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Synthesis of reactive homoleptic tellurolates of zirconium and hafnium and their conversion to terminal tellurides: a model for the first step in a molecule-to-solid transformation

Cite this: J. Am. Chem. Soc. 1992, 114, 15, 6240–6242
Publication Date (Print):July 1, 1992
https://doi.org/10.1021/ja00041a049
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    2. Alexander F. R. Kilpatrick, Jennifer C. Green, and F. Geoffrey N. Cloke . Reactivity of a Dititanium Bis(pentalene) Complex toward Heteroallenes and Main-Group Element–Element Bonds. Organometallics 2017, 36 (2) , 352-362. https://doi.org/10.1021/acs.organomet.6b00791
    3. Collin M. Kowalchuk,, Günter Schmid,, Wolfgang Meyer-Zaika,, Yining Huang, and, John F. Corrigan. Preparation, Characterization, and Condensation of Copper Tellurolate Clusters in the Pores of Periodic Mesoporous Silica MCM-41. Inorganic Chemistry 2004, 43 (1) , 173-180. https://doi.org/10.1021/ic0300868
    4. Marty W. DeGroot,, Michael W. Cockburn,, Mark S. Workentin, and, John F. Corrigan. Trialkylphosphine-Stabilized Copper−Phenyltellurolate Complexes:  From Small Molecules to Nanoclusters via Condensation Reactions. Inorganic Chemistry 2001, 40 (18) , 4678-4685. https://doi.org/10.1021/ic001260k
    5. Diem T. T. Tran and, John F. Corrigan. Synthesis and Characterization of Tris(trialkylphosphine)copper(I)trimethylsilylchalcogenolates. Organometallics 2000, 19 (24) , 5202-5208. https://doi.org/10.1021/om000624d
    6. Yuushou Nakayama,, Kouji Watanabe,, Norikazu Ueyama,, Akira Nakamura, and, Akira Harada, , Jun Okuda. Titanium Complexes Having Chelating Diaryloxo Ligands Bridged by Tellurium and Their Catalytic Behavior in the Polymerization of Ethylene. Organometallics 2000, 19 (13) , 2498-2503. https://doi.org/10.1021/om990906h
    7. Òscar González-Blanco,, Vicenç Branchadell,, Kereen Monteyne, and, Tom Ziegler. Nature and Strength of Metal−Chalcogen Multiple Bonds in High Oxidation State Complexes. Inorganic Chemistry 1998, 37 (8) , 1744-1748. https://doi.org/10.1021/ic970613l
    8. Thomas R. Cundari and, Philip D. Raby. Theoretical Estimation of Vibrational Frequencies Involving Transition Metal Compounds. The Journal of Physical Chemistry A 1997, 101 (32) , 5783-5788. https://doi.org/10.1021/jp963952t
    9. Christopher P. Gerlach,, Victor Christou, and, John Arnold. Synthesis and Reactivity of Group 4 Homoleptic Selenolates and Tellurolates:  Lewis Base Induced Conversion to Terminal and Bridging Chalcogenides. Inorganic Chemistry 1996, 35 (10) , 2758-2766. https://doi.org/10.1021/ic9600689
    10. Christopher P. Gerlach and, John Arnold. Synthesis, Structure, and Reactivity of Three-Coordinate Vanadium(III) Chalcogenolates and Vanadium(V) Chalcogenide Chalcogenolates. Inorganic Chemistry 1996, 35 (20) , 5770-5780. https://doi.org/10.1021/ic960439l
    11. Shuruthi Senthil, Seongyeon Kwon, Richard Y. Kong, Samantha N. MacMillan, Pavel Zatsepin, Michael R. Gau, Patrick J. Carroll, Mu-Hyun Baik, Kyle M. Lancaster, Daniel J. Mindiola. Tellurolate: an effective Te-atom transfer reagent to prepare the triad of group 5 metal bis(tellurides). Chemical Science 2023, 14 (43) , 12277-12282. https://doi.org/10.1039/D3SC03470D
    12. Vimal K. Jain, Rohit Singh Chauhan. Metal–Chalcogenolates: Synthesis and Applications in Material Chemistry. 2023, 58-82. https://doi.org/10.1039/BK9781839167386-00058
    13. Vimal K. Jain, G. Kedarnath. Applications of metal selenium/tellurium compounds in materials science. Physical Sciences Reviews 2019, 4 (5) https://doi.org/10.1515/psr-2017-0127
    14. Alexander M. Polgar, John F. Corrigan. Recent advances in the self-assembly of polynuclear metal–selenium and –tellurium compounds from 14–16 reagents. Physical Sciences Reviews 2019, 4 (2) https://doi.org/10.1515/psr-2017-0126
