ACS Publications. Most Trusted. Most Cited. Most Read
My Activity

Synthesis, Crystal Structure, and Solid-State NMR Investigations of Heteronuclear Zn/Co Coordination Networks — A Comparative Study

View Author Information
Universität Leipzig, Fakultät für Physik und Geowissenschaften, Linnéstr. 5, D-04103, Germany
Universität Leipzig, Fakultät für Chemie und Mineralogie, Johannisallee 29, D-04103, Germany
§ Universitè de Lyon, Centre de RMN à très hauts champs, CNRS/ENS Lyon/UCBL, 5 Rue de la Doua, 69100 Villeurbanne, France
Institut für Nichtklassische Chemie e. V., Permoserstr.15, D-04318, Germany
Department of Physics & Astronomy, University College London, Gower Street, London, United Kingdom
Cite this: Inorg. Chem. 2013, 52, 8, 4431–4442
Publication Date (Web):April 1, 2013
Copyright © 2013 American Chemical Society

    Article Views





    Other access options
    Supporting Info (1)»


    Abstract Image

    Synthesis and solid-state NMR characterization of two isomorphous series of zinc and cobalt coordination networks with 1,2,4-triazolyl benzoate ligands are reported. Both series consist of 3D diamondoid networks with four-fold interpenetration. Solid-state NMR identifies the metal coordination of the ligands, and assignment of all 1H and 13C shifts was enabled by the combination of 13C editing, FSLG-HETCOR spectra, and 2D 1H–1H back-to-back (BABA) spectra with results from NMR-CASTEP calculations. The incorporation of Co2+ replacing Zn2+ ions in the MOF over the full range of concentrations has significant influences on the NMR spectra. A uniform distribution of metal ions is documented based on the analysis of 1H T1 relaxation time measurements.

    Read this article

    To access this article, please review the available access options below.

    Get instant access

    Purchase Access

    Read this article for 48 hours. Check out below using your ACS ID or as a guest.


    Access through Your Institution

    You may have access to this article through your institution.

    Your institution does not have access to this content. You can change your affiliated institution below.

    Supporting Information

    Jump To

    IR, thermogravimetric, and temperature-dependent PXRD data and atomic coordinates of 2 are given in the Supporting Information. It also contains various CP spectra using spectral editing techniques; tables for 13C and 1H assignments; and additional 1H 1D, 13C CPMAS, 2D HETCOR, and BABA spectra. This material is available free of charge via the Internet at CCDC 852802 contains the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via

    Terms & Conditions

    Most electronic Supporting Information files are available without a subscription to ACS Web Editions. Such files may be downloaded by article for research use (if there is a public use license linked to the relevant article, that license may permit other uses). Permission may be obtained from ACS for other uses through requests via the RightsLink permission system:

    Cited By

    This article is cited by 16 publications.

