Synthesis and Properties of Tetracyanamidosilicates ARE[Si(CN2)4]Click to copy article linkArticle link copied!
Abstract
Tetracyanamidosilicates of the type ARE[Si(CN2)4] with A = K, Rb, and Cs and RE = Y and La−Lu have been prepared by a solid-state metathesis reaction. The potassium compounds with RE = La−Gd crystallize orthorhombically in the space group P21212. Rubidium as well as cesium compounds crystallize tetragonally in the space group I4̅. The luminescent properties of ARE[Si(CN2)4]:Ln compounds with RE = Y, La, and Gd doped with 5 mol % Ln = Ce, Eu, or Tb were investigated. Temperature-dependent magnetic susceptibilities were measured for KGd[Si(CN2)4]. The value of the magnetic moment is 7.3 μB/Gd3+ ion, which is in line with the expected value for the [Xe]4f7 configuration of Gd3+.
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