The Halogenation of Amidines. I. Synthesis of 3-Halo- and Other Negatively Substituted Diazirines¹

This article is cited by 281 publications.

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2. Nicholas J. Porter, Emma Danelius, Tamir Gonen, Frances H. Arnold. Biocatalytic Carbene Transfer Using Diazirines. Journal of the American Chemical Society 2022, 144 (20) , 8892-8896. https://doi.org/10.1021/jacs.2c02723
3. Monish Arbaz Ansari, Ganesh Kumar, Maya Shankar Singh. Base Mediated Diazirination via Iodine(III) Reagents. Organic Letters 2022, 24 (15) , 2815-2820. https://doi.org/10.1021/acs.orglett.2c00717
4. Balu D. Dherange, Patrick Q. Kelly, Jordan P. Liles, Matthew S. Sigman, Mark D. Levin. Carbon Atom Insertion into Pyrroles and Indoles Promoted by Chlorodiazirines. Journal of the American Chemical Society 2021, 143 (30) , 11337-11344. https://doi.org/10.1021/jacs.1c06287
5. Thomas Glachet, Hamid Marzag, Nathalie Saraiva Rosa, Johannes F. P. Colell, Guannan Zhang, Warren S. Warren, Xavier Franck, Thomas Theis, Vincent Reboul. Iodonitrene in Action: Direct Transformation of Amino Acids into Terminal Diazirines and 15N2-Diazirines and Their Application as Hyperpolarized Markers. Journal of the American Chemical Society 2019, 141 (34) , 13689-13696. https://doi.org/10.1021/jacs.9b07035
6. Lei Wang, Robert A. Moss, and Karsten Krogh-Jespersen . Complexes and Negative Activation Energies in Arylhalocarbene/Alkene Additions: Activation Parameter Dependence on Alkane Solvent Chain Length. The Journal of Organic Chemistry 2017, 82 (8) , 4216-4225. https://doi.org/10.1021/acs.joc.7b00186
7. Robert A. Moss . Adventures in Reactive Intermediate Chemistry: A Perspective and Retrospective. The Journal of Organic Chemistry 2017, 82 (5) , 2307-2318. https://doi.org/10.1021/acs.joc.6b02876
8. Irina Protasova, Bekir Bulat, Nicole Jung, and Stefan Bräse . Synthesis of Diaziridines and Diazirines via Resin-Bound Sulfonyl Oximes. Organic Letters 2017, 19 (1) , 34-37. https://doi.org/10.1021/acs.orglett.6b03252
9. Rafael Navrátil, Ján Tarábek, Igor Linhart, and Tomáš Martinů . Radical and Nitrenoid Reactivity of 3-Halo-3-phenyldiazirines. Organic Letters 2016, 18 (15) , 3734-3737. https://doi.org/10.1021/acs.orglett.6b01753
10. Geneviève Richter, Enrique Mendez-Vega, and Wolfram Sander . Singlet Halophenylcarbenes as Strong Hydrogen-Bond Acceptors. The Journal of Physical Chemistry A 2016, 120 (20) , 3524-3532. https://doi.org/10.1021/acs.jpca.6b02550
11. Lei Wang, Karsten Krogh-Jespersen, and Robert A. Moss . Activation Parameters for Additions to Alkenes of Arylchlorocarbenes with Enhanced Electrophilicity. The Journal of Organic Chemistry 2015, 80 (15) , 7590-7593. https://doi.org/10.1021/acs.joc.5b01210