    15. Christine Neuhausen, Martin Panthöfer, Wolfgang Tremel. Cs 3 UP 2 S 8 , a Coordination Polymer Containing the Unprecedented [U=S] 2+ Sulfidouranium(2+) Moiety. Zeitschrift für anorganische und allgemeine Chemie 2013, 639 (5) , 728-732. https://doi.org/10.1002/zaac.201200562
    16. Ernesto Schulz Lang, Davi Fernando Back, Gelson Manzoni de Oliveira. On the search of size- and shape-controlled metal chalcogenide cluster compounds. Journal of Organometallic Chemistry 2010, 695 (17) , 1966-1971. https://doi.org/10.1016/j.jorganchem.2010.05.002
    17. Uriah J. Kilgore, Jonathan A. Karty, Maren Pink, Xinfeng Gao, Daniel J. Mindiola. Tellus in, Tellus out: The Chemistry of the Vanadium Bis(telluride) Functionality. Angewandte Chemie 2009, 121 (13) , 2430-2433. https://doi.org/10.1002/ange.200806022
    18. Uriah J. Kilgore, Jonathan A. Karty, Maren Pink, Xinfeng Gao, Daniel J. Mindiola. Tellus in, Tellus out: The Chemistry of the Vanadium Bis(telluride) Functionality. Angewandte Chemie International Edition 2009, 48 (13) , 2394-2397. https://doi.org/10.1002/anie.200806022
    19. Wayne A. Chomitz, John Arnold. Reactivity of a Co(i) [N2P2] complex with azides: evidence for a transient Co(iii) imido species. Chemical Communications 2008, 103 (31) , 3648. https://doi.org/10.1039/b804754e
    20. E. Hollink, D.W. Stephan. Zirconium and Hafnium. 2003, 105-173. https://doi.org/10.1016/B0-08-043748-6/03029-2
    21. Lisa K. Knight, Warren E. Piers, Robert McDonald. Bimolecular Extrusion of TeR 2 from β-Diketiminato Supported Scandium Bis-tellurolates. Chemistry – A European Journal 2000, 6 (23) , 4322-4326. https://doi.org/10.1002/1521-3765(20001201)6:23<4322::AID-CHEM4322>3.0.CO;2-0
    22. Ajai K. Singh, Shivadhar Sharma. Recent developments in the ligand chemistry of tellurium. Coordination Chemistry Reviews 2000, 209 (1) , 49-98. https://doi.org/10.1016/S0010-8545(99)00236-2
    23. Igor D Sadekov, A V Zakharov. Stable tellurols and their metal derivatives. Russian Chemical Reviews 1999, 68 (11) , 909-923. https://doi.org/10.1070/RC1999v068n11ABEH000544
    24. John F. Corrigan, Dieter Fenske. New Copper Telluride Clusters by Light‐Induced Tellurolate–Telluride Conversions. Angewandte Chemie International Edition in English 1997, 36 (18) , 1981-1983. https://doi.org/10.1002/anie.199719811
    25. John F. Corrigan, Dieter Fenske. Neue Kupfertellurid‐Cluster durch photoinduzierte Tellurolat‐Tellurid‐Umwandlung. Angewandte Chemie 1997, 109 (18) , 2070-2072. https://doi.org/10.1002/ange.19971091816
    26. William A. Howard, Tina M. Trnka, Marcey Waters, Gerard Parkin. Terminal chalcogenido complexes of zirconium: Syntheses and reactivity of Cp2*Zr(E)(NC5H5) (E = O, S, Se, Te). Journal of Organometallic Chemistry 1997, 528 (1-2) , 95-121. https://doi.org/10.1016/S0022-328X(96)06584-9
    27. Gerard Parkin. Terminal Chalcogenido Complexes of the Transition Metals. 1997, 1-165. https://doi.org/10.1002/9780470166482.ch1
    28. Harkesh B. Singh, Narasimhan Sudha. Organotellurium precursors for metal organic chemical vapour deposition (MOCVD) of mercury cadmium telluride (MCT). Polyhedron 1996, 15 (5-6) , 745-763. https://doi.org/10.1016/0277-5387(95)00249-X
    29. Thomas R. Cundari, Michael T. Benson, M. Leigh Lutz, Shaun O. Sommerer. Effective Core Potential Approaches to the Chemistry of the Heavier Elements. 1996, 145-202. https://doi.org/10.1002/9780470125854.ch3
    30. Mark S. Gordon, Thomas R. Cundari. Effective core potential studies of transition metal bonding, structure and reactivity. Coordination Chemistry Reviews 1996, 147 , 87-115. https://doi.org/10.1016/0010-8545(95)01133-1
    31. Sylvia M. Draper, Brendan Twamley. 2. Zirconium 1992. Coordination Chemistry Reviews 1995, 146 , A91-A140. https://doi.org/10.1016/0010-8545(95)01196-X
