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Download Hi-Res ImageDownload to MS-PowerPointCite This:Inorg. Chem. 2015, 54, 6, 2772-2779
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Synthesis and Characterization of Mid-Infrared Transparency Compounds: Acentric BaHgS2 and Centric Ba8Hg4S5Se7

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† Key Laboratory of Functional Materials and Devices for Special Environments of CAS; Xinjiang Key Laboratory of Electronic Information Materials and Devices; Xinjiang Technical Institute of Physics & Chemistry of CAS, 40-1 South Beijing Road, Urumqi 830011, China
‡ University of Chinese Academy of Sciences, Beijing 100049, China
*E-mail: [email protected]. Phone: (+86)991-3674558. Fax: (+86)991-3838957.
Cite this: Inorg. Chem. 2015, 54, 6, 2772–2779
Publication Date (Web):March 5, 2015
https://doi.org/10.1021/ic502939g
Copyright © 2015 American Chemical Society
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Abstract

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Two mid-IR transparency compounds, namely, acentric BaHgS2 (BHS) and centric Ba8Hg4S5Se7 (BHSSe), were successfully synthesized by a conventional solid-state reaction method. The space group of BHS is orthorhombic Pmc21 with [HgS4] tetrahedra and isolated dumbbell-shaped [HgS2] units, while BHSSe belongs to the orthorhombic space group Pnma with infinite isolated ∞[HgSe2(S/Se)2]4– chains. Raman spectra and thermal analysis of the titled materials were measured. In addition, their band gaps are found to be 1.93 (BHS) and 1.98 eV (BHSSe) from the measured diffuse reflectance spectra. Significantly, the powder BHS sample exhibits a good second harmonic generation (SHG) response of ∼6.5 times compared with that of reference AgGaS2 at a fundamental wavelength (2.09 μm). The calculated SHG coefficients of BHS are also reported, and the maximum result agrees well with the test observation.

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CIF files; atomic coordinates and isotropic displacement parameters, and selected bond distances and angles tables for BHS and BHSSe; EDX spectrum and data for BHSSe; Raman and IR spectra, TG and DSC curves of BHS and BHSSe; calculated dielectric function of BHS; particle size versus SHG intensity for BHS. This material is available free of charge via the Internet at http://pubs.acs.org.

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  30. Kui Wu, Xin Su, Shilie Pan, Zhihua Yang. ChemInform Abstract: Synthesis and Characterization of Mid-Infrared Transparency Compounds: Acentric BaHgS 2 and Centric Ba 8 Hg 4 S 5 Se 7 .. ChemInform 2015, 46 (22) , no-no. https://doi.org/10.1002/chin.201522006

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