Pair your accounts.

Export articles to Mendeley

Get article recommendations from ACS based on references in your Mendeley library.

Pair your accounts.

Export articles to Mendeley

Get article recommendations from ACS based on references in your Mendeley library.

You’ve supercharged your research process with ACS and Mendeley!

STEP 1:
Click to create an ACS ID

Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

MENDELEY PAIRING EXPIRED
Your Mendeley pairing has expired. Please reconnect
ACS Publications. Most Trusted. Most Cited. Most Read
My Activity
CONTENT TYPES

Figure 1Loading Img

Effect of Ionic Liquid Treatment on Pyrolysis Products from Bamboo

View Author Information
PETRONAS Ionic Liquid Centre and Biofuel Center, Department of Chemical Engineering, Universiti Teknologi PETRONAS, Malaysia
*Tel.: 006053687702. Fax: 006053687598. E-mail: [email protected]
Cite this: Ind. Eng. Chem. Res. 2012, 51, 5, 2280–2289
Publication Date (Web):January 24, 2012
https://doi.org/10.1021/ie2014313
Copyright © 2012 American Chemical Society

    Article Views

    1618

    Altmetric

    -

    Citations

    LEARN ABOUT THESE METRICS
    Other access options

    Abstract

    In the present work 1-butyl-3-methylimidazolium chloride (BmimCl) and 1-butyl-3-methylimidazolium acetate (BmimOAc) ionic liquids have been used for the dissolution of bamboo biomass. After dissolution the treated samples were precipitated by using water. The calorific value, CHNS content, lignin content, and proximate analysis of the untreated and precipitated material were measured. The BmimCl treated sample was found to have a higher value for calorific value, elemental percentage of carbon, and lignin content as well as fixed carbon, compared to the untreated and BmimOAc treated samples. The untreated and ionic liquid treated samples were also characterized by TGA and XRD. Low thermal stability and change in crystalline form from cellulose Type I to Type II have been observed by the dissolution and precipitation treatment. Pyrolysis–gas chromatography/mass spectrometry (Py-GC/MS) was employed to achieve fast pyrolysis of the untreated and ionic liquid treated samples of bamboo. The desirable products with respect to bio-oil, such as phenols, furans, alcohols, hydrocarbons, and aromatics are increased, while the undesirable products such as aldehydes and ketones, except for total acids, are decreased for the BmimCl treated sample.

    Read this article

    To access this article, please review the available access options below.

    Get instant access

    Purchase Access

    Read this article for 48 hours. Check out below using your ACS ID or as a guest.

    Recommended

    Access through Your Institution

    You may have access to this article through your institution.

    Your institution does not have access to this content. You can change your affiliated institution below.

    Cited By

    This article is cited by 57 publications.

