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Continuous and discontinuous thermochromism of copper(II) and nickel(II) complexes with N,N-diethylethylenediamine
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    Continuous and discontinuous thermochromism of copper(II) and nickel(II) complexes with N,N-diethylethylenediamine
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    Inorganic Chemistry

    Cite this: Inorg. Chem. 1974, 13, 12, 3019–3021
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    https://doi.org/10.1021/ic50142a049
    Published December 1, 1974

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    This article is cited by 50 publications.

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    5. Victor N. Khrustalev, Svetlana O. Kostenko, Mikhail I. Buzin, Alexander A. Korlyukov, Yan V. Zubavichus, Michael A. Kurykin, and Mikhail Yu. Antipin . Highly Flexible Molecule “Chameleon”: Reversible Thermochromism and Phase Transitions in Solid Copper(II) Diiminate Cu[CF3—C(NH)—CF═C(NH)—CF3]2. Inorganic Chemistry 2012, 51 (20) , 10590-10602. https://doi.org/10.1021/ic300814w
    6. Fabio Parmeggiani and Alessandro Sacchetti . Preparation and Luminescence Thermochromism of Tetranuclear Copper(I)–Pyridine–Iodide Clusters. Journal of Chemical Education 2012, 89 (7) , 946-949. https://doi.org/10.1021/ed200736b
    7. Ai-Li Cui, Xi Chen, Long Sun, Jing-Zhi Wei, Jin Yang, and Hui-Zhong Kou . Preparation and Thermochromic Properties of Copper(II)-N,N-Diethylethylenediamine Complexes. Journal of Chemical Education 2011, 88 (3) , 311-312. https://doi.org/10.1021/ed100103a
    8. Natalie Baho and, Davit Zargarian. Diphenyl(dipyrazolyl)methane Complexes of Ni:  Synthesis, Structural Characterization, and Chromotropism of NiBr2 Derivatives. Inorganic Chemistry 2007, 46 (18) , 7621-7632. https://doi.org/10.1021/ic070093m
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    10. Nuggehalli M Ravindra, Samiha Hossain, Airefetalo Sadoh. Principles, properties and preparation of thermochromic materials. Material Science & Engineering International Journal 2023, 7 (3) , 146-156. https://doi.org/10.15406/mseij.2023.07.00218
    11. Hisashi Konaka, Akito Sasaki. Phase Transitions and Crystal Structures of Ni(II) Complexes Determined with X-ray Powder Diffraction Data. Crystals 2020, 10 (2) , 106. https://doi.org/10.3390/cryst10020106
    12. Jagadese J. Vittal, Hong Sheng Quah. Engineering solid state structural transformations of metal complexes. Coordination Chemistry Reviews 2017, 342 , 1-18. https://doi.org/10.1016/j.ccr.2017.03.028
    13. Bhumika Agrahari, Samaresh Layek, Shweta Kumari, Anuradha, Rakesh Ganguly, Devendra D. Pathak. Synthesis, characterization and crystal structure of Cu(II) complex of trans-cyclohexane-1,2-diamine: Application in synthesis of symmetrical biaryls. Journal of Molecular Structure 2017, 1134 , 85-90. https://doi.org/10.1016/j.molstruc.2016.12.053
    14. Sergey S. Bukalov, Rinat R. Aysin, Larissa A. Leites, Mikhail A. Kurykin, Victor N. Khrustalev. Non-rigid molecule of copper(II) diiminate Cu[CF3C(NH)C(F)C(NH)CF3]2, its conformational polymorphism in crystal and structure in solutions (Raman, UV–vis and quantum chemistry study). Journal of Molecular Structure 2015, 1098 , 246-254. https://doi.org/10.1016/j.molstruc.2015.06.002
    15. Mainak Ganguly, Sudipa Panigrahi, K. R. S. Chandrakumar, Anup Kumar Sasmal, Anjali Pal, Tarasankar Pal. Ligand chain length conveys thermochromism. Dalton Transactions 2014, 43 (30) , 11624. https://doi.org/10.1039/C4DT00769G
    16. Linpo Yu, George Z. Chen. Cryo-solvatochromism in ionic liquids. RSC Adv. 2014, 4 (76) , 40281-40285. https://doi.org/10.1039/C4RA08116A
    17. Shinya Hayami, Daisuke Urakami, Shoya Sato, Yoshihiro Kojima, Katsuya Inoue, Masaaki Ohba. Structures and Dielectric Properties in Thermochromic Nickel(II) Compounds. Chemistry Letters 2009, 38 (5) , 490-491. https://doi.org/10.1246/cl.2009.490
    18. Hasan Icbudak, Ahmet Uyanik, Ahmet Bulut, Cengiz Arici, Dincer Ülkü. Synthesis, thermal, spectroscopic and structural properties of di(aqua)bis( N , N′ -dimethylethylenediamine- κ 2 N , N ′)copper(II) acesulfamate. Zeitschrift für Kristallographie 2007, 222 (8) , 432-436. https://doi.org/10.1524/zkri.2007.222.8.432
    19. Shinya Hayami, Natsuko Motokawa, Aya Shuto, Naoji Masuhara, Yasuhiro Umebayashi, Yonezo Maeda, Osamu Sato, Katsuya Inoue, Ryo Kawajiri, Yui Kumura, Takashi Okubo, Tadaoki Mitani. Hysteresis Loops in Dielectric Properties of the Thermochromic Copper(II) Compounds. Chemistry Letters 2006, 35 (10) , 1114-1115. https://doi.org/10.1246/cl.2006.1114
    20. Panče Naumov, Seik Weng Ng. Crystal structure of a dimeric copper(II) complex with N , N -diethylethylenediamine (dien): a model for the thermally and photoinduced violet forms of the bis(dien)copper(II) cation. Journal of Coordination Chemistry 2006, 59 (11) , 1307-1309. https://doi.org/10.1080/00958970500491010
    21. A. Samat, R. Guglielmetti. Chromogenic Materials, Thermochromic. 2004https://doi.org/10.1002/0471238961.2008051807180505.a01.pub2
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    23. Yusaku Suenaga, Hisashi Konaka, Takeshi Sugimoto, Takayoshi Kuroda-Sowa, Masahiko Maekawa, Megumu Munakata. Crystal structure and photo-induced property of two-dimensional silver(I) complex with 1,3,5-tris(benzylsulfanyl)benzene. Inorganic Chemistry Communications 2003, 6 (4) , 389-393. https://doi.org/10.1016/S1387-7003(02)00780-3
    24. Osamu Sato, Shinya Hayami, Yasuaki Einaga, Zhong-Ze Gu. Control of the Magnetic and Optical Properties in Molecular Compounds by Electrochemical, Photochemical and Chemical Methods. Bulletin of the Chemical Society of Japan 2003, 76 (3) , 443-470. https://doi.org/10.1246/bcsj.76.443
    25. Subratanath Koner, Masaru Tsutake, Isoroku Nagasawa, Ryuichi Ikeda, Pratap K. Saha, Alok K. Mukherjee, Surajit Banerjee. Thermochromism in nickel(II) complexes: thermal, solid state 1H NMR and single crystal X-ray analysis of bis-(N,N-dimethyl-1,2-ethanediamine) nickel(II) perchlorate. Journal of Molecular Structure 2002, 608 (1) , 63-69. https://doi.org/10.1016/S0022-2860(01)00930-9
    26. Charles B. Greenberg. Chromogenic Materials, Thermochromic. 2000https://doi.org/10.1002/0471238961.2008051807180505.a01
    27. Saied M. E. Khalil. CHROMOTROPIC CHANGES OF Cu(II) AND Ni(II) COMPLEXES WITH N 2 O 2 AND N 3 O 2 SCHIFF-BASE LIGANDS IN THE SOLID PHASE. Journal of Coordination Chemistry 2000, 52 (1) , 73-86. https://doi.org/10.1080/00958970008024564
    28. B Narayanan, M.M Bhadbhade. Structural studies on Cu(N,N-dialkyldiamine)2X2 complexes: X-ray structure of bis(N-isopropyl-1,2-ethanediamine) copper(II)tetrafluroborate. Journal of Molecular Structure 2000, 516 (2-3) , 247-254. https://doi.org/10.1016/S0022-2860(99)00201-X
    29. Beena Narayanan, Mohan M. Bhadbhade. X-RAY STRUCTURE OF THERMOCHROMIC BIS ( N,N -DIETHYLETHYLENEDIAMINE)-COPPER(II)TETRAFLUOROBORATE. Journal of Coordination Chemistry 1998, 46 (1) , 115-123. https://doi.org/10.1080/00958979808047201
    30. Chandi Pariya, Kaliyamoorthy Panneerselvan, Chung-Sun Chung, Tian-Huey Lu. Syntheses, crystal structures and solid state thermochromic conversion of trans-1,2-diaminocyclohexane complexes of copper (II) perchlorate. Polyhedron 1998, 17 (15) , 2555-2561. https://doi.org/10.1016/S0277-5387(97)00475-0
    31. Chandi Pariya, Fen-Ling Liao, Sue-Lein Wang, Chung-Sun Chung. Syntheses, crystal structures and solid state thermochromism of copper(II) complexes of trans-1,2-diaminocyclohexane. Polyhedron 1998, 17 (4) , 547-554. https://doi.org/10.1016/S0277-5387(97)00339-2
    32. Akihito Nishimori, Michio Sorai, Edward A. Schmitt, David N. Hendrickson. CALORIMETRIC STUDY OF THERMOCHROMIC COMPLEXES. 2. HEAT CAPACITY AND PHASE TRANSITION OF BIS( N,N ‐DIETHYLETHYLENEDIAMINE)COPPER(II) PERCHLORATE. Journal of Coordination Chemistry 1996, 37 (1-4) , 327-340. https://doi.org/10.1080/00958979608023563
    33. Ryuichi Ikeda, Kyoko Kotani, Hiroshi Ohki, Shin'ichi Ishimaru, Ken-Ichi Okamoto, Ashutosh Ghosh. Studies on 2H NMR and single crystal X-ray diffraction of thermochromic bis (N,N-diethyl-1,2-ethanediamine) nickel(II) complexes with and without structural phase transitions. Journal of Molecular Structure 1995, 345 , 159-165. https://doi.org/10.1016/0022-2860(94)08403-5
    34. Hisako Hara, Michio Sorai. Heat capacity and phase transition of the thermochromic complex bis(1,5-diazacyclo-octane)copper(II) nitrate. Journal of Physics and Chemistry of Solids 1995, 56 (2) , 223-232. https://doi.org/10.1016/0022-3697(94)00169-3
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    Inorganic Chemistry

    Cite this: Inorg. Chem. 1974, 13, 12, 3019–3021
    Click to copy citationCitation copied!
    https://doi.org/10.1021/ic50142a049
    Published December 1, 1974

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