1,1,2-TrimethylsilaethyleneClick to copy article linkArticle link copied!
Note: In lieu of an abstract, this is the article's first page.
Cited By
This article is cited by 80 publications.
- Tao Yang, Beni B. Dangi, Pavlo Maksyutenko, and Ralf I. Kaiser , Luke W. Bertels and Martin Head-Gordon . Combined Experimental and Theoretical Study on the Formation of the Elusive 2-Methyl-1-silacycloprop-2-enylidene Molecule under Single Collision Conditions via Reactions of the Silylidyne Radical (SiH; X2Π) with Allene (H2CCCH2; X1A1) and D4-Allene (D2CCCD2; X1A1). The Journal of Physical Chemistry A 2015, 119
(50)
, 12562-12578. https://doi.org/10.1021/acs.jpca.5b09773
- Tracy L. Morkin and, William J. Leigh, , Thomas T. Tidwell and, Annette D. Allen. Direct Detection of Wiberg's Silene (1,1-Dimethyl-2,2-bis(trimethylsilyl)silene) and Absolute Rate Constants for Its Reactions in Solution. Organometallics 2001, 20
(26)
, 5707-5716. https://doi.org/10.1021/om010777g
- William J. Leigh,, Corinna Kerst,, Rabah Boukherroub,, Tracy L. Morkin,, Stephen I. Jenkins,, Kuangsen Sung, and, Thomas T. Tidwell. Substituent Effects on the Reactivity of the Silicon−Carbon Double Bond. Substituted 1,1-Dimethylsilenes from Far-UV Laser Flash Photolysis of α-Silylketenes and (Trimethylsilyl)diazomethane. Journal of the American Chemical Society 1999, 121
(20)
, 4744-4753. https://doi.org/10.1021/ja984277z
- Valery N. Khabashesku,, Konstantin N. Kudin,, Josef Tamás,, Sergei E. Boganov,, John L. Margrave, and, Oleg M. Nefedov. Transient 1,1-Dimethyl-1-germene, (CH3)2GeCH2. Gas-Phase Pyrolytic Generation and EIMS, Matrix Isolation FTIR, and Theoretical Studies. Journal of the American Chemical Society 1998, 120
(20)
, 5005-5016. https://doi.org/10.1021/ja971134o
- Eric Deydier,, Marie-Joëlle Menu,, Michèle Dartiguenave,, Yves Dartiguenave,, Michel Simard,, André L. Beauchamp,, John C. Brewer, and, Harry B. Gray. Transition Metal Diazoalkane Complexes. Synthesis, Structure, and Photochemistry of Rh[C(N2)SiMe3](PEt3)3. Organometallics 1996, 15
(4)
, 1166-1175. https://doi.org/10.1021/om950490h
- Martin Trommer and, Wolfram Sander. (Trimethoxysilyl)carbene: Photochemistry, Oxidation, and Carbonylation of a Silylcarbene. Organometallics 1996, 15
(2)
, 736-740. https://doi.org/10.1021/om950782i
- Yury V. Tomilov, Leonid G. Menchikov, Evgeny A. Shapiro, Valentin D. Gvozdev, Konstantin N. Shavrin, Nikolay V. Volchkov, Maria B. Lipkind, Mikhail P. Egorov, Sergey E. Boganov, Valery N. Khabashesku, Esfir G. Baskir. Carbenes, related intermediates, and small-sized cycles: contribution from Professor Nefedov’s laboratory. Mendeleev Communications 2021, 31
(6)
, 750-768. https://doi.org/10.1016/j.mencom.2021.11.002
- . References. 2018, 241-297. https://doi.org/10.1002/9781119404675.oth1
- M. Z. Kassaee, H. Zandi. P‐Heterocyclic silylenes: a survey of stability with density functional theory. Journal of Physical Organic Chemistry 2012, 25
(1)
, 50-57. https://doi.org/10.1002/poc.1867
- Sergei M. Korneev. Valence Isomerization between Diazo Compounds and Diazirines. European Journal of Organic Chemistry 2011, 2011
(31)
, 6153-6175. https://doi.org/10.1002/ejoc.201100224
- Michal Czyzewski, Justin Bower, Matthew Box, Henrik Ottosson, Patrick G. Steel. Silene equivalents through the rhodium-catalysed reactions of α-hypersilyl diazoesters: a computational and experimental study. Chemical Science 2011, 2
(12)
, 2367. https://doi.org/10.1039/c1sc00405k