    32. Sylvia M. Draper, Norah Kelly. 3. Hafnium 1992. Coordination Chemistry Reviews 1995, 146 , A141-A153. https://doi.org/10.1016/0010-8545(95)01197-8
    33. Thomas R. Cundari, Yueping Li. Effective core potential modeling of Group IVA–Group IVB chemical vapor deposition. International Journal of Quantum Chemistry 1995, 55 (4) , 315-328. https://doi.org/10.1002/qua.560550403
    34. Wen‐Feng Liaw, Yih‐Chern Horng, Der‐Shiaw On, Chin‐Yuan Chuang, Chen‐Kang Lee, Gene‐Hsiang Lee, Shie‐Ming Peng. Rhenium(I) Tellurolate, Telluroether and Bidentate‐Telluroether Complexes: Crystal Structures of Re(CO) 3 Br(PhTe(CH 2 ) 3 TePh), PhTeRe(CO) 5 Re 2 (μ‐SePh) 2 (CO) 8 and [(PhTeMe)Re(CO) 5 ][BF 4 ]. Journal of the Chinese Chemical Society 1995, 42 (1) , 59-65. https://doi.org/10.1002/jccs.199500010
    35. John Arnold. The Chemistry of Metal Complexes with Selenolate and Tellurolate Ligands. 1995, 353-417. https://doi.org/10.1002/9780470166444.ch4
    36. Donna R. Gardner, James C. Fettinger, Bryan W. Eichhorn. Synthesis and Structure of [WOTe 3 ] 2−. Angewandte Chemie International Edition in English 1994, 33 (18) , 1859-1860. https://doi.org/10.1002/anie.199418591
    37. William A. Howard, Gerard Parkin. Multiple bonds between hafnium and the chalcogens: syntheses and structures of the terminal chalcogenido complexes (η15-C5Me4R)2Hf(E)(NC5 H5) (E  O, S, Se, Te). Journal of Organometallic Chemistry 1994, 472 (1-2) , c1-c4. https://doi.org/10.1016/0022-328X(94)80226-2
    38. Michael T. Benson, Thomas R. Cundari, Yueping Li, Lynn A. Strohecker. Effective core potential study of multiply bonded transition metal complexes of the heavier main group elements. International Journal of Quantum Chemistry 1994, 52 (S28) , 181-194. https://doi.org/10.1002/qua.560520819
    39. Donna R. Gardner, James C. Fettinger, Bryan W. Eichhorn. Synthese und Struktur von [WOTe 3 ] 2−. Angewandte Chemie 1994, 106 (18) , 1973-1975. https://doi.org/10.1002/ange.19941061834
    40. Matthew C. Kuchta, Gerard Parkin. Multiple bonding between germanium and the chalcogens: the syntheses and structures of the terminal chalogenido complexes (η 4 -Me 8 taa)GeE (E = S, Se, Te). J. Chem. Soc., Chem. Commun. 1994, 12 (11) , 1351-1352. https://doi.org/10.1039/C39940001351
    41. Victor Christou, John Arnold. Synthese monomerer terminaler Chalkogenide durch templatinduzierte Disilylchalkogenid‐Eliminierung; die Struktur von [ETa{(Me 3 SiNCH 2 CH 2 ) 3 N}] (E  Se, Te). Angewandte Chemie 1993, 105 (10) , 1551-1553. https://doi.org/10.1002/ange.19931051046
    42. Victor Christou, John Arnold. Formation of Monomeric Terminal Chalcogenides by Template‐Induced Disilylchalcogenide Elimination; the Crystal Structures of [ETa{(Me 3 SiNCH 2 CH 2 ) 3 N}] (E  Se, Te). Angewandte Chemie International Edition in English 1993, 32 (10) , 1450-1452. https://doi.org/10.1002/anie.199314501
    43. Wen‐Feng Liaw, Chia‐Huei Lai, Ming‐Hsi Chiang, Cheng‐Kang Hsieh, Gcne‐Hsiang Lee, Shie‐Ming Peng. Oxidative Addition vs. Ligand‐Exchange: Fe(II)‐Mixed‐Phenylchalcogenolate Complexes fac ‐[PPN][Fe(CO) 3 (TePh) n (SePh) 3‐N ] (n = 1, 2). Journal of the Chinese Chemical Society 1993, 40 (5) , 437-444. https://doi.org/10.1002/jccs.199300069
    44. Ulrich Siemeling. Tellurium—An Interesting Bonding Partner for Transition Metals: New Results from Molecular Chemistry. Angewandte Chemie International Edition in English 1993, 32 (1) , 67-68. https://doi.org/10.1002/anie.199300671
    45. Ulrich Siemeling. Tellur ‐ ein interessanter Bindungspartner für Übergangsmetalle: Neues aus der Molekülchemie. Angewandte Chemie 1993, 105 (1) , 70-71. https://doi.org/10.1002/ange.19931050109

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