(methyldiphenylphosphino)-1,4,8,11-tetraazacyclotetradecane). Journal of Organometallic Chemistry 1993, 461 (1-2) , 117-125. https://doi.org/10.1016/0022-328X(93)83283-2
  27. Ivan Bernal, George M. Reisner, Gerard R. Dobson, Charles B. Dobson. Solid state structure and reactivity in solution. 8. Implications of the structure of [1,2-bis(diphenylphosphino)ethane] tetra-carbonylmolybdenum(0) to the chelate effect. Inorganica Chimica Acta 1986, 121 (2) , 199-206. https://doi.org/10.1016/S0020-1693(00)84520-X
  28. James A.S. Howell, Denis T. Dixon, John C. Kola. The solution structure and fluxional behaviour of (η4-enone)Fe(CO)2L complexes (L = phosphine, phosphite). Journal of Organometallic Chemistry 1984, 266 (1) , 69-82. https://doi.org/10.1016/0022-328X(84)80112-6
  29. James A.S. Howell, John C. Kola, Denis T. Dixon, Philip M. Burkinshaw, Marion J. Thomas. The kinetics and mechanism of diene exchange in (η4-enone) Fe(CO)2L complexes (L = phosphine, phosphite). Journal of Organometallic Chemistry 1984, 266 (1) , 83-96. https://doi.org/10.1016/0022-328X(84)80113-8
  30. Wolfdieter A. Schenk, Wolfgang Buchner. Tetracarbonyl tungsten complexes containing two different donor ligands. III. [1] 31P-NMR spectra. Inorganica Chimica Acta 1983, 70 , 189-196. https://doi.org/10.1016/S0020-1693(00)82801-7
  31. Richard J. Puddephatt, G.Michael Bancroft, Tammy Chan. Photoelectron spectra and basicity of tertiary phosphines PMenPh3−n. Inorganica Chimica Acta 1983, 73 , 83-89. https://doi.org/10.1016/S0020-1693(00)90830-2
  32. F. A. COTTON, D. J. DARENSBOURG, S. KLEIN, B. W. S. KOLTHAMMER. ChemInform Abstract: STERIC CONTRIBUTIONS TO THE SOLID-STATE STRUCTURES OF BIS(PHOSPHINE) DERIVATIVES OF MOLYBDENUM CARBONYL. X-RAY STRUCTURAL STUDIES OF CIS-MO(CO)4(PPH3-NMEN)2 (N = 0, 1, 2). Chemischer Informationsdienst 1982, 13 (15) https://doi.org/10.1002/chin.198215086
  33. Donald J. Darensbourg. Mechanistic Pathways for Ligand Substitution Processes in Metal Carbonyls. 1982,,, 113-150. https://doi.org/10.1016/S0065-3055(08)60379-2

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