    1. Chongpeng Qiu, Xuelun Zhang, You Zhang, Qi Tang, Zihui Yuan, Cornelis F. De Hoop, Jiwen Cao, Shilin Hao, Ting Liang, Feng Li, Xingyan Huang. Bamboo-Based Biofoam Adsorbents for the Adsorption of Cationic Pollutants in Wastewater: Methylene Blue and Cu(II). ACS Omega 2021, 6 (36) , 23447-23459. https://doi.org/10.1021/acsomega.1c03438
    2. Wafa Dastyar, Abdul Raheem, Ming Zhao, Wenyi Yuan, Hui Li, Zhao Jia Ting. Effects of Ionic Liquid-Assisted Pretreatment of Heavy Metal-Contaminated Biomass on the Yield and Composition of Syngas Production Using Noncatalytic and Catalytic Pyrolysis and Gasification Processes. ACS Sustainable Chemistry & Engineering 2019, 7 (22) , 18303-18312. https://doi.org/10.1021/acssuschemeng.9b03468
    3. Piyali Dhar, Ann Mary Jose, Giovanni Pilloni, Ravikrishnan Vinu. Development of Novel Imidazole–Poly(ethylene glycol) Solvent for the Conversion of Lignocellulosic Agro-Residues to Valuable Chemicals. Industrial & Engineering Chemistry Research 2019, 58 (35) , 16033-16044. https://doi.org/10.1021/acs.iecr.9b00665
    4. Wafa Dastyar, Ming Zhao, Wenyi Yuan, Hui Li, Zhao Jia Ting, Hosein Ghaedi, Hairong Yuan, Xiujin Li, Wei Wang. Effective Pretreatment of Heavy Metal-Contaminated Biomass Using a Low-Cost Ionic Liquid (Triethylammonium Hydrogen Sulfate): Optimization by Response Surface Methodology–Box Behnken Design. ACS Sustainable Chemistry & Engineering 2019, 7 (13) , 11571-11581. https://doi.org/10.1021/acssuschemeng.9b01457
    5. Enshi Liu, Mi Li, Lalitendu Das, Yunqiao Pu, Taylor Frazier, Bingyu Zhao, Mark Crocker, Arthur J. Ragauskas, Jian Shi. Understanding Lignin Fractionation and Characterization from Engineered Switchgrass Treated by an Aqueous Ionic Liquid. ACS Sustainable Chemistry & Engineering 2018, 6 (5) , 6612-6623. https://doi.org/10.1021/acssuschemeng.8b00384
    6. Florence J. V. Gschwend Agnieszka Brandt-Talbot Clementine L. Chambon Jason P. Hallett . Ultra-Low Cost Ionic Liquids for the Delignification of Biomass. 2017, 209-223. https://doi.org/10.1021/bk-2017-1250.ch009
    7. Nawoda L. Kapuge Dona, Charini P. Maladeniya, Rhett C. Smith. Reactivity of Biomass‐Derived Olefins with Elemental Sulfur: Mechanistic Insight. European Journal of Organic Chemistry 2024, 27 (14) https://doi.org/10.1002/ejoc.202301269
    8. Jieyi Wen, Jiawen Zhou, Rui Zhang, Wenqiang Ren, Jianbo Zhao, Di Cai. Current advances of the valorization technologies for heavy metal containing hyperaccumulators. Industrial Crops and Products 2024, 209 , 118051. https://doi.org/10.1016/j.indcrop.2024.118051
    9. A.S. Norfarhana, R.A. Ilyas, Norzita Ngadi, Mohd Hafiz Dzarfan Othman, Muhammad Syukri Mohamad Misenan, Mohd Nor Faiz Norrrahim. Revolutionizing lignocellulosic biomass: A review of harnessing the power of ionic liquids for sustainable utilization and extraction. International Journal of Biological Macromolecules 2024, 256 , 128256. https://doi.org/10.1016/j.ijbiomac.2023.128256
    10. . Isolation of Lignin. 2023, 12-28. https://doi.org/10.1002/9781394191666.ch2
    11. Tiantian Jiao, Shaojie Lin, Guangming Bai, Chuhan Ren, Yaqing Zhang, Xiangping Li, Huawei Zhang, Peng Liang. Study on extract-pyrolysis cascading utilization characteristics of typical biomass using imidazolium-based ionic liquids. Fuel 2023, 346 , 128279. https://doi.org/10.1016/j.fuel.2023.128279