12. Stephanie R. Hare, Marina Orman, Faizunnahar Dewan, Elizabeth Dalchand, Camilla Buzard, Sadia Ahmed, Julia C. Tolentino, Ulweena Sethi, Kelly Terlizzi, Camille Houferak, Aliza M. Stein, Alexandra Stedronsky, Dasan M. Thamattoor, Dean J. Tantillo, and Dina C. Merrer . Experimental and Computational Mechanistic Investigation of Chlorocarbene Additions to Bridgehead Carbene–Anti-Bredt Systems: Noradamantylcarbene–Adamantene and Adamantylcarbene–Homoadamantene. The Journal of Organic Chemistry 2015, 80 (10) , 5049-5065. https://doi.org/10.1021/acs.joc.5b00456
13. Lei Wang, Robert A. Moss, and Karsten Krogh-Jespersen . Hammett Analyses of Halocarbene–Halocarbanion Equilibria. Organic Letters 2013, 15 (8) , 2014-2017. https://doi.org/10.1021/ol400698y
14. Lei Wang, Robert A. Moss, and Karsten Krogh-Jespersen . Directly Observed Halocarbene–Halocarbanion Equilibration. Journal of the American Chemical Society 2012, 134 (42) , 17459-17461. https://doi.org/10.1021/ja308779w
15. Yong-miao Shen, Robert A. Moss, and Karsten Krogh-Jespersen . Directly Measured Activation Parameters for the Ring Expansions of Cyclopropylhalocarbenes. Organic Letters 2012, 14 (3) , 910-913. https://doi.org/10.1021/ol203426e
16. Min Zhang, Robert A. Moss, Jack Thompson, and Karsten Krogh-Jespersen . Evolution of Structure and Reactivity in a Series of Iconic Carbenes. The Journal of Organic Chemistry 2012, 77 (2) , 843-850. https://doi.org/10.1021/jo2023558
17. Robert A. Moss, Yongmaio Shen, Lei Wang, and Karsten Krogh-Jespersen . Pentafluorophenylhalocarbenes. Organic Letters 2011, 13 (17) , 4752-4754. https://doi.org/10.1021/ol2019532
18. Elliot J. Lawrence, Gregory G. Wildgoose, Leigh Aldous, Yimin A. Wu, Jamie H. Warner, Richard G. Compton, and Paul D. McNaughter . 3-Aryl-3-(trifluoromethyl)diazirines as Versatile Photoactivated “Linker” Molecules for the Improved Covalent Modification of Graphitic and Carbon Nanotube Surfaces. Chemistry of Materials 2011, 23 (16) , 3740-3751. https://doi.org/10.1021/cm201461w
19. Lei Wang, Robert A. Moss, and Karsten Krogh-Jespersen . Trimethoxybenzene Complexes of Pentafluorophenylchlorocarbene. The Journal of Physical Chemistry A 2011, 115 (28) , 8113-8118. https://doi.org/10.1021/jp2039493
20. Midori O. Ishitsuka, Shogo Sano, Haruka Enoki, Satoru Sato, Hidefumi Nikawa, Takahiro Tsuchiya, Zdenek Slanina, Naomi Mizorogi, Michael T. H. Liu, Takeshi Akasaka, and Shigeru Nagase . Regioselective Bis-functionalization of Endohedral Dimetallofullerene, La2@C80: Extremal La–La Distance. Journal of the American Chemical Society 2011, 133 (18) , 7128-7134. https://doi.org/10.1021/ja200903q
21. Lei Wang, Robert A. Moss, Jack Thompson, and Karsten Krogh-Jespersen . Hammett Analysis of a Family of Carbene−Carbene Complex Equilibria. Organic Letters 2011, 13 (5) , 1198-1201. https://doi.org/10.1021/ol200083a
22. Robert A. Moss. “Carbon Dichloride”: Dihalocarbenes Sixty Years After Hine. The Journal of Organic Chemistry 2010, 75 (17) , 5773-5783. https://doi.org/10.1021/jo100390p
23. Robert A. Moss, Lei Wang, Christina M. Odorisio and Karsten Krogh-Jespersen. A Carbene−Carbene Complex Equilibrium. Journal of the American Chemical Society 2010, 132 (31) , 10677-10679. https://doi.org/10.1021/ja104514h