- . Heavy Analogs of Alkenes, 1,3‐Dienes, Allenes and Alkynes: Multiply Bonded Derivatives of Si, Ge, Sn and Pb. 2010, 199-334. https://doi.org/10.1002/9780470669266.ch5
- Gerhard Maas. Silicon‐Substituted Carbenes. 2009https://doi.org/10.1002/9780470682531.pat0175
- Tracy L. Morkin, Thomas R. Owens, William J. Leigh. Kinetic Studies of the Reactions of
Si
C
and
Si
Si
Bonds. 2009https://doi.org/10.1002/9780470682531.pat0251
- Mohammad Zaman Kassaee, Farnaz Alipour Shakib, Mohammad Reza Momeni, Mehdi Ghambarian, Seyed Majid Musavi. Silabenzene through divalent precursors at theoretical levels. Monatshefte für Chemie - Chemical Monthly 2009, 140
(1)
, 33-38. https://doi.org/10.1007/s00706-008-0048-8
- Henrik Ottosson, Patrick G. Steel. Silylenes, Silenes, and Disilenes: Novel Silicon‐Based Reagents for Organic Synthesis?. Chemistry – A European Journal 2006, 12
(6)
, 1576-1585. https://doi.org/10.1002/chem.200500429
- Wolfram Sander, Martin Trommer, Andreas Patyk. Oxidation of Silenes and Silylenes: Matrix Isolation of Unusual Silicon Species. 2005, 86-94. https://doi.org/10.1002/9783527620777.ch15b
- Leonid E. Gusel'nikov. Hetero-π-systems from 2+2 cycloreversions. Part 1. Gusel'nikov–Flowers route to silenes and origination of the chemistry of doubly bonded silicon. Coordination Chemistry Reviews 2003, 244
(1-2)
, 149-240. https://doi.org/10.1016/S0010-8545(03)00104-8
- Robert West. Multiple bonds to silicon: 20 years later. Polyhedron 2002, 21
(5-6)
, 467-472. https://doi.org/10.1016/S0277-5387(01)01017-8
- V. N. Khabashesku, S. E. Boganov, K. N. Kudin, J. L. Margrave, J. Michl, O. M. Nefedov. Interconversions of the silylene-to-silene and germylene-to-germene types: direct spectroscopic studies and calculations. Russian Chemical Bulletin 1999, 48
(11)
, 2003-2015. https://doi.org/10.1007/BF02494839
- Miguel Fuentes-Cabrera, Alfonso Muñoz, Wolfgang Windl, Alexander A Demkov, Otto F Sankey. Theoretical study of graphitic analogues of simple semiconductors. Modelling and Simulation in Materials Science and Engineering 1999, 7
(6)
, 929-938. https://doi.org/10.1088/0965-0393/7/6/302
- Valery N. Khabashesku, Konstantin N. Kudin, John L. Margrave. Vibrational analysis of infrared spectra of matrix-isolated transient silenes on basis of density functional theory calculations. Journal of Molecular Structure 1998, 443
(1-3)
, 175-189. https://doi.org/10.1016/S0022-2860(97)00398-0
- Wolfram Sander, Martin Trommer, Andreas Patyk. Oxidation of Silenes and Silylenes: Matrix Isolation of Unusual Silicon Species. 1997, 86-94. https://doi.org/10.1002/9783527619900.ch15
- . Silicon. 1997, 328-366. https://doi.org/10.1016/B978-0-7506-3365-9.50015-8
- Martin Trommer, Wolfram Sander, Carl‐Henrik Ottosson, Dieter Cremer. Reaction of 1,1‐Dimethylsilene with Formaldehyde. Angewandte Chemie International Edition in English 1995, 34
(8)
, 929-931. https://doi.org/10.1002/anie.199509291
- Martin Trommer, Wolfram Sander, Carl‐Henrik Ottosson, Dieter Cremer. Reaktion von 1,1‐Dimethylsilen mit Formaldehyd. Angewandte Chemie 1995, 107
(8)
, 999-1001. https://doi.org/10.1002/ange.19951070821
- Joseph B. Sweeney. Alkyl Chalcogenides: Oxygen-based Functional Groups. 1995, 37-112. https://doi.org/10.1016/B0-08-044705-8/00250-8
- Frank S. Guziec, Lynn J. Guziec. Seleno- and Telluroaldehydes and -ketones. 1995, 381-401. https://doi.org/10.1016/B0-08-044705-8/00253-3
- Tao Ye, M. Anthony McKervey. Doubly Bonded Metalloid Functions (Si, Ge, B). 1995, 501-505. https://doi.org/10.1016/B0-08-044705-8/00279-X
