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Chemical and structural characterization of W(CO)5OPPh2NPPh3. A novel tungsten carbonyl complex containing a phosphine oxide ligand derived from the bis(triphenylphosphine)nitrogen(1+) cation

Cite this: Inorg. Chem. 1986, 25, 19, 3537–3541
Publication Date (Print):September 1, 1986
https://doi.org/10.1021/ic00239a047
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    Cited By

    This article is cited by 8 publications.

    1. Donald J. Darensbourg,, Monica L. Meckfessel Jones, and, Joseph H. Reibenspies. The Reversible Insertion Reaction of Carbon Dioxide with the W(CO)5OH- Anion. Isolation and Characterization of the Resulting Bicarbonate Complex [PPN][W(CO)5O2COH]. Inorganic Chemistry 1996, 35 (15) , 4406-4413. https://doi.org/10.1021/ic9516525
    2. Jessica Q. Geisenhoff, Hang Yin, Natacha Oget, Haeun Chang, Linfeng Chen, Alina M. Schimpf. Controlled CO labilization of tungsten carbonyl precursors for the low-temperature synthesis of tungsten diselenide nanocrystals. Frontiers in Nanotechnology 2022, 4 https://doi.org/10.3389/fnano.2022.1026635
    3. Nicolas J. Rahier, Jean-Noël Volle, Marie Agnès Lacour, Marc Taillefer. Reactivity of Ph3PNLi towards PIII and PV electrophiles. Tetrahedron 2008, 64 (28) , 6645-6650. https://doi.org/10.1016/j.tet.2008.05.019
    4. Julian B. Cook, Brian K. Nicholson, Derek W. Smith. A structural, spectroscopic and theoretical study of the triphenylphosphine chalcogenide complexes of tungsten carbonyl, [W(XPPh3)(CO)5], X=O, S, Se. Journal of Organometallic Chemistry 2004, 689 (4) , 860-869. https://doi.org/10.1016/j.jorganchem.2003.12.016
    5. Simon Woodward. Carbonyl Complexes of Noncarbon σ-Bonded Ligands of Chromium, Molybdenum and Tungsten. 1995, 215-280. https://doi.org/10.1016/B978-008046519-7.00041-1
    6. P. Planinić, H. Meider. Synthesis and characterization of molybdenum(0) and tungsten(0) carbonyl derivatives of methylenebis[diphenylphosphine oxide] and bis[(diphenylphosphinyl)methyl]phenylphosphine Oxide. Polyhedron 1989, 8 (5) , 627-632. https://doi.org/10.1016/S0277-5387(00)83824-3
    7. P.L. Gaus, Lisa M. Jones, Loretta A. Zamiska. Reaction of the hydrido-bridged, group 6 metal carbonyl dimers with organic alkoxides. An apparent beta-hydride elimination reaction pertinent to catalysis. Polyhedron 1989, 8 (5) , 653-657. https://doi.org/10.1016/S0277-5387(00)83828-0
    8. D. J. DARENSBOURG, M. PALA, D. SIMMONS, A. L. RHEINGOLD. ChemInform Abstract: Chemical and Structural Characterization of W(CO)5OPPh2NPPh3. A Novel Complex Containing a Phosphine Oxide Ligand Derived from the Bis(triphenylphosphine)nitrogen(1+) Cation.. ChemInform 1987, 18 (3) https://doi.org/10.1002/chin.198703269

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