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An Unprecedented Decanuclear GdIII Cluster for Magnetic Refrigeration

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Download Hi-Res ImageDownload to MS-PowerPointCite This:Inorg. Chem. 2013, 52, 16, 9163-9165
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    An Unprecedented Decanuclear GdIII Cluster for Magnetic Refrigeration
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    † Department of Chemistry, TKL of Metal- and Molecule-Based Material Chemistry and Synergetic Innovation Center of Chemical Science and Engineering (Tianjin), Nankai University, Tianjin 300071, China
    ‡ College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China
    § School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275, China
    *E-mail: [email protected]. Fax: +86-22-23502458.
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    Inorganic Chemistry

    Cite this: Inorg. Chem. 2013, 52, 16, 9163–9165
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    https://doi.org/10.1021/ic400487m
    Published July 29, 2013
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    Abstract

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    An unprecedented decanuclear GdIII cluster composed of the [Gd10(μ3-OH)8]22+ core has been hydrothermally synthesized. Magnetic analyses indicate that this complex shows weak antiferromagnetic behavior with a relatively large magnetocaloric effect (−ΔSmmax = 31.22 J kg–1 K–1).

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    Crystallographic details (CIF), experimental section, supplementary tables, structural figures and scheme, and additional characterizations. This material is available free of charge via the Internet at http://pubs.acs.org.

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    Cite this: Inorg. Chem. 2013, 52, 16, 9163–9165
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    Published July 29, 2013
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