    12. Guolan Dou, Liying Zhang. Study of the pyrolysis of ionic liquid [Bmim]Cl-pretreated mango pit at low temperature. Journal of Material Cycles and Waste Management 2023, 25 (4) , 2326-2337. https://doi.org/10.1007/s10163-023-01684-x
    13. Mohammad Eqbalpour, Amirhossein Andooz, Elaheh Kowsari, Seeram Ramakrishna, Zahra Ansari Cheshmeh, Amutha Chinnappan. A comprehensive review on how ionic liquids enhance the pyrolysis of cellulose, lignin, and lignocellulose toward a circular economy. WIREs Energy and Environment 2023, 12 (4) https://doi.org/10.1002/wene.473
    14. Ruosong Xie, Weiwei He, Guangfei Qu, HuanHuan Wu, Ziying Li, Junyan Li, Weijie Li. Low-Temperature Catalytic Pyrolysis of Cellulose to Directional Products 5-Methylfurfural by Magnetic Ionic Liquid. BioEnergy Research 2023, 16 (2) , 1108-1120. https://doi.org/10.1007/s12155-022-10494-2
    15. Hong Peng, Hongwei He, Ling Liu, Limin Shen, Guiming Fu, Yin Wan, Yuhuan Liu, Lifang Hu. Evaluation of the dissolving selectivity of ionic liquids for the three main components of bamboo powder under microwave irradiation. Industrial Crops and Products 2023, 194 , 116376. https://doi.org/10.1016/j.indcrop.2023.116376
    16. Zhen Wu, Lei Hu, Yetao Jiang, Xiaoyu Wang, Jiaxing Xu, Qingfeng Wang, Shenfang Jiang. Recent advances in the acid-catalyzed conversion of lignin. Biomass Conversion and Biorefinery 2023, 13 (1) , 519-539. https://doi.org/10.1007/s13399-020-00976-8
    17. Xinyu Lu, Xiaoli Gu. A review on lignin pyrolysis: pyrolytic behavior, mechanism, and relevant upgrading for improving process efficiency. Biotechnology for Biofuels and Bioproducts 2022, 15 (1) https://doi.org/10.1186/s13068-022-02203-0
    18. Liyang Ma, Jillian L. Goldfarb, Qiulin Ma. Enabling lower temperature pyrolysis with aqueous ionic liquid pretreatment as a sustainable approach to rice husk conversion to biofuels. Renewable Energy 2022, 198 , 712-722. https://doi.org/10.1016/j.renene.2022.08.077
    19. Zhen Wu, Fei Wang, Jiming Xu, Jun Zhang, Xinxu Zhao, Lei Hu, Yetao Jiang. Improved lignin pyrolysis over attapulgite-supported solid acid catalysts. Biomass Conversion and Biorefinery 2022, 12 (4) , 1049-1058. https://doi.org/10.1007/s13399-020-00667-4
    20. Chuanwei Zhang, Pengfei Zhang, Lianjun Cheng, Jianyong Li, Ranran Jian, Maocheng Ji, Fangyi Li. A strong, hydrophobic, transparent and biodegradable nano-lignocellulosic membrane from wheat straw by novel strategy. Journal of Cleaner Production 2022, 99 , 131879. https://doi.org/10.1016/j.jclepro.2022.131879
    21. Asma Nasrullah, Amir Sada Khan, Shahan Zeb Khan, Abrar Inayat, Taghreed M. Fagieh, Esraa M. Bakhsh, Kalsoom Akhtar, Sher Bahadar Khan, Israf Ud Din. Kinetics and thermodynamic study of Calligonum polygonoides pyrolysis using model-free methods. Process Safety and Environmental Protection 2022, 160 , 130-138. https://doi.org/10.1016/j.psep.2022.01.084
    22. Ranim Alayoubi, Omar Aboelazayem. Progress on Ionic Liquid Pre‐Treatment for Lignocellulosic Biomass Valorization into Biofuels and Bio‐Products. 2021, 343-374. https://doi.org/10.1002/9781119785439.ch9