24. Yunlong Zhang, Lei Wang, Robert A. Moss and Matthew S. Platz. Ultrafast Spectroscopy of Arylchlorodiazirines: Hammett Correlations of Excited State Lifetimes. Journal of the American Chemical Society 2009, 131 (46) , 16652-16653. https://doi.org/10.1021/ja907915z
25. Bastian Noller, Lionel Poisson, Raman Maksimenka, Oliver Gobert, Ingo Fischer and J. M. Mestdagh. Ultrafast Dynamics of Isolated Phenylcarbenes Followed by Femtosecond Time-Resolved Velocity Map Imaging. The Journal of Physical Chemistry A 2009, 113 (13) , 3041-3050. https://doi.org/10.1021/jp810974m
26. Xavier Creary and Elizabeth D. Kochly. Systematic Repression of β-Silyl Carbocation Stabilization. The Journal of Organic Chemistry 2009, 74 (5) , 2134-2144. https://doi.org/10.1021/jo802722z
27. Reinaldo Moya-Barrios, Frances L. Cozens and Norman P. Schepp. Absolute Reactivity of Halo(pyridyl)carbenes. The Journal of Organic Chemistry 2009, 74 (3) , 1148-1155. https://doi.org/10.1021/jo802132z
28. Robert A. Moss and Min Zhang. Activation Parameters for Additions of Ambiphilic Methoxychlorocarbene to Alkenes. Organic Letters 2008, 10 (18) , 4045-4048. https://doi.org/10.1021/ol801575v
29. Robert A. Moss,, Jingzhi Tian,, Ronald R. Sauers,, Christopher Skalit, and, Karsten Krogh-Jespersen. Chlorofluorocarbene:  First UV Observation of a Dihalocarbene in Solution. Organic Letters 2007, 9 (20) , 4053-4056. https://doi.org/10.1021/ol701804m
30. Robert A. Moss,, Jingzhi Tian,, Ronald R. Sauers, and, Karsten Krogh-Jespersen. Tracking “Invisible” Alkylchlorocarbenes by Their σ → p Absorptions:  Dynamics and Solvent Interactions. Journal of the American Chemical Society 2007, 129 (32) , 10019-10028. https://doi.org/10.1021/ja071799i
31. Robert A. Moss,, Jingzhi Tian,, Ronald R. Sauers,, Daniel H. Ess,, Kendall N. Houk, and, Karsten Krogh-Jespersen. The Synthesis of Dichlorodiazirine and the Generation of Dichlorocarbene:  Spectroscopy and Structure of Dichlorocarbene Ylides. Journal of the American Chemical Society 2007, 129 (16) , 5167-5174. https://doi.org/10.1021/ja068727w
32. Jin Wang,, Gotard Burdzinski,, Jacek Kubicki,, Matthew S. Platz,, Robert A. Moss,, Xiaolin Fu,, Piotr Piotrowiak, and, Mykhaylo Myahkostupov. Ultrafast Spectroscopic Study of the Photochemistry and Photophysics of Arylhalodiazirines:  Direct Observation of Carbene and Zwitterion Formation. Journal of the American Chemical Society 2006, 128 (51) , 16446-16447. https://doi.org/10.1021/ja067205d
33. Xiaolin Fu,, Robert A. Moss,, Piotr Piotrowiak,, Mykhaylo Myahkostupov, and, Ian R. Gould. Fragmentation of 2,2,2-Triphenylethoxychlorocarbene:  Evidence for Ultrafast Fragmentation−Rearrangement in Excited Diazirines. Organic Letters 2006, 8 (21) , 4807-4809. https://doi.org/10.1021/ol061863l
34. Jin Xi, Renyu Liu, Matthew J. Rossi, Jay Yang, Patrick J. Loll, William P. Dailey and Roderic G. Eckenhoff . Photoactive Analogues of the Haloether Anesthetics Provide High-Resolution Features from Low-Affinity Interactions. ACS Chemical Biology 2006, 1 (6) , 377-384. https://doi.org/10.1021/cb600207d
