Reaction of xenon with dioxygenyl tetrafluoroborate. Preparation of FXe-BF2

Charles T. Goetschel, and Karl R. Loos

J. Am. Chem. Soc., 1972, 94 (9), pp 3018–3021

DOI: 10.1021/ja00764a022

Publication Date: May 1972

Cite this:J. Am. Chem. Soc. 94, 9, 3018-3021

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Article

Reaction of xenon with dioxygenyl tetrafluoroborate. Preparation of FXe-BF2

NgMCp⁺: Noble Gas Bound Half-Sandwich Complexes (Ng = He–Rn, M = Be–Ba, and Cp = η⁵-C₅H₅)

Interactions in the B⁺–RG Complexes and Comparison with Be⁺–RG (RG = He–Rn): Evidence for Chemical Bonding

Novel Rare Gas Ions BXe⁺, BKr⁺, and BAr⁺ Formed in a Halogen/Rare Gas Exchange Reaction

Dioxygenyl pentafluorogermanate(IV), 02+GeF5-

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Reaction of xenon with dioxygenyl tetrafluoroborate. Preparation of FXe-BF2

NgMCp+: Noble Gas Bound Half-Sandwich Complexes (Ng = He–Rn, M = Be–Ba, and Cp = η5-C5H5)

Interactions in the B+–RG Complexes and Comparison with Be+–RG (RG = He–Rn): Evidence for Chemical Bonding

Novel Rare Gas Ions BXe+, BKr+, and BAr+ Formed in a Halogen/Rare Gas Exchange Reaction

Dioxygenyl pentafluorogermanate(IV), 02+GeF5-

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NgMCp⁺: Noble Gas Bound Half-Sandwich Complexes (Ng = He–Rn, M = Be–Ba, and Cp = η⁵-C₅H₅)

Interactions in the B⁺–RG Complexes and Comparison with Be⁺–RG (RG = He–Rn): Evidence for Chemical Bonding

Novel Rare Gas Ions BXe⁺, BKr⁺, and BAr⁺ Formed in a Halogen/Rare Gas Exchange Reaction