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Kinetics and Mechanism of Benzene Formation from Acetylene on Pd(111) Studied by Laser-Induced Thermal Desorption/Fourier Transform Mass Spectrometry

Cite this: J. Am. Chem. Soc. 1995, 117, 37, 9509–9514
Publication Date (Print):September 1, 1995
https://doi.org/10.1021/ja00142a018
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    Cited By

    This article is cited by 33 publications.

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    2. H. Öberg, Y. Nestsiarenka, A. Matsuda, J. Gladh, T. Hansson, L. G. M. Pettersson, and H. Öström . Adsorption and Cyclotrimerization Kinetics of C2H2 at a Cu(110) Surface. The Journal of Physical Chemistry C 2012, 116 (17) , 9550-9560. https://doi.org/10.1021/jp300514f
    3. Yan-Ping Ma,, Wei Xue,, Zhe-Chen Wang,, Mao-Fa Ge, and, Sheng-Gui He. Acetylene Cyclotrimerization Catalyzed by TiO2 and VO2 in the Gas Phase:  A DFT Study. The Journal of Physical Chemistry A 2008, 112 (16) , 3731-3741. https://doi.org/10.1021/jp711027z
    4. Georgios Kyriakou,, Jisu Kim,, Mintcho S. Tikhov,, Norman Macleod, and, Richard M. Lambert. Acetylene Coupling on Cu(111):  Formation of Butadiene, Benzene, and Cyclooctatetraene. The Journal of Physical Chemistry B 2005, 109 (21) , 10952-10956. https://doi.org/10.1021/jp044213c
    5. M. Noel Rocklein,, Tyrone V. Arnold,, Christopher M. Gerth, and, Donald P. Land. The Desorption Kinetics of Flat-Lying Benzene from Palladium (111). The Journal of Physical Chemistry B 2004, 108 (3) , 1009-1013. https://doi.org/10.1021/jp036038q
    6. Ihab M. Abdelrehim,, Kalman Pelhos, and, Theodore E. Madey, , Joseph Eng, Jr. and, Jingguang G. Chen. Reaction Pathways of Acetylene on Pd/W(211):  A TPD and HREELS Investigation. The Journal of Physical Chemistry B 1998, 102 (48) , 9697-9707. https://doi.org/10.1021/jp982613s
    7. T. V. W. Janssens,, S. Völkening,, T. Zambelli, and, J. Wintterlin. Direct Observation of Surface Reactions of Acetylene on Pd(111) with Scanning Tunneling Microscopy. The Journal of Physical Chemistry B 1998, 102 (34) , 6521-6528. https://doi.org/10.1021/jp981383e
    8. Tracy E. Caldwell,, Ihab M. Abdelrehim, and, Donald P. Land. A Laser-Induced Thermal Desorption/Fourier Transform Mass Spectrometry Study of Acetylene Cyclization on S/Pd(111):  The Formation and Kinetics of Benzene, Thiophene, and 1,3-Butadiene. Langmuir 1998, 14 (6) , 1407-1410. https://doi.org/10.1021/la970775u
    9. Tracy E. Caldwell,, Ihab M. Abdelrehim, and, Donald P. Land. Preadsorbed Oxygen Atoms Affect the Product Distribution and Kinetics of Acetylene Cyclization to Benzene on Pd(111):  A Laser-Induced Thermal Desorption/Fourier Transform Mass Spectrometry Study. The Journal of Physical Chemistry B 1998, 102 (3) , 562-568. https://doi.org/10.1021/jp972409p
    10. D. C. Papageorgopoulos,, Q. Ge,, S. Nimmo, and, D. A. King. Thermal Conversion of Chemisorbed Acetylene to Vinylidene and Hydrogenation to Ethylidyne on Rh{111}:  A Laser Induced Desorption Study. The Journal of Physical Chemistry B 1997, 101 (11) , 1999-2005. https://doi.org/10.1021/jp962865y
    11. Julian R. Lomas,, Christopher J. Baddeley,, Mintcho S. Tikhov, and, Richard M. Lambert, , Gianfranco Pacchioni. Adsorption of Ethyne on Cu(110):  Experimental and Theoretical Study. Langmuir 1997, 13 (4) , 758-764. https://doi.org/10.1021/la960865j
    12. Ihab M. Abdelrehim,, Tracy E. Caldwell, and, Donald P. Land. Coverage Effects on the Kinetics of Benzene Formation from Acetylene on Pd(111):  A Laser-Induced Thermal Desorption/Fourier Transform Mass Spectrometry Investigation. The Journal of Physical Chemistry 1996, 100 (24) , 10265-10268. https://doi.org/10.1021/jp953737x
    13. Hung-Lung Chiang, Fang-Yang Wu, Pei-Hsiu Huang, Ting-Yi Lee. Characteristics of acetylene cracking on MCM-41 to form carbon materials and their exhaust emission. Microporous and Mesoporous Materials 2018, 268 , 100-108. https://doi.org/10.1016/j.micromeso.2018.04.006
    14. Yu-wei Zhang, Yong-Cheng Wang, Xiao-jun Zhang, Xiao-li Wang, Shuang Li. A theoretical study on La-activated bicyclo-oligomerization of acetylene to form naphthalene in gas phase using density functional theory (DFT). Structural Chemistry 2018, 29 (1) , 171-178. https://doi.org/10.1007/s11224-017-1016-x
    15. Zhe-Peng Deng, Yong-Cheng Wang, Jian-Wu Zhe, Yu Sun, Guang-Ming Liu, Pan-Pan Ma, Gui-Ping Niu, Neng-Zhi Jin, Yang Sheng, Hu Da. Acetylene cyclotrimerization catalyzed by PdCl2 and CuCl2 in the gas phase: A theoretical study. Computational and Theoretical Chemistry 2017, 1104 , 18-23. https://doi.org/10.1016/j.comptc.2017.01.027
    16. Victoria L. Frankland, Alexander D. James, Juan Diego Carrillo Sánchez, Thomas P. Mangan, Karen Willacy, Andrew R. Poppe, John M.C. Plane. Uptake of acetylene on cosmic dust and production of benzene in Titan's atmosphere. Icarus 2016, 278 , 88-99. https://doi.org/10.1016/j.icarus.2016.06.007
    17. Rajeeva Thilakaratne, Jean-Philippe Tessonnier, Robert C. Brown. Conversion of methoxy and hydroxyl functionalities of phenolic monomers over zeolites. Green Chemistry 2016, 18 (7) , 2231-2239. https://doi.org/10.1039/C5GC02548F
    18. Hung-Lung Chiang, Trong-Neng Wu, Yung-Shou Ho, Li-Xuan Zeng. Carbon material formation on SBA-15 and Ni-SBA-15 and residue constituents during acetylene decomposition. Journal of Hazardous Materials 2014, 276 , 43-51. https://doi.org/10.1016/j.jhazmat.2014.05.016
    19. Wilfred T. Tysoe. Catalytic Chemistry of Hydrocarbon Conversion Reactions on Metallic Single Crystals. 2010, 1-28. https://doi.org/10.1007/978-0-387-98049-2_1
    20. D. Stacchiola, F. Calaza, T. Zheng, Wilfred T. Tysoe. Hydrocarbon conversion on palladium catalysts. Journal of Molecular Catalysis A: Chemical 2005, 228 (1-2) , 35-45. https://doi.org/10.1016/j.molcata.2004.09.064
    21. S Haq, S.C Laroze, C Mitchell, N Winterton, R Raval. Chlorinated ethenes at Cu(110): adsorption, dissociation and reactions of trans-1,2-dichloroethene. Surface Science 2003, 531 (2) , 145-158. https://doi.org/10.1016/S0039-6028(03)00441-2
    22. M. Heintze, M. Magureanu. Methane Conversion into Aromatics in a Direct Plasma-Catalytic Process. Journal of Catalysis 2002, 206 (1) , 91-97. https://doi.org/10.1006/jcat.2001.3467
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    24. Donna M. Jaramillo, Deborah E. Hunka, Donald P. Land. Iodobenzene on Pd(111) studied by thermal desorption spectroscopy and laser-induced thermal desorption–Fourier transform mass spectrometry. Surface Science 2000, 445 (1) , 23-31. https://doi.org/10.1016/S0039-6028(99)01033-X
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