    23. Guangming Bai, Tiantian Jiao, Chuhan Ren, Yaqing Zhang, Shiwei Wang, Xiaobin Wang, Xing Fan, Peng Liang. Study on extract-pyrolysis cascading utilization of chlorella based on green chemistry. Journal of Analytical and Applied Pyrolysis 2021, 157 , 105204. https://doi.org/10.1016/j.jaap.2021.105204
    24. Tazien Rashid, Farooq Sher, Amir Sada Khan, Ushna Khalid, Tahir Rasheed, Hafiz M.N. Iqbal, Thanabalan Murugesan. Effect of protic ionic liquid treatment on the pyrolysis products of lignin extracted from oil palm biomass. Fuel 2021, 291 , 120133. https://doi.org/10.1016/j.fuel.2021.120133
    25. Zongren Song, Qiang Yan, Meichen Xia, Xiaochen Qi, Zhiheng Zhang, Jie Wei, Dawei Fang, Xiaoxue Ma. Physicochemical properties of N-alkylpyridine trifluoroacetate ionic liquids [C Py][TFA] (n = 2–6). The Journal of Chemical Thermodynamics 2021, 155 , 106366. https://doi.org/10.1016/j.jct.2020.106366
    26. Pobitra Halder, Savankumar Patel, Sazal Kundu, Ibrahim Gbolahan Hakeem, Mojtaba Hedayati Marzbali, Biplob Pramanik, Kalpit Shah. Dissolution reaction kinetics and mass transfer during aqueous choline chloride pre-treatment of oak wood. Bioresource Technology 2021, 322 , 124519. https://doi.org/10.1016/j.biortech.2020.124519
    27. Pobitra Halder, Sazal Kundu, Savankumar Patel, Mojtaba Hedayati Marzbali, Rajarathinam Parthasarathy, Kalpit Shah. Furfural and levoglucosenone production from the pyrolysis of ionic liquid pre-treated sugarcane straw. Cellulose 2021, 28 (1) , 133-151. https://doi.org/10.1007/s10570-020-03547-2
    28. Tazien Rashid, Farooq Sher, Tahir Rasheed, Fatima Zafar, Shengfu Zhang, Thanabalan Murugesan. Evaluation of current and future solvents for selective lignin dissolution–A review. Journal of Molecular Liquids 2021, 321 , 114577. https://doi.org/10.1016/j.molliq.2020.114577
    29. Siu Hua Chang. Rice Husk and Its Pretreatments for Bio-oil Production via Fast Pyrolysis: a Review. BioEnergy Research 2020, 13 (1) , 23-42. https://doi.org/10.1007/s12155-019-10059-w
    30. Venkatesh Balan, Mingjie Jin, Bryan Ubanwa. Chemical and thermochemical methods on lignocellulosic biorefinery. 2020, 101-132. https://doi.org/10.1016/B978-0-12-818223-9.00005-9
    31. Peng Liang, Xizhuang Qin, Guangming Bai, Zexing Wu, Dekui Sun, Yaqing Zhang, Tiantian Jiao. Effects of ionic liquid pretreatment on pyrolysis characteristics of a high-sulfur bituminous coal. Fuel 2019, 258 , 116134. https://doi.org/10.1016/j.fuel.2019.116134
    32. Pobitra Halder, Sazal Kundu, Savankumar Patel, Adi Setiawan, Rob Atkin, Rajarathinam Parthasarthy, Jorge Paz-Ferreiro, Aravind Surapaneni, Kalpit Shah. Progress on the pre-treatment of lignocellulosic biomass employing ionic liquids. Renewable and Sustainable Energy Reviews 2019, 105 , 268-292. https://doi.org/10.1016/j.rser.2019.01.052
    33. Jun-Cheng Jiang, Li Li, Jia-Jia Jiang, Yan Wang, Siu-Ming Lo, Yong Pan, Xu-Hai Pan, Lei Ni. Effect of ionic liquids on the thermal decomposition process of tert-butyl peroxybenzoate (TBPB) by DSC. Thermochimica Acta 2019, 671 , 127-133. https://doi.org/10.1016/j.tca.2018.11.017
    34. Yujia Liang, Qi Han, Nolene Byrne, Lu Sun, Xungai Wang. Recyclable One-Step Extraction and Characterization of Intact Melanin from Alpaca Fibers. Fibers and Polymers 2018, 19 (8) , 1640-1646. https://doi.org/10.1007/s12221-018-8144-9
    35. Wenhao Yu, Ping Zhu, Zhiping Lei, Hengfu Shui, Shigang Kang, Zhicai Wang, Shibiao Ren, Chunxiu Pan. Study of Pyrolysis Behavior of Shenhua Coal Pretreated by Ionic Liquid 1-Ethyl-3-Methylimidazolium Acetate. International Journal of Chemical Reactor Engineering 2018, 16 (7) https://doi.org/10.1515/ijcre-2017-0244
    36. Chao Liu, Youming Li, Yi Hou. Basicity Characterization of Imidazolyl Ionic Liquids and Their Application for Biomass Dissolution. International Journal of Chemical Engineering 2018, 2018 , 1-8. https://doi.org/10.1155/2018/7501659
    37. Sanjeev Kumar, Lohit K.S. Gujjala, Rintu Banerjee. Simultaneous pretreatment and saccharification of bamboo for biobutanol production. Industrial Crops and Products 2017, 101 , 21-28. https://doi.org/10.1016/j.indcrop.2017.02.028
    38. Agnieszka Brandt-Talbot, Florence J. V. Gschwend, Paul S. Fennell, Tijs M. Lammens, Bennett Tan, James Weale, Jason P. Hallett. An economically viable ionic liquid for the fractionation of lignocellulosic biomass. Green Chemistry 2017, 19 (13) , 3078-3102. https://doi.org/10.1039/C7GC00705A
    39. Da-Wei Fang, Fang Zhang, Rui Jia, Wei-jun Shan, Li-xin Xia, Jia-zhen Yang. Physicochemical properties of [C n mim][TFA] (n = 2, 3, 4, 5, 6) ionic liquids. RSC Advances 2017, 7 (19) , 11616-11625. https://doi.org/10.1039/C7RA00197E
    40. Qian Wen, Yuzhi Wang, Kaijia Xu, Na Li, Hongmei Zhang, Qin Yang, Yigang Zhou. Magnetic solid-phase extraction of protein by ionic liquid-coated Fe@graphene oxide. Talanta 2016, 160 , 481-488. https://doi.org/10.1016/j.talanta.2016.07.031
    41. Zhi-Ping Lei, Kai Zhang, Zhi-quan Hu, Hao Zhang, Heng-Fu Shui, Shi-Biao Ren, Zhi-Cai Wang, Shi-Gang Kang, Chun-Xiu Pan. Effect of ionic liquid 1-butyl-3-methyl-imidazolium dihydrogen phosphate pretreatment on pyrolysis of Shengli lignite. Fuel Processing Technology 2016, 147 , 26-31. https://doi.org/10.1016/j.fuproc.2016.01.016
    42. Yusuf Osman Donar, Ali Sınağ. Catalytic effect of tin oxide nanoparticles on cellulose pyrolysis. Journal of Analytical and Applied Pyrolysis 2016, 119 , 69-74. https://doi.org/10.1016/j.jaap.2016.03.016
    43. Nannan Xing, Bing Dai, Xiaoxue Ma, Jie Wei, Yi Pan, Wei Guan. The molar surface Gibbs energy and prediction of surface tension of [C n py][DCA] ( n = 3, 4, 5). The Journal of Chemical Thermodynamics 2016, 95 , 21-25. https://doi.org/10.1016/j.jct.2015.11.023
    44. Nawshad Muhammad, Yanan Gao, Farasat Iqbal, Pervaiz Ahmad, Rile Ge, Umar Nishan, Abdur Rahim, Girma Gonfa, Zahoor Ullah. Extraction of biocompatible hydroxyapatite from fish scales using novel approach of ionic liquid pretreatment. Separation and Purification Technology 2016, 161 , 129-135. https://doi.org/10.1016/j.seppur.2016.01.047
    45. Nawshad Muhammad, Yanan Gao, Muhammad Irfan Khan, Zakir Khan, Abdur Rahim, Farasat Iqbal, Amir Sada khan, Jibran Iqbal. Effect of ionic liquid on thermo-physical properties of bamboo biomass. Wood Science and Technology 2015, 49 (5) , 897-913. https://doi.org/10.1007/s00226-015-0736-6
    46. Dengyu Chen, Dong Liu, Hongru Zhang, Yong Chen, Qian Li. Bamboo pyrolysis using TG–FTIR and a lab-scale reactor: Analysis of pyrolysis behavior, product properties, and carbon and energy yields. Fuel 2015, 148 , 79-86. https://doi.org/10.1016/j.fuel.2015.01.092
