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Proton, carbon-13, and nitrogen-15 nuclear magnetic resonance studies of a dinitrogen complex of permethyltitanocene. Evidence for molecular nitrogen coordinated edge-on to a transition metal

Cite this: J. Am. Chem. Soc. 1974, 96, 2, 612–614
Publication Date (Print):January 1, 1974
https://doi.org/10.1021/ja00809a063
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    This article is cited by 38 publications.

    1. Philip Coppens,, Irina Novozhilova, and, Andrey Kovalevsky. Photoinduced Linkage Isomers of Transition-Metal Nitrosyl Compounds and Related Complexes. Chemical Reviews 2002, 102 (4) , 861-884. https://doi.org/10.1021/cr000031c
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    5. Fabio Masero, Marie A. Perrin, Subal Dey, Victor Mougel. Dinitrogen Fixation: Rationalizing Strategies Utilizing Molecular Complexes. Chemistry – A European Journal 2021, 27 (12) , 3892-3928. https://doi.org/10.1002/chem.202003134
    6. Lauren E. Hatcher, Paul R. Raithby. Solid-state photochemistry of molecular photo-switchable species: the role of photocrystallographic techniques. Acta Crystallographica Section C Crystal Structure Communications 2013, 69 (12) , 1448-1456. https://doi.org/10.1107/S010827011303223X
    7. Dhurairajan Senthilnathan, Sundararajan Vaideeswaran, Ponnambalam Venuvanalingam, Gernot Frenking. Antitumor activity of bent metallocenes: electronic structure analysis using DFT computations. Journal of Molecular Modeling 2011, 17 (3) , 465-475. https://doi.org/10.1007/s00894-010-0734-4
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    21. J. Jeffrey, M.F. Lappert, P.I. Riley. Organozirconium dinitrogen complexes [Zr(η-C5H4R')2(η2-N2)R] and [{Zr(η-C5H5)2R}2N2][R=(Me3Si)2CH,R'= H OR Me]. Journal of Organometallic Chemistry 1979, 181 (1) , 25-36. https://doi.org/10.1016/S0022-328X(00)85734-4
    22. Herbert Motschi, Paul S. Pregosin, Luigi M. Venanzi. 15N-NMR. and31P-NMR. Studies of palladium and platinum complexes. Helvetica Chimica Acta 1979, 62 (3) , 667-677. https://doi.org/10.1002/hlca.19790620304
    23. M. Witanowski, I. stefaniak, G.A. Webb. Nitrogen NMR Spectroscopy. 1978, 117-244. https://doi.org/10.1016/S0066-4103(08)60189-1
    24. M Witanowski, L Stefaniak, S Szymański, H Januszewski. External neat nitromethane scale for nitrogen chemical shifts. Journal of Magnetic Resonance (1969) 1977, 28 (2) , 217-226. https://doi.org/10.1016/0022-2364(77)90148-2
    25. John E. Bercaw. The Activation of Molecular Nitrogen. 1977, 129-146. https://doi.org/10.1007/978-1-4615-7038-7_6
    26. K. Kishi, M.W. Roberts. Adsorption of nitrogen and ammonia by polycrystalline iron surfaces in the temperature range 80–290 K studied by electron spectroscopy. Surface Science 1977, 62 (1) , 252-266. https://doi.org/10.1016/0039-6028(77)90441-1
    27. C. R. Lucas, A. Shaver. Bis(η 5 ‐Cyclopentadienyl) [Tetrahydroborato(1−)]Titanium. 1977, 91-94. https://doi.org/10.1002/9780470132487.ch27
    28. P.S. Braterman. Transition metals: Physical methods and results of general interest (1974). Journal of Organometallic Chemistry 1976, 123 , 75-204. https://doi.org/10.1016/S0022-328X(00)87612-3
    29. Theodore Axenrod, Pietro Mangiaracina, Paul S. Pregosin. A13C- and15N-NMR. Study of Some 1-Aryl-3, 3-dimethyl Triazene Derivatives. Helvetica Chimica Acta 1976, 59 (5) , 1655-1660. https://doi.org/10.1002/hlca.19760590526
    30. Peter C. Wailes. Titanium, zirconium and hafnium. Journal of Organometallic Chemistry 1975, 103 , 475-494. https://doi.org/10.1016/S0022-328X(00)89241-4
    31. Thomas C. McKenzie, Robert D. Sanner, John E. Bercaw. The crystal and molecular structure of bis(pentamethylcyclopentadienyl)dichlorotitanium(IV). Journal of Organometallic Chemistry 1975, 102 (4) , 457-466. https://doi.org/10.1016/S0022-328X(00)89390-0
    32. R. Ugo. The Contribution of Organometallic Chemistry and Homogeneous Catalysis to the Understanding of Surface Reactions. Catalysis Reviews 1975, 11 (1) , 225-297. https://doi.org/10.1080/01614947508079986
    33. Ulrich Burger, Arlette Delay, François Mazenod. 1,2,3,4,5-Pentamethyl-5-acetyl-cyclopentadien-1,3, ein ungewöhnliches Keton. Helvetica Chimica Acta 1974, 57 (7) , 2106-2111. https://doi.org/10.1002/hlca.19740570725
    34. Dieter Sellmann. Distickstoff-Übergangsmetall-Komplexe: Synthese, Eigenschaften und Bedeutung. Angewandte Chemie 1974, 86 (19) , 692-702. https://doi.org/10.1002/ange.19740861903
    35. Dieter Sellmann. Dinitrogen-Transition Metal Complexes: Synthesis, Properties, and Significance. Angewandte Chemie International Edition in English 1974, 13 (10) , 639-649. https://doi.org/10.1002/anie.197406391
    36. JOHN E. BERCAW, EDWARD ROSENBERG, JOHN D. ROBERTS. ChemInform Abstract: (1)H, (13)C, AND (15)N NUCLEAR MAGNETIC RESONANCE STUDIES OF A DINITROGEN COMPLEX OF PERMETHYLTITANOCENE, EVIDENCE FOR MOLECULAR NITROGEN COORDINATED ′EDGE-ON′ TO A TRANSITION METAL. Chemischer Informationsdienst 1974, 5 (14) , no-no. https://doi.org/10.1002/chin.197414398
    37. Robert G. Bergstrom, George H. Wahl, Heinrich Zollinger. Reaction of unactivated nitrogen molecules with phenyl cations in 2,2,2-trifluoroethanol. Tetrahedron Letters 1974, 15 (34) , 2975-2978. https://doi.org/10.1016/S0040-4039(01)91796-4
    38. Walter G. Zumft. The molecular basis of biological dinitrogen fixation. , 1-65. https://doi.org/10.1007/BFb0116518

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