35. Tomas Martinu and, William P. Dailey. Reactivity of 1-Chloro-3-phenyldiazirines. The Journal of Organic Chemistry 2006, 71 (13) , 5012-5015. https://doi.org/10.1021/jo060341g
36. Robert A. Moss and, Jingzhi Tian. Hammett Studies of Aryldichloromethide Carbanion Reactions. Organic Letters 2006, 8 (6) , 1245-1247. https://doi.org/10.1021/ol060188c
37. Robert A. Moss,, Xiaolin Fu,, Ronald R. Sauers, and, Peter Wipf. Endo Entry to the Nortricyclyl−Norbornenyl Cation System:  Stereochemistry in the Fragmentation of endo-5-Norbornenyl-2-oxychlorocarbene. The Journal of Organic Chemistry 2005, 70 (21) , 8454-8460. https://doi.org/10.1021/jo051222o
38. Robert A. Moss,, Jingzhi Tian,, Ronald R. Sauers,, Robert S. Sheridan,, Avinash Bhakta, and, Peter S. Zuev. Kinetic Studies of the Cyclization of Singlet Vinylchlorocarbenes. Organic Letters 2005, 7 (21) , 4645-4648. https://doi.org/10.1021/ol051743y
39. Asya F. Nikitina and, Robert S. Sheridan. Geometry and Aromaticity in Highly Strained Heterocyclic Allenes:  Characterization of a 2,3-Didehydro-2H-thiopyran. Organic Letters 2005, 7 (20) , 4467-4470. https://doi.org/10.1021/ol051733x
40. Robert A. Moss and, Jingzhi Tian. Concurrent Cyclopropanation by Carbenes and Carbanions. Journal of the American Chemical Society 2005, 127 (25) , 8960-8961. https://doi.org/10.1021/ja052426p
41. Ying Cheng,, Qing Zhu,, Quan Song Li, and, Otto Meth-Cohn. Interaction of Aryloxychlorocarbenes with Acetylenedicarboxylate:  Novel Formation of Polyfunctional Butadienes and 8-Oxatricyclo[3.2.1.02.4]oct-6-enes. The Journal of Organic Chemistry 2005, 70 (12) , 4840-4846. https://doi.org/10.1021/jo0501792
42. Robert A. Moss,, Yan Ma,, Xiaolin Fu, and, Ronald R. Sauers. Homolytic Fragmentation of Allyloxychlorocarbene. Organic Letters 2005, 7 (10) , 2055-2058. https://doi.org/10.1021/ol050668o
43. Robert A. Moss,, Gaosheng Chu, and, Ronald R. Sauers. Unprecedented Chemistry of an Aryloxychlorodiazirine:  Generation of a Dihalodiazirine and Diazirinone. Journal of the American Chemical Society 2005, 127 (8) , 2408-2409. https://doi.org/10.1021/ja050103n
44. Robert A. Moss,, Xiaolin Fu,, Jingzhi Tian,, Ronald Sauers, and, Peter Wipf. Stereochemistry of Oxachlorocarbene SNi Reactions. Organic Letters 2005, 7 (7) , 1371-1374. https://doi.org/10.1021/ol050185k
45. Robert A. Moss,, Fengmei Zheng,, Jean-Marie Fedé,, Lauren A. Johnson, and, Ronald R. Sauers. Solvent-Equilibrated Ion Pairs from Carbene Fragmentation Reactions. Journal of the American Chemical Society 2004, 126 (39) , 12421-12431. https://doi.org/10.1021/ja040146o
46. Peter S. Zuev and, Robert S. Sheridan. Singlet Vinylcarbenes:  Spectroscopy and Photochemistry. Journal of the American Chemical Society 2004, 126 (39) , 12220-12221. https://doi.org/10.1021/ja046309q
47. Tomas Martinu and, William P. Dailey. Synthesis of Carboalkoxychloro- and Bromodiazirines. The Journal of Organic Chemistry 2004, 69 (21) , 7359-7362. https://doi.org/10.1021/jo040194r
