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Figure 1Loading Img

Rate constant for the reaction of atomic bromine with formaldehyde from 223 to 480 K

Cite this: J. Phys. Chem. 1981, 85, 13, 1896–1899
Publication Date (Print):June 1, 1981
https://doi.org/10.1021/j150613a024
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    Cited By

    This article is cited by 15 publications.

    1. Rosa Becerra, , Ian W. Carpenter and, Robin Walsh. Time-Resolved Studies of the Kinetics of the Reactions of CHO with HI and HBr:  Thermochemistry of the CHO Radical and the C−H Bond Strengths in CH2O and CHO. The Journal of Physical Chemistry A 1997, 101 (23) , 4185-4190. https://doi.org/10.1021/jp970443y
    2. Malcolm Scott, Raymond W. Walker. Addition of toluene and ethylbenzene to mixtures of H2 and O2 at 773 K. Combustion and Flame 2002, 129 (4) , 365-377. https://doi.org/10.1016/S0010-2180(02)00350-4
    3. Bj�rn Ramacher, John J. Orlando, Geoffrey S. Tyndall. Temperature-dependent rate coefficient measurements for the reaction of bromine atoms with trichloroethene, ethene, acetylene, and tetrachloroethene in air. International Journal of Chemical Kinetics 2001, 33 (3) , 198-211. https://doi.org/10.1002/1097-4601(200103)33:3<198::AID-KIN1014>3.0.CO;2-Z
    4. B. Ramacher, J. J. Orlando, G. S. Tyndall. Temperature-dependent rate coefficient measurements for the reaction of bromine atoms with a series of aldehydes. International Journal of Chemical Kinetics 2000, 32 (8) , 460-465. https://doi.org/10.1002/1097-4601(2000)32:8<460::AID-KIN2>3.0.CO;2-P
    5. I. Szilágyi, K. Imrik, S. Dóbé, T. Bérces. Kinetics of the reactions of bromine atoms with a series of aliphatic aldehydes at 298 K. Berichte der Bunsengesellschaft für physikalische Chemie 1998, 102 (1) , 79-84. https://doi.org/10.1002/bbpc.19981020110
    6. G. Yarwood, N. Peng, H. Niki. FTIR spectroscopic study of the Cl‐ and Br‐atom initiated oxidation of ethene. International Journal of Chemical Kinetics 1992, 24 (4) , 369-383. https://doi.org/10.1002/kin.550240406
    7. J.M. Nicovich, C.J. Shackelford, P.H. Wine. Kinetics of the Br2CH3CHO photochemical chain reaction. Journal of Photochemistry and Photobiology A: Chemistry 1990, 51 (2) , 141-153. https://doi.org/10.1016/1010-6030(90)87048-G
    8. Timothy J. Wallington, Loretta M. Skewes, Walter O. Siegl, Steven M. Japar. A relative rate study of the reaction of bromine atoms with a variety of organic compounds at 295 K. International Journal of Chemical Kinetics 1989, 21 (11) , 1069-1076. https://doi.org/10.1002/kin.550211108
    9. I. Barnes, V. Bastian, K. H. Becker, R. Overath, Zhu Tong. Rate constants for the reactions of Br atoms with a series of alkanes, alkenes, and alkynes in the presence of O 2. International Journal of Chemical Kinetics 1989, 21 (7) , 499-517. https://doi.org/10.1002/kin.550210703
    10. W. A. Payne, D. F. Nava, J. Brunning, L. J. Stief. Reaction of atomic bromine with acetylene and loss rate of atmospheric acetylene due to reaction with OH, Cl, O, and Br. Journal of Geophysical Research: Atmospheres 1986, 91 (D3) , 4097-4101. https://doi.org/10.1029/JD091iD03p04097
    11. H. Niki, P. D. Maker, C. M. Savage, L. P. Breitenbach. An FTIR spectroscopic study of the reactions Br + CH 3 CHO → HBr + CH 3 CO and CH 3 C(O)OO + NO 2 ⇌ CH 3 C(O)OONO 2 (PAN). International Journal of Chemical Kinetics 1985, 17 (5) , 525-534. https://doi.org/10.1002/kin.550170505
    12. Tajmeri S. A. Islam, Roger M. Marshall, Sidney W. Benson. VLPR study of the reaction Br + CH 3 CHO. International Journal of Chemical Kinetics 1984, 16 (9) , 1161-1166. https://doi.org/10.1002/kin.550160911
    13. G. Poulet, G. Laverdet, G. Le Bras. Kinetics of the reactions of atomic bromine with HO2 and HCO at 298 K. The Journal of Chemical Physics 1984, 80 (5) , 1922-1928. https://doi.org/10.1063/1.446953
    14. D. F. Nava, S. R. Bosco, L. J. Stief. Rate constant for the reaction of O(3 P ) with HBr from 221 to 455 K. The Journal of Chemical Physics 1983, 78 (5) , 2443-2448. https://doi.org/10.1063/1.445047
    15. R.A. Cox, D.W. Sheppard, M.P. Stevens. Absorption coefficients and kinetics of the BrO radical using molecular modulation. Journal of Photochemistry 1982, 19 (3) , 189-207. https://doi.org/10.1016/0047-2670(82)80022-1