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Stability of organogold(III) complexes. Isolation and crystal structure of dimethylgold trifluoromethanesulfonate

Cite this: Inorg. Chem. 1977, 16, 8, 2138–2140
Publication Date (Print):August 1, 1977
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    10. . References. 2018, 241-297.
    11. . References. 2018, 403-426.
    12. Luca Rocchigiani, Julio Fernandez‐Cestau, Peter H. M. Budzelaar, Manfred Bochmann. Reductive Elimination Leading to C−C Bond Formation in Gold(III) Complexes: A Mechanistic and Computational Study. Chemistry – A European Journal 2018, 24 (35) , 8893-8903.
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    16. Michael N. Pillay, Werner E. Van Zyl. Fluoro-, Fluoroalkyl-, and Heterofluorogold Complexes. Comments on Inorganic Chemistry 2012, 33 (3-4) , 122-160.
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    18. R. Alan Aitken. Pyrolysis of Organic Derivatives of Silver and Gold. 2009
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    20. Marc A. F. Hernandez-Gruel, Jesús J. Pérez-Torrente, Miguel A. Ciriano, José A. López, Fernando J. Lahoz, Luis A. Oro. NewEarly Zirconium-Sulfido Metallaligands forLate Transition Metals; Synthesis and Reactivity of [Cptt2Zr(SH)2] and [Cptt2Zr(SH)(OTf)]. European Journal of Inorganic Chemistry 1999, 1999 (11) , 2047-2050.<2047::AID-EJIC2047>3.0.CO;2-R
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    22. Sabine Schlecht, Jörg Magull, Dieter Fenske, Kurt Dehnicke. Trimethylplatintriflat — ein vielseitiger Koordinationsbaustein. Angewandte Chemie 1997, 109 (18) , 2087-2089.
    23. S. A. Cotton. Silver and gold. 1997, 273-327.
    24. Martin Paul, Hubert Schmidbaur. Coordination Chemistry of Dimethylgold Halides with Bidentate Phosphorus and Arsenic Ligands – Revisited. Chemische Berichte 1996, 129 (1) , 77-83.
    25. M.Concepción Gimeno, Josefina Jiménez, Antonio Laguna, Mariano Laguna, Peter G. Jones, R.V. (Dick) Parish. Asymmetric monocationic and dicationic gold(II) complexes: X-ray structure of [MePh2PAuCH2PPh2CH2)2AuOH2] (ClO4)2 · 2CH2Cl2· H2O. Journal of Organometallic Chemistry 1994, 481 (1) , 37-44.
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    27. Motohiro Mizuno, Tetsuo Asaji, Daiyu Nakamura, Michiko B Inoue, Motomichi Inoue. 1H and 19F NMR Relaxations of Electroconducting Polypyrrole and Polythiophene Trifluoromethanesulfonates. Bulletin of the Chemical Society of Japan 1990, 63 (11) , 3323-3325.
    28. Geoffrey A. Lawrance. Leaving Groups on Inert Metal Complexes with Inherent or Induced Lability. 1989, 145-194.
    29. Milan Melnínk, R.V. Parish. Classification and analysis of gold compounds on the basis of their x-ray structural and mössbauer spectroscopic data. Coordination Chemistry Reviews 1986, 70 , 157-257.
    30. H. Sutcliffe, A. Thornton. Trifluoromethanesulphonato derivatives of zirconium. Journal of Fluorine Chemistry 1985, 28 (2) , 171-182.
    31. P. Huppmann, H. Hartl, K. Seppelt. Synthese und Struktur von Au(OTeF 5 ) 3. Zeitschrift für anorganische und allgemeine Chemie 1985, 524 (5) , 26-32.
    32. R.J. Puddephatt. Gold. 1982, 765-821.
    33. Gordon K. Anderson. The Organic Chemistry of Gold. 1982, 39-114.
    34. Peter G. Jones. X-ray structural investigations of gold compounds. Gold Bulletin 1981, 14 (4) , 159-166.
    35. Michael I. Bruce. Structures of organo-transition metal complexes determined by diffraction methods. Reports appearing during 1977.. Journal of Organometallic Chemistry 1979, 167 , 361-466.
    36. H. Coutelle, R. Hüttel. Molmassen-bestimmungen und leitfähigkeits-messungen an olefin- und basen-goldchlorid-komplexen. Ein beitrag zur konstitution. Journal of Organometallic Chemistry 1978, 153 (3) , 359-368.
    37. . Concerted Two-Equivalent Processes for the Decomposition of Alkylmetals. 1978, 246-340.