48. Robert A. Moss and, Xiaolin Fu. Arylmethyl Radicals from Arylmethoxybromodiazirines. Organic Letters 2004, 6 (19) , 3353-3356. https://doi.org/10.1021/ol0400443
49. Robert A. Moss,, Ronald R. Sauers,, Robert S. Sheridan,, Jingzhi Tian, and, Peter S. Zuev. Carbon Tunneling in the Ring Expansion of Noradamantylchlorocarbene. Journal of the American Chemical Society 2004, 126 (33) , 10196-10197. https://doi.org/10.1021/ja0488939
50. Robert A. Moss,, Ronald R. Sauers,, Fengmei Zheng,, Xiaolin Fu,, Thomas Bally, and, Alexander Maltsev. Rearrangements Concerted with Fragmentation of Cyclopropylmethoxychlorocarbene and Cyclobutoxychlorocarbene in Hydrocarbon Solvents and Ar Matrices. Journal of the American Chemical Society 2004, 126 (27) , 8466-8476. https://doi.org/10.1021/ja049421x
51. Robert A. Moss,, Yan Ma,, Ronald R. Sauers, and, Mahvash Madni. Nortricyclyl−Norbornenyl Cation System Accessed by Carbene Fragmentation. The Journal of Organic Chemistry 2004, 69 (11) , 3628-3634. https://doi.org/10.1021/jo0401218
52. Norio Nakane,, Tomonori Enyo, and, Hideo Tomioka. Photolysis of 3-(2-Formylphenyl)-3-chlorodiazirine in an Ar Matrix at Low Temperature. The Journal of Organic Chemistry 2004, 69 (10) , 3538-3545. https://doi.org/10.1021/jo049802t
53. Reinaldo Moya-Barrios and, Frances L. Cozens. First Direct Observation of Reactive Carbenes in the Cavities of Cation-Exchanged Y Zeolites. Organic Letters 2004, 6 (6) , 881-884. https://doi.org/10.1021/ol0363669
54. Robert A. Moss and, Xiaolin Fu. Carbene Fragmentation in the Bicyclo[3.1.0]hexyl System:  Disconnecting the Trishomocyclopropenyl Cation. Organic Letters 2004, 6 (6) , 981-983. https://doi.org/10.1021/ol040001m
55. Jean-Marie Fedé,, Steffen Jockusch,, Nan Lin,, Robert A. Moss, and, Nicholas J. Turro. Aryloxy Radicals from Diaryloxydiazirines:  α-Cleavage of Diaryloxycarbenes or Excited Diazirines?. Organic Letters 2003, 5 (26) , 5027-5030. https://doi.org/10.1021/ol030123z
56. Michael T. H. Liu,, Yoong-Kee Choe,, Masahiro Kimura,, Kaoru Kobayashi,, Shigeru Nagase,, Takatsugu Wakahara,, Yasuyuki Niino,, Midori O. Ishitsuka,, Yutaka Maeda, and, Takeshi Akasaka. Effect of Substituents on the Thermal Decomposition of Diazirines:  Experimental and Computational Studies. The Journal of Organic Chemistry 2003, 68 (19) , 7471-7478. https://doi.org/10.1021/jo034949q
57. Robert A. Moss,, Lauren A. Johnson,, Monica Kacprzynski, and, Ronald R. Sauers. Fragmentation of Menthyl- and Neomenthyloxychlorocarbenes:  Elimination and Substitution Reactions of Alicyclic Oxychlorocarbenes. The Journal of Organic Chemistry 2003, 68 (13) , 5114-5118. https://doi.org/10.1021/jo030100y
58. Carlos N. Sanrame,, Christopher P. Suhrada,, Hung Dang, and, Miguel A. Garcia-Garibay. Photochemistry of Crystalline Chlorodiazirines:  The Influence of Conformational Disorder and Intermolecular Cl···NN Interactions on the Solid-State Reactivity of Singlet Chlorocarbenes. The Journal of Physical Chemistry A 2003, 107 (18) , 3287-3294. https://doi.org/10.1021/jp026641t
