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Ni2Mo3N: A New Ternary Interstitial Nitride with a Filled β-Manganese Structure

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    Ni2Mo3N: A New Ternary Interstitial Nitride with a Filled β-Manganese Structure†
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    Solid State and Structural Chemistry Unit and Materials Research Center, Indian Institute of Science, Bangalore 560 012, India
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    Inorganic Chemistry

    Cite this: Inorg. Chem. 1998, 37, 16, 4128–4130
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    https://doi.org/10.1021/ic980211t
    Published July 11, 1998
    Copyright © 1998 American Chemical Society
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    Copyright © 1998 American Chemical Society

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    †

     Contribution No. 1336 from the Solid State and Structural Chemistry Unit.

    *

    In papers with more than one author, the asterisk indicates the name of the author to whom inquiries about the paper should be addressed.

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     Solid State and Structural Chemistry Unit.

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     Materials Research Center.

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    This article is cited by 35 publications.

    1. Lev A. Sviridov, Peter D. Battle, Fernande Grandjean, Gary J. Long and Timothy J. Prior . Magnetic Ordering in Nitrides with the η-Carbide Structure, (Ni,Co,Fe)2(Ga,Ge)Mo3N. Inorganic Chemistry 2010, 49 (3) , 1133-1143. https://doi.org/10.1021/ic902069w
    2. Huamin Wang,, Wei Li, and, Minghui Zhang. New Approach to the Synthesis of Bulk and Supported Bimetallic Molybdenum Nitrides. Chemistry of Materials 2005, 17 (12) , 3262-3267. https://doi.org/10.1021/cm047735d
    3. Scott Korlann,, Brian Diaz, and, Mark E. Bussell. Synthesis of Bulk and Alumina-Supported Bimetallic Carbide and Nitride Catalysts. Chemistry of Materials 2002, 14 (10) , 4049-4058. https://doi.org/10.1021/cm011508j
    4. Sophie Hund, Oscar Gómez-Cápiro, Holger Ruland, Eva M. Heppke, Martin Lerch. Ni 2 Mo 3 N: crystal structure, thermal properties, and catalytic activity for ammonia decomposition. Zeitschrift für Naturforschung B 2024, 79 (4) , 147-153. https://doi.org/10.1515/znb-2023-0071
    5. Chenxi Zhao, Jiequan Wang, Xiao Chen, Changhai Liang. Nickel Molybdenum Bimetallic Nitrides as Efficient Catalysts for the Hydrodeoxygenation of Methyl Palmitate. European Journal of Inorganic Chemistry 2023, 26 (17) https://doi.org/10.1002/ejic.202300073
    6. Jonas Elmroth Nordlander, Marie Bermeo, Pau Ternero, David Wahlqvist, Toni Schmeida, Sara Blomberg, Maria E. Messing, Martin Ek, Julia-Maria Hübner. Mo3Ni2N Nanoparticle Generation by Spark Discharge. Materials 2023, 16 (3) , 1113. https://doi.org/10.3390/ma16031113
    7. J.J. Malpica-Maldonado, A.L. Martínez-Salazar, B. Portales-Martínez, M.A. Coronel-García, Y. Salazar-Cerda. Biocrude production by catalytic hydrothermal liquefaction of wood chips using NiMo series catalysts. International Journal of Hydrogen Energy 2022, 47 (70) , 30160-30171. https://doi.org/10.1016/j.ijhydene.2022.06.109
    8. Sang Heon Park, Soon Hyung Kang, Duck Hyun Youn. Direct One-Step Growth of Bimetallic Ni2Mo3N on Ni Foam as an Efficient Oxygen Evolution Electrocatalyst. Materials 2021, 14 (16) , 4768. https://doi.org/10.3390/ma14164768
