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Multivalence Ce and Sn Oxide Doped Materials with Controlled Porosity for Renewable Energy Applications

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Chemical Engineering and Materials Science, University of California, One Shields Avenue, Davis California 95616, United States
Department of Magnetism and Superconductivity, National Institute of Materials Physics, 105 bis Atomistilor, 077125 Magurele-Ilfov, Romania
Cite this: Ind. Eng. Chem. Res. 2014, 53, 19, 7829–7839
Publication Date (Web):April 23, 2014
https://doi.org/10.1021/ie500384t
Copyright © 2014 American Chemical Society

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    Abstract

    Multivalence Ce and Sn oxide doped materials are of critical importance in many renewable energy applications, especially in a porous form. Of special interest is the understanding of the basic properties of Ce–Sn–O nanoparticles and the effect of doping with different trivalent (Fe3+, Yb3+, Gd3+) elements, as well as developing Ce–Sn–O materials in the form of homogeneous and heterogeneous multilayers with unique properties at high temperature. We discuss various applications of nanosize metal-oxide sensors and energy conservation through improved energy efficiency such as renewable sources and fuel cells. In addition, ceria and ceria-based materials are studied for their electronic, magnetic, optical, and catalytic properties, which are important in applications such as gas sensors, heterogeneous catalysis, solid electrolyte fuel cells (SOFC), and UV-shielding application. Additionally, at the nanoscale, the surface area of metal oxide particles is dramatically increased, which not only increases oxygen exchange but also makes it easy for redox reactions.

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