59. Ying Sun,, Eric M. Tippmann, and, Matthew S. Platz. A Search for Carbene−Solvent Interactions Using Time-Resolved Infrared Spectroscopy. Organic Letters 2003, 5 (8) , 1305-1307. https://doi.org/10.1021/ol034236u
60. Robert A. Moss,, Yan Ma,, Fengmei Zheng, and, Ronald R. Sauers, , Thomas Bally and, Alexander Maltsev, , John P. Toscano and, Brett M. Showalter. The Fragmentation of Alkoxychlorocarbenes in Hydrocarbon Solvents and in Low Temperature Argon Matrixes. The Journal of Physical Chemistry A 2002, 106 (51) , 12280-12291. https://doi.org/10.1021/jp0217076
61. Robert A. Moss,, Yan Ma, and, Ronald R. Sauers. A Duality of Mechanisms for the Fragmentation of Substituted Benzyloxychlorocarbenes. Journal of the American Chemical Society 2002, 124 (47) , 13968-13969. https://doi.org/10.1021/ja0207605
62. Takatsugu Wakahara,, Yasuyuki Niino,, Takashi Kato,, Yutaka Maeda,, Takeshi Akasaka,, Michael T. H. Liu,, K. Kobayashi, and, S. Nagase. A Nonspectroscopic Method To Determine the Photolytic Decomposition Pathways of 3-Chloro-3-alkyldiazirine:  Carbene, Diazo and Rearrangement in Excited State. Journal of the American Chemical Society 2002, 124 (32) , 9465-9468. https://doi.org/10.1021/ja0116876
63. Asya Nikitina and, Robert S. Sheridan. Characterization of a Didehydrobenzoxazine Intermediate in a Novel Carbene-to-Carbene Transformation. Journal of the American Chemical Society 2002, 124 (26) , 7670-7671. https://doi.org/10.1021/ja026300t
64. Robert A. Moss,, Fengmei Zheng,, Jean-Marie Fedé, and, Ronald R. Sauers. The Carbene Fragmentation−Ring Expansion Route to Bridgehead Carbocations. Organic Letters 2002, 4 (14) , 2341-2344. https://doi.org/10.1021/ol020083j
65. Robert A. Moss,, Fengmei Zheng,, Jean-Marie Fedé,, Yan Ma,, Ronald R. Sauers,, John P. Toscano, and, Brett M. Showalter. Bridgehead Carbocations via Carbene Fragmentation:  Erasing a 1010 Kinetic Preference. Journal of the American Chemical Society 2002, 124 (19) , 5258-5259. https://doi.org/10.1021/ja020002e
66. Robert A. Moss,, Fengmei Zheng,, Ronald R. Sauers, and, John P. Toscano. The 2-Norbornyl Cation via the Fragmentations of exo- and endo-2-Norbornyloxychlorocarbenes:  Distinction without Much Difference. Journal of the American Chemical Society 2001, 123 (33) , 8109-8116. https://doi.org/10.1021/ja010598q
67. Robert A. Moss,, Jean-Marie Fedé, and, Shunqi Yan. SbF5-Mediated Reactions of Oxafluorodiazirines. Organic Letters 2001, 3 (15) , 2305-2308. https://doi.org/10.1021/ol010091k
68. Robert A. Moss,, Fengmei Zheng, and, Karsten Krogh-Jespersen. Rearrangement Kinetics of Spiropentylchlorocarbene, [3]Triangulylchlorocarbene, and Related Species. Organic Letters 2001, 3 (10) , 1439-1442. https://doi.org/10.1021/ol010023y
69. Athanassios Nicolaides,, Tomonori Enyo,, Daisuke Miura, and, Hideo Tomioka. p-Phenylenecarbenonitrene and Its Halogen Derivatives: How Does Resonance Interaction between a Nitrene and a Carbene Center Affect the Overall Electronic Configuration?. Journal of the American Chemical Society 2001, 123 (11) , 2628-2636. https://doi.org/10.1021/ja003709e
70. Sol Çelebi,, Meng-Lin Tsao, and, Matthew S. Platz. Laser Flash Photolysis Studies of the Reaction of Arylhalocarbenes with Tetramethylethylene as a Function of Solvent. The Journal of Physical Chemistry A 2001, 105 (7) , 1158-1162. https://doi.org/10.1021/jp002944g
71. Seong Hwi Cho,, Won-Hwa Park,, Sang Kyu Kim, and, Young S. Choi. Unimolecular Dissociation Dynamics of Vinyl Chloride on the Ground Potential Energy Surface:  The Method of Excitation and Product State Distributions of HCl and Cl Fragments. The Journal of Physical Chemistry A 2000, 104 (45) , 10482-10488. https://doi.org/10.1021/jp001125t
72. Robert A. Moss,, Jean-Marie Fedé, and, Shunqi Yan. Reactions of Diazirines with Aluminum Chloride:  Lewis Acid-Mediated Carbene Generation and Friedel−Crafts Reactions. Journal of the American Chemical Society 2000, 122 (40) , 9878-9879. https://doi.org/10.1021/ja002174m
73. Roland Bonneau, , Michael T. H. Liu. Kinetic and Spectroscopic Properties of Carbene−Diazirine Ylides. The Journal of Physical Chemistry A 2000, 104 (17) , 4115-4120. https://doi.org/10.1021/jp993711w
74. Tania Khasanova and, Robert S. Sheridan. Photoselection of Carbene Stereoisomers with Surprisingly Different Electronic Spectra:  3-Furylchlorocarbene. Organic Letters 1999, 1 (7) , 1091-1093. https://doi.org/10.1021/ol990890r
75. Robert A. Moss and, Shunqi Yan. Remote Substituent Effects on Phenylchlorocarbene C−H Insertion Reactions. Organic Letters 1999, 1 (5) , 819-822. https://doi.org/10.1021/ol990161b
76. Robert A. Moss,, Lauren A. Johnson,, Dina C. Merrer, and, George E. Lee, Jr.. Carbenes as Substrates:  Bimolecular Fragmentation of Alkoxychlorocarbenes. Journal of the American Chemical Society 1999, 121 (25) , 5940-5944. https://doi.org/10.1021/ja984418x
77. John Paul Pezacki,, Paul D. Wood,, Timothy A. Gadosy,, Janusz Lusztyk, and, John Warkentin. Laser Flash Photolysis Studies of Oxygen and Sulfur Atom Transfer Reactions from Oxiranes and Thiiranes to Singlet Carbenes1. Journal of the American Chemical Society 1998, 120 (34) , 8681-8691. https://doi.org/10.1021/ja973469b
78. Dina C. Merrer,, Robert A. Moss,, Michael T. H. Liu,, J. T. Banks, and, Keith U. Ingold. Benzylchlorocarbene:  Origins of Arrhenius Curvature in the Kinetics of the 1,2-H Shift Rearrangement. The Journal of Organic Chemistry 1998, 63 (9) , 3010-3016. https://doi.org/10.1021/jo972198k
79. Robert A. Moss,, Shunqi Yan, and, Karsten Krogh-Jespersen. Modulation of Carbenic Reactivity by π-Complexation to Aromatics. Journal of the American Chemical Society 1998, 120 (5) , 1088-1089. https://doi.org/10.1021/ja973649l
80. Tania Khasanova and, Robert S. Sheridan. Stereochemical Effects in Carbene Photochemistry:  2-Furylchlorocarbene. Journal of the American Chemical Society 1998, 120 (1) , 233-234. https://doi.org/10.1021/ja973550e
