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Pressure-Responsive Curvature Change of a “Rigid” Geodesic Ligand in a (3,24)-Connected Mesoporous Metal–Organic Framework

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    Pressure-Responsive Curvature Change of a “Rigid” Geodesic Ligand in a (3,24)-Connected Mesoporous Metal–Organic Framework
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    † Department of Chemistry, Texas A&M University, College Station, Texas 77843, United States
    ‡ Chemical Sciences and Engineering Division, Argonne National Laboratory, 9700 S. Cass Avenue, Argonne, Illinois 60439, United States
    E-mail: [email protected]
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    Inorganic Chemistry

    Cite this: Inorg. Chem. 2011, 50, 21, 10528–10530
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    https://doi.org/10.1021/ic201744n
    Published September 26, 2011
    Copyright © 2011 American Chemical Society
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    Abstract

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    A (3,24)-connected mesoporous metal–organic framework, PCN-69, was synthesized by linking a hexatopic ligand btti with dicopper paddlewheel clusters. This material has rigid connectivity but a flexible framework, which has been attributed to a curvature change of the ligand.

    Copyright © 2011 American Chemical Society

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    Crystallographic data for PCN-69 and experimental details. This material is available free of charge via the Internet at http://pubs.acs.org.

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    Cite this: Inorg. Chem. 2011, 50, 21, 10528–10530
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    https://doi.org/10.1021/ic201744n
    Published September 26, 2011
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