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Synthesis and Properties of Tetracyanamidosilicates ARE[Si(CN2)4]
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    Synthesis and Properties of Tetracyanamidosilicates ARE[Si(CN2)4]
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    Institut für Anorganische Chemie, Universität Tübingen, Ob dem Himmelreich 7, D-72074 Tübingen, Germany
    Fachhochschule Münster, Labor für Angewandte Materialwissenschaft, Stegerwaldstrasse 39, D-48565 Steinfurt, Germany
    *To whom correspondence should be addressed. E-mail: [email protected] (T.J.), [email protected] (H.-J.M.).
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    Inorganic Chemistry

    Cite this: Inorg. Chem. 2010, 49, 6, 2954–2959
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    https://doi.org/10.1021/ic902498p
    Published February 16, 2010
    Copyright © 2010 American Chemical Society

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    Tetracyanamidosilicates of the type ARE[Si(CN2)4] with A = K, Rb, and Cs and RE = Y and La−Lu have been prepared by a solid-state metathesis reaction. The potassium compounds with RE = La−Gd crystallize orthorhombically in the space group P21212. Rubidium as well as cesium compounds crystallize tetragonally in the space group I4̅. The luminescent properties of ARE[Si(CN2)4]:Ln compounds with RE = Y, La, and Gd doped with 5 mol % Ln = Ce, Eu, or Tb were investigated. Temperature-dependent magnetic susceptibilities were measured for KGd[Si(CN2)4]. The value of the magnetic moment is 7.3 μB/Gd3+ ion, which is in line with the expected value for the [Xe]4f7 configuration of Gd3+.

    Copyright © 2010 American Chemical Society

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    This article is cited by 28 publications.

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    27. Jochen Glaser, Helga Bettentrup, Thomas Juestel, H.‐Juergen Meyer. ChemInform Abstract: Synthesis and Properties of Tetracyanamidosilicates ARE[Si(CN 2 ) 4 ].. ChemInform 2010, 41 (29) https://doi.org/10.1002/chin.201029018
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    Inorganic Chemistry

    Cite this: Inorg. Chem. 2010, 49, 6, 2954–2959
    Click to copy citationCitation copied!
    https://doi.org/10.1021/ic902498p
    Published February 16, 2010
    Copyright © 2010 American Chemical Society

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