81. Didier Bourissou,, Yves Canac,, Maria Isabel Collado,, Antoine Baceiredo, and, Guy Bertrand. Synthesis and Reactivity of a Stable η2-(Diphosphirenylium)W(CO)5 Complex. Journal of the American Chemical Society 1997, 119 (41) , 9923-9924. https://doi.org/10.1021/ja971973a
82. Roland Bonneau,, Michael T. H. Liu,, Kyu Chul Kim, and, Joshua L. Goodman. Rearrangement of Alkylchlorocarbenes:  1,2-H Shift in Free Carbene, Carbene−Olefin Complex, and Excited States of Carbene Precursors. Journal of the American Chemical Society 1996, 118 (16) , 3829-3837. https://doi.org/10.1021/ja952700n
83. Gilles Alcaraz,, Valérie Piquet,, Antoine Baceiredo,, Françoise Dahan,, Wolfgang W. Schoeller, and, Guy Bertrand. Mechanism of the Exchange Reaction of Halodiazirines with Nucleophiles Revisited. Synthesis of Neutral, Mono- or Dicationic 4−16-Membered Phosphorus Heterocycles. Journal of the American Chemical Society 1996, 118 (5) , 1060-1065. https://doi.org/10.1021/ja9532143
84. Michael T. H. Liu and, Roland Bonneau. Laser Flash Photolysis Studies on Intra- and Intermolecular Reactions of Some Halocarbenes. Journal of the American Chemical Society 1996, 118 (34) , 8098-8101. https://doi.org/10.1021/ja960176u
85. Robert A. Moss,, Song Xue, and, Ronald R. Sauers. A Remarkably Specific π-Mediated Rearrangement of Benzocyclobutenylfluorocarbene. Journal of the American Chemical Society 1996, 118 (42) , 10307-10308. https://doi.org/10.1021/ja961939g
86. Robert A. Moss,, Chuan-Sheng Ge, and, Ljiljana Maksimovic. Absolute Kinetics of Alkoxychlorocarbene Fragmentation. Journal of the American Chemical Society 1996, 118 (40) , 9792-9793. https://doi.org/10.1021/ja962194h
87. Robert A. Moss,, Song Xue,, Weiguo Liu, and, Karsten Krogh-Jespersen. Reactions and Reactivity of Acyloxycarbenes. Journal of the American Chemical Society 1996, 118 (50) , 12588-12597. https://doi.org/10.1021/ja9626244
88. Xavier Creary. Reactions of halodiazirines by SN2' and electron transfer initiated processes. Accounts of Chemical Research 1992, 25 (1) , 31-38. https://doi.org/10.1021/ar00013a005
89. Robert A. Moss. Carbenic reactivity revisited. Accounts of Chemical Research 1989, 22 (1) , 15-21. https://doi.org/10.1021/ar00157a003
90. Matthew S. Platz. Dichlorocarbene: From Jack Hine to Robert Moss. Journal of Physical Organic Chemistry 2023, 123 https://doi.org/10.1002/poc.4563
91. Ben W. Joynson, Graham R. Cumming, Liam T. Ball. Photochemically Mediated Ring Expansion of Indoles and Pyrroles with Chlorodiazirines: Synthetic Methodology and Thermal Hazard Assessment. Angewandte Chemie 2023, 135 (31) https://doi.org/10.1002/ange.202305081
92. Ben W. Joynson, Graham R. Cumming, Liam T. Ball. Photochemically Mediated Ring Expansion of Indoles and Pyrroles with Chlorodiazirines: Synthetic Methodology and Thermal Hazard Assessment. Angewandte Chemie International Edition 2023, 62 (31) https://doi.org/10.1002/anie.202305081
93. Ben W. Joynson, Liam T. Ball. Skeletal Editing: Interconversion of Arenes and Heteroarenes. Helvetica Chimica Acta 2023, 106 (3) https://doi.org/10.1002/hlca.202200182
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