- . References to Volume 3. 1995, 727-856. https://doi.org/10.1016/B0-08-044705-8/09011-7
- Victor A. Korolev, Oleg M. Nefedov. Matrix Infrared Spectroscopy of Intermediates with Low Coordinated Carbon, Silicon and Germanium Atoms. 1995, 1-61. https://doi.org/10.1016/S0065-3160(08)60032-5
- Martin Trommer, Wolfram Sander, Claudia Marquard. 1,1‐Dimethyl‐1
H
‐silirene. Angewandte Chemie International Edition in English 1994, 33
(7)
, 766-769. https://doi.org/10.1002/anie.199407661
- Martin Trommer, Wolfram Sander, Claudia Marquard. 1,1‐Dimethyl‐1
H
‐siliren. Angewandte Chemie 1994, 106
(7)
, 816-818. https://doi.org/10.1002/ange.19941060725
- Takayuki Shioiri, Toyohiko Aoyama. TRIMETHYLSILYLDIAZOMETHANE. 1993, 51-101. https://doi.org/10.1016/B978-1-4831-0094-4.50007-4
- Wolfram Sander, Martin Trommer. Oxidation of Trimethylsilene with Molecular Oxygen — a Matrix Isolation Study. Chemische Berichte 1992, 125
(12)
, 2813-2815. https://doi.org/10.1002/cber.19921251230
- Tarun K. Sarkar, Binay K. Ghorai. Silicon-directed Bamford–Stevens reaction of β-trimethylsilyl N-aziridinylimines. J. Chem. Soc., Chem. Commun. 1992, 0
(17)
, 1184-1185. https://doi.org/10.1039/C39920001184
- O. M. Nefedov. Generation, low-temperature stabilization, structure, and reactivity of intermediates with low-coordinated carbon, silicon, and germanium atoms. Bulletin of the Academy of Sciences of the USSR Division of Chemical Science 1991, 40
(11)
, 2113-2128. https://doi.org/10.1007/BF00961022
- M.Samy El-Shall. Silicon-nitrogen multiple bonding: Theoretical study of silanitriles and silaisonitriles. Chemical Physics Letters 1989, 159
(1)
, 21-26. https://doi.org/10.1016/S0009-2614(89)87446-9
- Xavier Creary, You-Xiong Wang. β-Silyl carbenes. Tetrahedron Letters 1989, 30
(19)
, 2493-2496. https://doi.org/10.1016/S0040-4039(01)80433-0
- G. Märkl, W. Schlosser, W.S. Sheldrick. Photochemische und thermische zersetzung vondiazo-2-trimethylsilyl-2-sila-3,5-cyclohexadienen. Silabenzole und silafulvene als zwischenstufen. Tetrahedron Letters 1988, 29
(4)
, 467-470. https://doi.org/10.1016/S0040-4039(00)80123-9
- Jens Oddershede, John R. Sabine, Geerd H. F. Diercksen. Stability and Conformation of Silicon-Carbon Compounds. A Case Study of SiC2, Si2C and Si3. 1987, 465-480. https://doi.org/10.1007/978-94-009-3781-9_29
- Wolfŕam W. Sander. Chemiluminescence from arylcarbene oxidation: Phenylchlorocarbene and (2-chlorophenyl)carbene. Spectrochimica Acta Part A: Molecular Spectroscopy 1987, 43
(5)
, 637-646. https://doi.org/10.1016/0584-8539(87)80146-0
- Steven S Zigler, Robert West, Josef Michl. OBSERVATION OF A SILANIMINE IN AN INERT MATRIX AND IN SOLUTION AT LOW TEMPERATURE. Chemistry Letters 1986, 15
(6)
, 1025-1028. https://doi.org/10.1246/cl.1986.1025
- MANFRED REGITZ, GERHARD MAAS. Photochemistry of Aliphatic Diazo Compounds. 1986, 166-198. https://doi.org/10.1016/B978-0-12-585840-3.50008-8
- A.G. Brook, Kim M. Baines. Silenes. 1986, 1-44. https://doi.org/10.1016/S0065-3055(08)60571-7
- Robert West. Isolable Compounds Containing a Silicon-Silicon Double Bond. Science 1984, 225
(4667)
, 1109-1114. https://doi.org/10.1126/science.225.4667.1109
- Günther Maier, Gerhard Mihm, Hans Peter Reisenauer. Hetero‐π‐Systeme, 8. Silaethen. Chemische Berichte 1984, 117
(7)
, 2351-2368. https://doi.org/10.1002/cber.19841170708
- Samih Amine Kazoura, William P. Weber. Flash vacuum pyrolysis of dimethoxymethylsilyl-bis(trimethylsilyl)amine: 1,3-Sigmatropic rearrangements of silaimine intermediates. Journal of Organometallic Chemistry 1984, 268