    9. Sang Heon Park, Tae Hwan Jo, Min Hee Lee, Kenta Kawashima, C. Buddie Mullins, Hyung-Kyu Lim, Duck Hyun Youn. Highly active and stable nickel–molybdenum nitride (Ni 2 Mo 3 N) electrocatalyst for hydrogen evolution. Journal of Materials Chemistry A 2021, 9 (8) , 4945-4951. https://doi.org/10.1039/D0TA10090K
    10. Rudra Kumar, Thiruvelu Bhuvana, Ashutosh Sharma. Ammonolysis synthesis of nickel molybdenum nitride nanostructures for high-performance asymmetric supercapacitors. New Journal of Chemistry 2020, 44 (33) , 14067-14074. https://doi.org/10.1039/D0NJ01693D
    11. Samia Al Sobhi, Justin S. J. Hargreaves, Andrew L. Hector, Said Laassiri. Citrate-gel preparation and ammonia synthesis activity of compounds in the quaternary (Ni,M) 2 Mo 3 N (M = Cu or Fe) systems. Dalton Transactions 2019, 48 (44) , 16786-16792. https://doi.org/10.1039/C9DT03673C
    12. Ayesha Khan Tareen, G. Sudha Priyanga, Santosh Behara, Tiju Thomas, Minghui Yang. Mixed ternary transition metal nitrides: A comprehensive review of synthesis, electronic structure, and properties of engineering relevance. Progress in Solid State Chemistry 2019, 53 , 1-26. https://doi.org/10.1016/j.progsolidstchem.2018.11.001
    13. Denis V. Leybo, Dmitry I. Arkhipov, Konstantin L. Firestein, Denis V. Kuznetsov. Study of Chemical and Morphological Transformations during Ni2Mo3N Synthesis via an Oxide Precursor Nitration Route. Catalysts 2018, 8 (10) , 436. https://doi.org/10.3390/catal8100436
    14. Enamul Haque, M. Anwar Hossain. Elastic, magnetic, transport and electronic properties of noncentrosymmetric M2Mo3N (M = Fe, Co, Ni, Rh): A first-principles study. Journal of Alloys and Compounds 2018, 748 , 117-126. https://doi.org/10.1016/j.jallcom.2018.03.151
    15. Liangbiao Wang, Wanjun Xi, Qinglin Cheng, Kailong Zhang, Weiqiao Liu, Hengfei Qin, Tao Mei, Ao Zheng, Quanfa Zhou. A Solid-state Approach to the Synthesis of the Ternary Nitride Ni 2 Mo 3 N. Chemistry Letters 2018, 47 (1) , 20-22. https://doi.org/10.1246/cl.170916
    16. P. Höhn, R. Niewa. Nitrides of Non‐Main Group Elements. 2017, 251-359. https://doi.org/10.1002/9783527691036.hsscvol1008
    17. David Headspith, Maria Francesconi. Structural Classification of Quasi-One-Dimensional Ternary Nitrides. Inorganics 2016, 4 (4) , 37. https://doi.org/10.3390/inorganics4040037
    18. N. Bion, F. Can, J. Cook, J.S.J. Hargreaves, A.L. Hector, W. Levason, A.R. McFarlane, M. Richard, K. Sardar. The role of preparation route upon the ambient pressure ammonia synthesis activity of Ni2Mo3N. Applied Catalysis A: General 2015, 504 , 44-50. https://doi.org/10.1016/j.apcata.2014.10.030
    19. Ning Tang, Yunping Li, Yuichiro Koizumi, Akihiko Chiba. Nitriding of Co–Cr–Mo alloy in nitrogen. Materials Chemistry and Physics 2014, 145 (3) , 350-356. https://doi.org/10.1016/j.matchemphys.2014.02.023
    20. Haru Niimura, Kenji Kawashima, Keigo Inoue, Masaaki Yoshikawa, Jun Akimitsu. Superconductivity in the Ternary Boride Cr 2 Re 3 B with the β-Mn-Type Structure. Journal of the Physical Society of Japan 2014, 83 (4) , 044702. https://doi.org/10.7566/JPSJ.83.044702
    21. Xiaoqiang Fan, Huimin Zhang, Jianmei Li, Zhen Zhao, Chunming Xu, Jian Liu, Aijun Duan, Guiyuan Jiang, Yuechang Wei. Ni-Mo nitride catalysts: Synthesis and application in the ammoxidation of propane. Chinese Journal of Catalysis 2014, 35 (3) , 286-293. https://doi.org/10.1016/S1872-2067(14)60015-2
    22. Qi CHU, Jie FENG, Wenying LI, Kechang XIE. Synthesis of Ni/Mo/N catalyst and its application in benzene hydrogenation in the presence of thiophene. Chinese Journal of Catalysis 2013, 34 (1) , 159-166. https://doi.org/10.1016/S1872-2067(11)60509-3
    23. J.S.J. Hargreaves, D. Mckay. A comparison of the reactivity of lattice nitrogen in Co3Mo3N and Ni2Mo3N catalysts. Journal of Molecular Catalysis A: Chemical 2009, 305 (1-2) , 125-129. https://doi.org/10.1016/j.molcata.2008.08.006
    24. M. Zakeri, M.R. Rahimipour, A. Khanmohammadian. Mechanically activated synthesis of nanocrystalline ternary carbide Fe3Mo3C. Materials Science and Engineering: A 2008, 492 (1-2) , 311-316. https://doi.org/10.1016/j.msea.2008.05.008
    25. Zhi-Qiang Wang, Yan-Li Ma, Ming-Hui Zhang, Wei Li, Ke-Yi Tao. A novel route to the synthesis of bulk and well dispersed alumina-supported Ni2Mo3N catalysts via single-step hydrogen thermal treatment. Journal of Materials Chemistry 2008, 18 (37) , 4421. https://doi.org/10.1039/b807748g
    26. A. Gomathi. Ternary metal nitrides by the urea route. Materials Research Bulletin 2007, 42 (5) , 870-874. https://doi.org/10.1016/j.materresbull.2006.08.021
    27. Timothy J. Prior, Sophie E. Oldham, Victoria J. Couper, Peter D. Battle. Ferromagnetic Nitrides with the Filled β-Mn Structure:  Fe 2 - x M x Mo 3 N (M = Ni, Pd, Pt). Chemistry of Materials 2005, 17 (7) , 1867-1873. https://doi.org/10.1021/cm047859q
    28. Abdelouahad El-Himri, David Marrero-López, Pedro Núñez. Pt2Mo3N and PdPtMo3N: new interstitial nitrides prepared from freeze-dried precursors. Journal of Solid State Chemistry 2004, 177 (9) , 3219-3223. https://doi.org/10.1016/j.jssc.2004.06.006
    29. Brian Diaz, Stephanie J Sawhill, Denise H Bale, Rebekah Main, Diana C Phillips, Scott Korlann, Randy Self, Mark E Bussell. Hydrodesulfurization over supported monometallic, bimetallic and promoted carbide and nitride catalysts. Catalysis Today 2003, 86 (1-4) , 191-209. https://doi.org/10.1016/S0920-5861(03)00411-5
    30. Timothy J Prior, Peter D Battle. Facile synthesis of interstitial metal nitrides with the filled β-manganese structure. Journal of Solid State Chemistry 2003, 172 (1) , 138-147. https://doi.org/10.1016/S0022-4596(02)00171-8
    31. Kenichiro Hada, Junko Tanabe, Shinzo Omi, Masatoshi Nagai. Characterization of Cobalt Molybdenum Nitrides for Thiophene HDS by XRD, TEM, and XPS. Journal of Catalysis 2002, 207 (1) , 10-22. https://doi.org/10.1006/jcat.2001.3495
    32. Claus J. H. Jacobsen, J. J. Zhu, H. Lindeløv, J. Z. Jiang. Synthesis of ternary nitrides by mechanochemical alloying. J. Mater. Chem. 2002, 12 (10) , 3113-3116. https://doi.org/10.1039/B204079B
    33. K.S. Weil, P.N. Kumta, J. Grins. Revisiting a Rare Intermetallic Ternary Nitride, Ni2Mo3N: Crystal Structure and Property Measurements. Journal of Solid State Chemistry 1999, 146 (1) , 22-35. https://doi.org/10.1006/jssc.1999.8296
    34. Yan Xu. Porous and low-dimensional molybdates. Current Opinion in Solid State and Materials Science 1999, 4 (2) , 133-139. https://doi.org/10.1016/S1359-0286(99)00017-0
    35. P. S. HERLE, M. S. HEGDE, K. SOORYANARAYANA, T. N. G. ROW, G. N. SUBBANNA. ChemInform Abstract: Ni 2 Mo 3 N: A New Ternary Interstitial Nitride with a Filled β‐Manganese Structure.. ChemInform 1998, 29 (41) https://doi.org/10.1002/chin.199841011
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    Inorganic Chemistry

    Cite this: Inorg. Chem. 1998, 37, 16, 4128–4130
    Click to copy citationCitation copied!
    https://doi.org/10.1021/ic980211t
    Published July 11, 1998
    Copyright © 1998 American Chemical Society
    Request reuse permissions

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