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Download Hi-Res ImageDownload to MS-PowerPointCite This:Inorg. Chem. 2013, 52, 5, 2274-2276
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Heteronuclear RuIIAgI Complexes Having a Pyrroloquinolinequinone Derivative as a Bridging Ligand

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† Department of Chemistry, University of Tsukuba, 1-1-1 Tennoudai, Tsukuba, Ibaraki 305-8571, Japan
‡ Institute for Materials Chemistry and Engineering, Kyushu University, Motooka, Nishi-Ku, Fukuoka 819-0395, Japan
*E-mail: [email protected]
Cite this: Inorg. Chem. 2013, 52, 5, 2274–2276
Publication Date (Web):February 19, 2013
https://doi.org/10.1021/ic302617b
Copyright © 2013 American Chemical Society
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Abstract

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Herein, we report the synthesis of a novel heterohexanuclear complex (1) of a heteroaromatic cofactor, pyrroloquinolinequinone (PQQ). The crystal structure of 1 was determined to reveal that two PQQ-bridged RuIIAgI units were linked by two [AgI(OTf)2]− units (OTf = CF3SO3–). A solvent-bound RuIIAgI heterodinuclear complex (2) was formed from 1 in a coordinating solvent such as acetone to show an intense metal-to-ligand charge-transfer band at 709 nm.

Supporting Information

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Crystallographic data of 1 in CIF format, crystal packing of 1, 1H NMR spectrum of 2, ESI-MS spectrum and CV and DPV of 2, ESR spectrum of 1e–-reduced 2, and the details of the DFT studies of 2. This material is available free of charge via the Internet at http://pubs.acs.org.

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Cited By

This article is cited by 7 publications.

  1. Henning Lumpe, Lena J. Daumann. Studies of Redox Cofactor Pyrroloquinoline Quinone and Its Interaction with Lanthanides(III) and Calcium(II). Inorganic Chemistry 2019, 58 (13) , 8432-8441. https://doi.org/10.1021/acs.inorgchem.9b00568
  2. Alex McSkimming, Thibault Cheisson, Patrick J. Carroll, and Eric J. Schelter . Functional Synthetic Model for the Lanthanide-Dependent Quinoid Alcohol Dehydrogenase Active Site. Journal of the American Chemical Society 2018, 140 (4) , 1223-1226. https://doi.org/10.1021/jacs.7b12318
  3. Henning Lumpe, Peter Mayer, Lena J. Daumann. Crystal structure of a calcium(II)–pyrroloquinoline quinone (PQQ) complex outside a protein environment. Acta Crystallographica Section C Structural Chemistry 2020, 76 (12) , 1051-1056. https://doi.org/10.1107/S2053229620014278
  4. Henning Lumpe, Annika Menke, Christoph Haisch, Peter Mayer, Anke Kabelitz, Kirill V. Yusenko, Ana Guilherme Buzanich, Theresa Block, Rainer Pöttgen, Franziska Emmerling, Lena J. Daumann. The Earlier the Better: Structural Analysis and Separation of Lanthanides with Pyrroloquinoline Quinone. Chemistry – A European Journal 2020, 26 (44) , 10133-10139. https://doi.org/10.1002/chem.202002653
  5. Lena J. Daumann. Essenziell und weitverbreitet: Lanthanoid‐Metalloproteine. Angewandte Chemie 2019, 131 (37) , 12926-12933. https://doi.org/10.1002/ange.201904090
  6. Lena J. Daumann. Essential and Ubiquitous: The Emergence of Lanthanide Metallobiochemistry. Angewandte Chemie International Edition 2019, 58 (37) , 12795-12802. https://doi.org/10.1002/anie.201904090
  7. Hiroumi Mitome, Tomoya Ishizuka, Yoshihito Shiota, Kazunari Yoshizawa, Takahiko Kojima. Controlling the redox properties of a pyrroloquinolinequinone (PQQ) derivative in a ruthenium( ii ) coordination sphere. Dalton Transactions 2015, 44 (7) , 3151-3158. https://doi.org/10.1039/C4DT03358B

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