(1)
, 19-30. https://doi.org/10.1016/0022-328X(84)85093-7
- �. G. Baskir, A. K. Mal'tsev, O. M. Nefedov. Vibrational spectra of silaethylenes H2C=SiX2 (X=H, D, Cl). Bulletin of the Academy of Sciences of the USSR Division of Chemical Science 1983, 32
(6)
, 1186-1190. https://doi.org/10.1007/BF00953154
- Harold W. Heine. Diaziridines, 3H‐Diazirines, Diaziridinones, and Diaziridinimines. 1983, 547-628. https://doi.org/10.1002/9780470187197.ch4
- Clifford Burford, Frank Cooke, Glenn Roy, Philip Magnus. Silicon in synthesis—17. Tetrahedron 1983, 39
(6)
, 867-876. https://doi.org/10.1016/S0040-4020(01)88585-9
- Wataru Ando, Hirohide Tanikawa, Akira Sekiguchi. Ring expansion of silacyclopentadienylcarbene to silabenzene. Tetrahedron Letters 1983, 24
(39)
, 4245-4248. https://doi.org/10.1016/S0040-4039(00)88312-4
- D.A. Armitage. Organosilanes. 1982, 1-203. https://doi.org/10.1016/B978-008046518-0.00014-3
- P.D. Magnus, T. Sarkar, S. Djuric. Organosilicon Compounds in Organic Synthesis. 1982, 515-659. https://doi.org/10.1016/B978-008046518-0.00104-5
- Mark S. Baird, Sheila R. Buxton, Manjushri Mitra. Intramolecular trapping of α-alkyl-α-trimethylsilyl-carbenes (carbenoids) by addition to carboncarbon double bonds. Tetrahedron Letters 1982, 23
(26)
, 2701-2704. https://doi.org/10.1016/S0040-4039(00)87436-5
- Günther Maier, Gerhard Mihm, Hans Peter Reisenauer. Silaethen. Angewandte Chemie 1981, 93
(6-7)
, 615-616. https://doi.org/10.1002/ange.19810930637
- Günther Maier, Gerhard Mihm, Hans Peter Reisenauer. Silaethene. Angewandte Chemie International Edition in English 1981, 20
(6-7)
, 597-598. https://doi.org/10.1002/anie.198105971
- Brian Coleman, Maitland Jones. Silenes. Reviews of Chemical Intermediates 1981, 4
(1-4)
, 297-367. https://doi.org/10.1007/BF03052418
- Ernest W. Colvin. Physical properties of organosilicon compounds. 1981, 4-14. https://doi.org/10.1016/B978-0-408-10831-7.50008-1
- O.M. Nefedov, A.K. Maltsev, V.N. Khabashesku, V.A. Korolev. Ar-matrix stabilization and ir spectra of 1,1-dimethyl-1-silaethylene and its deuteromethyl derivative. Journal of Organometallic Chemistry 1980, 201
(1)
, 123-136. https://doi.org/10.1016/S0022-328X(00)92571-3
- L.E. Gusel'nikov, V.V. Volkova, V.G. Avakyan, N.S. Nametkin. Very low pressure pyrolysis (VLPP) of monosilacyclobutanes. Infrared absorptions of 1,1-dimethyl-1-silaethylene, (CH3)2SiCH2, and 1,1-dideuteriomethyl-1-silaethylene, (CD3)2SiCH2 isolated in argon matrices. Journal of Organometallic Chemistry 1980, 201
(1)
, 137-150. https://doi.org/10.1016/S0022-328X(00)92572-5
- G. Märkl, P. Hofmeister. cis-dicarbonyl-η-1-silacyclohexa-2,4-dien-molybdän(0) und -wolfram(0)-komplexe, dimere 4-alkyl-1-silacyclohexa-1,3-diene mit 1,3-disilacyclobutanstruktur, und 2,2′-di-1-silacyclohexa-2,4-diene. Journal of Organometallic Chemistry 1980, 187
(1)
, 31-42. https://doi.org/10.1016/S0022-328X(00)90532-1
- Iain M.T. Davidson, Naaman A. Ostah, Dietmar Seyferth, Don P. Duncan. A gas kinetic study of the pyrolysis of octamethyl-1,2-disilacyclobutane. Journal of Organometallic Chemistry 1980, 187
(3)
, 297-304. https://doi.org/10.1016/S0022-328X(00)93422-3
- E. Bastian, P. Potzinger, A. Ritter, H.‐P. Schuchmann, C. von Sonntag, G. Weddle. The Direct Photolysis of Tetramethylsilane in the Gas and Liquid Phases. Berichte der Bunsengesellschaft für physikalische Chemie 1980, 84
(1)