    1. Hyuk Taek Kwon, Hae-Kwon Jeong, Albert S. Lee, He Seong An, and Jong Suk Lee . Heteroepitaxially Grown Zeolitic Imidazolate Framework Membranes with Unprecedented Propylene/Propane Separation Performances. Journal of the American Chemical Society 2015, 137 (38) , 12304-12311.
    2. Olga Lapina, Ilya Yakovlev. Nuclear Magnetic Resonance (NMR): Modern Methods. 2023, 787-812.
    3. Austin D. Ready, Shona M. Becwar, Dahee Jung, Anna Kallistova, Emily Schueller, Kierstyn P. Anderson, Rebecca Kubena, Ram Seshadri, Bradley F. Chmelka, Alexander M. Spokoyny. Synthesis and structural properties of a 2D Zn( ii ) dodecahydroxy- closo -dodecaborate coordination polymer. Dalton Transactions 2022, 51 (30) , 11547-11557.
    4. C.A. Klug, M.W. Swift, J.B. Miller, J.L. Lyons, A. Albert, M. Laskoski, C.M. Hangarter. High resolution solid state NMR in paramagnetic metal-organic frameworks. Solid State Nuclear Magnetic Resonance 2022, 120 , 101811.
    5. Mao-Long Chen, Zhen-Li Qi, Wan-Ting Jin, Zhou Xu, Yun-Hui Cheng, Zhao-Hui Zhou. Cation exchange in a fluorescent zinc-based metal–organic framework for cadmium ion detection. CrystEngComm 2021, 23 (42) , 7442-7449.
    6. Alejandro Enríquez-Cabrera, Lucie Routaboul, Lionel Salmon, Azzedine Bousseksou. Complete post-synthetic modification of a spin crossover complex. Dalton Transactions 2019, 48 (45) , 16853-16856.
    7. Marko Bertmer. Paramagnetic solid-state NMR of materials. Solid State Nuclear Magnetic Resonance 2017, 81 , 1-7.
    8. Bryan E. G. Lucier, Yue Zhang, Yining Huang. Complete multinuclear solid‐state NMR of metal‐organic frameworks: The case of α‐Mg‐formate. Concepts in Magnetic Resonance Part A 2016, 45A (6)
    9. Lina Chong, Gabriel A. Goenaga, Kia Williams, Heather M. Barkholtz, Lauren R. Grabstanowicz, Jeremy A. Brooksbank, Alex B. Papandrew, Radwan Elzein, Rudiger Schlaf, Thomas A. Zawodzinski, Jianxin Zou, Shengqian Ma, Di‐Jia Liu. Investigation of Oxygen Reduction Activity of Catalysts Derived from Co and Co/Zn Methyl‐Imidazolate Frameworks in Proton Exchange Membrane Fuel Cells. ChemElectroChem 2016, 3 (10) , 1541-1545.
    10. Stephan I. Brückner, Julia Pallmann, Eike Brunner. Nuclear Magnetic Resonance of Metal-Organic Frameworks (MOFs). 2016, 607-628.
    11. Ophir Flomenbom, Larysa Baraban, Vyacheslav Misko. Commentary on the Special Issue Continuation on “Single File Dynamics and Generalizations in Interdisciplinary Sciences”. Biophysical Reviews and Letters 2016, 11 (01) , 1-8.
    12. Ying Wang, Jin-Min Yi, Meng-Yuan Zhang, Ping Xu, Xiao-Jun Zhao. I 2 -induced SC–SC transformation within two-dimensional Zn( ii )-triazole framework: an ideal detector of cyano-containing molecules. Chemical Communications 2016, 52 (15) , 3099-3102.
    13. Anusree Viswanath Kuttatheyil, Marcel Handke, Jens Bergmann, Daniel Lässig, Jörg Lincke, Jürgen Haase, Marko Bertmer, Harald Krautscheid. 113 Cd Solid‐State NMR for Probing the Coordination Sphere in Metal–Organic Frameworks. Chemistry – A European Journal 2015, 21 (3) , 1118-1124.
    14. Xiaozhou Li, Andrew D. Bond, Kristoffer E. Johansson, Jacco Van de Streek. Distinguishing tautomerism in the crystal structure of ( Z )- N -(5-ethyl-2,3-dihydro-1,3,4-thiadiazol-2-ylidene)-4-methylbenzenesulfonamide using DFT-D calculations and 13 C solid-state NMR. Acta Crystallographica Section C Structural Chemistry 2014, 70 (8) , 784-789.
    15. Charlotte Martineau, Jürgen Senker, Francis Taulelle. NMR Crystallography. 2014, 1-57.
    16. Christian Worch, Florian Kettner, Daniel Lässig, Jörg Lincke, Harald Krautscheid, Roger Gläser. Tuning the catalytic activity of the heteronuclear coordination polymers [CoxZn1−x(tdc)(bipy)] and [CoxZn1−x(Me2trz–pba)2] in the epoxidation of cyclooctene via isomorphous substitution. Catalysis Communications 2014, 44 , 46-49.

    Pair your accounts.

    Export articles to Mendeley

    Get article recommendations from ACS based on references in your Mendeley library.

    Pair your accounts.

    Export articles to Mendeley

    Get article recommendations from ACS based on references in your Mendeley library.

    You’ve supercharged your research process with ACS and Mendeley!

    STEP 1:
    Click to create an ACS ID

    Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

    Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

    Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

    Your Mendeley pairing has expired. Please reconnect