    47. Fei Song, Chen Xu, Wen-Yi Bao, Xiu-Li Wang, Yu-Zhong Wang. Bamboo (Neosinocalamus affinis)-based thin film, a novel biomass material with high performances. Carbohydrate Polymers 2015, 119 , 167-172. https://doi.org/10.1016/j.carbpol.2014.11.055
    48. Seema Singh, Gang Cheng, Noppadon Sathitsuksanoh, Dong Wu, Patanjali Varanasi, Anthe George, Venkatesh Balan, Xiadi Gao, Rajeev Kumar, Bruce E. Dale, Charles E. Wyman, Blake A. Simmons. Comparison of Different Biomass Pretreatment Techniques and Their Impact on Chemistry and Structure. Frontiers in Energy Research 2015, 2 https://doi.org/10.3389/fenrg.2014.00062
    49. Jiafu Zhang, Xin Zhang, Chi Li, Wenyu Zhang, Jingkun Zhang, Ruihong Zhang, Qipeng Yuan, Guangqing Liu, Gang Cheng. A comparative study of enzymatic hydrolysis and thermal degradation of corn stover: understanding biomass pretreatment. RSC Advances 2015, 5 (46) , 36999-37005. https://doi.org/10.1039/C5RA01930C
    50. Jihua Li, Yihong Wang, Xiaoyi Wei, Fei Wang, Donghui Han, Qinghuang Wang, Lingxue Kong. Homogeneous isolation of nanocelluloses by controlling the shearing force and pressure in microenvironment. Carbohydrate Polymers 2014, 113 , 388-393. https://doi.org/10.1016/j.carbpol.2014.06.085
    51. Dengyu Chen, Jianbin Zhou, Qisheng Zhang. Effects of heating rate on slow pyrolysis behavior, kinetic parameters and products properties of moso bamboo. Bioresource Technology 2014, 169 , 313-319. https://doi.org/10.1016/j.biortech.2014.07.009
    52. Haijuan Zhang, Shengda Qi, Yalei Dong, Xiaojiao Chen, Yinyin Xu, Yanhua Ma, Xingguo Chen. A sensitive colorimetric method for the determination of nitrite in water supplies, meat and dairy products using ionic liquid-modified methyl red as a colour reagent. Food Chemistry 2014, 151 , 429-434. https://doi.org/10.1016/j.foodchem.2013.11.016
    53. Jiafu Zhang, Lu Feng, Dan Wang, Ruihong Zhang, Guangqing Liu, Gang Cheng. Thermogravimetric analysis of lignocellulosic biomass with ionic liquid pretreatment. Bioresource Technology 2014, 153 , 379-382. https://doi.org/10.1016/j.biortech.2013.12.004
    54. Rebecca Garlock Ong, Shishir P. S. Chundawat, David B. Hodge, Sai Keskar, Bruce E. Dale. Linking Plant Biology and Pretreatment: Understanding the Structure and Organization of the Plant Cell Wall and Interactions with Cellulosic Biofuel Production. 2014, 231-253. https://doi.org/10.1007/978-1-4614-9329-7_14
    55. Christos K. Nitsos, Chrysa M. Mihailof, Konstantinos A. Matis, Angelos A. Lappas, Kostas S. Triantafyllidis. The Role of Catalytic Pretreatment in Biomass Valorization Toward Fuels and Chemicals. 2013, 217-260. https://doi.org/10.1016/B978-0-444-56330-9.00007-3
    56. Nawshad Muhammad, Zakaria Man, M. Azmi Bustam, M.I. Abdul Mutalib, Sikander Rafiq. Investigations of novel nitrile-based ionic liquids as pre-treatment solvent for extraction of lignin from bamboo biomass. Journal of Industrial and Engineering Chemistry 2013, 19 (1) , 207-214. https://doi.org/10.1016/j.jiec.2012.08.003
    57. Yihong Wang, Xiaoyi Wei, Jihua Li, Qinghuang Wang, Fei Wang, Lingxue Kong. Homogeneous Isolation of Nanocellulose from Cotton Cellulose by High Pressure Homogenization. Journal of Materials Science and Chemical Engineering 2013, 01 (05) , 49-52. https://doi.org/10.4236/msce.2013.15010