, 56-62. https://doi.org/10.1002/bbpc.19800840112
- A.G. BROOK, A.R. BASSINDALE. Molecular Rearrangements of Organosilicon Compounds. 1980, 149-227. https://doi.org/10.1016/B978-0-12-481302-1.50008-6
- MICHEL NASTASI, JACQUES STREITH. Photochemical Rearrangements Involving Three-Membered Rings. 1980, 445-499. https://doi.org/10.1016/B978-0-12-481303-8.50014-7
- S. Basu, I. M. T. Davidson, R. Laupert, P. Potzinger. Low pressure pyrolysis of 1,1‐dimethyl‐1‐silacyclobutane. Berichte der Bunsengesellschaft für physikalische Chemie 1979, 83
(12)
, 1282-1286. https://doi.org/10.1002/bbpc.19790831216
- N. Auner, J. Grobe. Silaethene. III. Versuche zur Darstellung und spektroskopischen Charakterisierung von H
2
SiCH
2
, D
2
SiCH
2
und Me(H)SiCH
2. Zeitschrift für anorganische und allgemeine Chemie 1979, 459
(1)
, 15-36. https://doi.org/10.1002/zaac.19794590103
- Gottfried Märkl, Peter Hofmeister. 1,4‐Di‐
tert
‐butylsilabenzene: Generation and Trapping Reactions. Angewandte Chemie International Edition in English 1979, 18
(10)
, 789-790. https://doi.org/10.1002/anie.197907891
- Gottfried Märkl, Peter Hofmeister. 1, 4‐Di‐
tert
‐butylsilabenzol; Erzeugung und Abfangreaktionen. Angewandte Chemie 1979, 91
(10)
, 863-864. https://doi.org/10.1002/ange.19790911032
- A. K. Mal'tsev, V. N. Khabashesku, O. M. Nefedov. New infrared spectroscopic observation of 1,1-dimethyl-1-silaethylene in an argon matrix. Bulletin of the Academy of Sciences of the USSR Division of Chemical Science 1979, 28
(9)
, 1980-1981. https://doi.org/10.1007/BF00952497
- Thomas J. Barton, Christopher R. Tully. Unexpected chemistry in an attempted generation of a sterically hindered silene. Journal of Organometallic Chemistry 1979, 172
(1)
, 11-19. https://doi.org/10.1016/S0022-328X(00)81852-5
- L.E. Gusel'nikov, N.S. Nametkin. 1,1-Dimethyl-1-silaethylene. Journal of Organometallic Chemistry 1979, 169
(2)
, 155-164. https://doi.org/10.1016/S0022-328X(00)81154-7
- Thomas J. Barton, S. Kent Hoekman. Convenient Synthesis of Trimethylsilyldiazomethane - A Silene Generator. Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry 1979, 9
(4)
, 297-300. https://doi.org/10.1080/00945717908069745
- Ryoji Noyori, Masashi Yamakawa, Wataru Ando. A Molecular Orbital Study of Silylated Carbenes. Bulletin of the Chemical Society of Japan 1978, 51
(3)
, 811-814. https://doi.org/10.1246/bcsj.51.811
- Mark S. Gordon. The methylsilylene-silaethylene-silylcarbene isomerization. Chemical Physics Letters 1978, 54
(1)
, 9-13. https://doi.org/10.1016/0009-2614(78)85652-8
- Nils Wiberg, Gerhard Preiner. Darstellung und einige Reaktionen von 1,1‐Dimethyl‐2,2‐bis(trimethylsilyl)‐1‐silaethen. Angewandte Chemie 1977, 89
(5)
, 343-344. https://doi.org/10.1002/ange.19770890528
- Nils Wiberg, Gerhard Preiner. Synthesis and Some Reactions of 1,1‐Dimethyl‐2,2‐bis‐(trimethylsilyl)‐1‐silaethene. Angewandte Chemie International Edition in English 1977, 16
(5)
, 328-330. https://doi.org/10.1002/anie.197703282
- O. L. CHAPMAN, C.‐C. CHANG, J. KOLC, M. E. JUNG, J. A. LOWE, T. J. BARTON, M. L. TUMEY. ChemInform Abstract: 1,1,2‐TRIMETHYLSILAETHYLENE. Chemischer Informationsdienst 1977, 8
(9)
https://doi.org/10.1002/chin.197709280
- . Anorganische Chemie 1976. Nachrichten aus Chemie, Technik und Laboratorium 1977, 55-58. https://doi.org/10.1002/nadc.19770250204
Article Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.
Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.
The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated.