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Kinetic Model for Methacrolein OxidationInfluence of Cesium and Vanadium on Heteropolyacid Catalysts CsxH3-x+y[PMo12-yVyO40]

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    Kinetic Model for Methacrolein OxidationInfluence of Cesium and Vanadium on Heteropolyacid Catalysts CsxH3-x+y[PMo12-yVyO40]
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    Institut für Chemische Technologie, Technische Universität Darmstadt, Petersenstrasse 20, 64287 Darmstadt, Germany
    BASF AG, 67056 Ludwigshafen, Germany
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    Industrial & Engineering Chemistry Research

    Cite this: Ind. Eng. Chem. Res. 1998, 37, 8, 3230–3236
    Click to copy citationCitation copied!
    https://doi.org/10.1021/ie970799w
    Published June 26, 1998
    Copyright © 1998 American Chemical Society
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    Abstract

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    A kinetic model has been developed for the heterogeneously catalyzed methacrolein oxidation, the parameters of which reflect the redox and adsorptive properties of the heteropolyacid catalysts CsxH3-x+y[PMo12-yVyO40] (x = 0, y = 0, 1; x = 1, y = 0, 1, 2). The model based on the Mars−van Krevelen mechanism describes the reaction rates of methacrolein and oxygen consumption as well as the rate of methacrylic acid and byproduct formation as a function of the methacrolein and oxygen partial pressures. Substitution of Mo by V causes a strong decrease of the ratio of reaction rate constants of reoxidation and methacrolein oxidation. The substitution of Mo by V leads to a strong decrease of the rate of consecutive methacrylic acid oxidation. Salification of the free acid by cesium provides a decrease of byproduct formation via parallel and consecutive oxidation and also a reduction of the hindrance of catalyst reoxidation caused by strong adsorption of methacrolein.

    Copyright © 1998 American Chemical Society

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    This article is cited by 30 publications.

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    27. . Oxidation Processes. 2002, 227-288. https://doi.org/10.1007/0-306-47378-X_10
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    30. S. Paul, V. Dubromez, L. Zair, M. Foumier, D. Vanhove. Control of the textural properties of cesium 12-molybdophosphate-based supports. 2000, 481-488. https://doi.org/10.1016/S0167-2991(00)80689-8
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    Cite this: Ind. Eng. Chem. Res. 1998, 37, 8, 3230–3236
    Click to copy citationCitation copied!
    https://doi.org/10.1021/ie970799w
    Published June 26, 1998
    Copyright © 1998 American Chemical Society
    Request reuse permissions

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