Allylation of aromatic compounds with organopalladium salts

Richard F. Heck

J. Am. Chem. Soc., 1968, 90 (20), pp 5531–5534

DOI: 10.1021/ja01022a036

Publication Date: September 1968

Cite this:J. Am. Chem. Soc. 90, 20, 5531-5534

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Article

Allylation of aromatic compounds with organopalladium salts

Switch to Allylic Selectivity in Cobalt-Catalyzed Dehydrogenative Heck Reactions with Unbiased Aliphatic Olefins

Legacy of Richard Heck

Isomerization of Allylbenzenes

Pd-Catalyzed Intramolecular C–N Bond Cleavage, 1,4-Migration, sp³ C–H Activation, and Heck Reaction: Four Controllable Diverse Pathways Depending on the Judicious Choice of the Base and Ligand

Chelation-Mediated Palladium(II)-Catalyzed Domino Heck−Mizoroki/Suzuki−Miyaura Reactions Using Arylboronic Acids: Increasing Scope and Mechanistic Understanding

Large-Scale Applications of Transition Metal-Catalyzed Couplings for the Synthesis of Pharmaceuticals

γ-Selective Cross-Coupling Reactions of Potassium Allyltrifluoroborates with Haloarenes Catalyzed by a Pd(0)/D-t-BPF or Pd(0)/Josiphos ((R,S)-CyPF-t-Bu) Complex: Mechanistic Studies on Transmetalation and Enantioselection

Efficient Palladium(II) Catalysis under Air. Base-Free Oxidative Heck Reactions at Room Temperature or with Microwave Heating

Palladium-Assisted Routes to Nucleosides

New Chemical Cross-Coupling between Aryl Halides and Allylic Acetates Using a Cobalt Catalyst

Cobalt-Catalyzed Direct Electrochemical Cross-Coupling between Aryl or Heteroaryl Halides and Allylic Acetates or Carbonates

Palladium(II)-Catalyzed Exchange and Isomerization Reactions. 17. Exchange of Chiral Allyl Alcohols with Hydroxide, Methoxide, and Phenyl at High [Cl^-]. Stereochemistry of the Wacker Reaction

The Alkylation of Iodouridine by a Heterogeneous Palladium Catalyst

Synthesis of α- and β-C-Aryl Δ²-Glycopyranosides from p-tert-Butylphenyl Δ²-Glycopyranosides via Grignard Reagents

Stereochemistry of the Wacker Reaction: Modes of Addition of Hydroxide, Methoxide, and Phenyl at High and Low [Cl^-]. A Study Using Chirality Transfer

Nickel-Catalyzed Coupling Reaction of 1,3-Disubstituted Secondary Allylic Carbonates and Lithium Aryl- and Alkenylborates

A New Poly(3-alkylthiophene) Synthesis via Pd-Catalyzed Coupling of Thienyl Mercuric Chlorides

Nickel-Catalyzed Direct Electrochemical Cross-Coupling between Aryl Halides and Activated Alkyl Halides

Regio- and Stereochemical Aspects of the Palladium-Catalyzed Reactions of Silanes

Estragole: An Acute Toxic Principle from the Volatile Oil of the Leaves of Clausena anisata

Palladium- or nickel-catalyzed cross coupling. A new selective method for carbon-carbon bond formation

Carbon-carbon bond formation via palladium complexes

The palladium-catalyzed arylation of enol esters, ethers, and halides. A new synthesis of 2-aryl aldehydes and ketones

Acylation, methylation, and carboxyalkylation of olefins by Group VIII metal derivatives

Classical Reagents: New Surprises in Palladium-Catalyzed CC Coupling Reactions

The Heck–Mizoroki cross-coupling reaction: a mechanistic perspective

C-Alkenylation of pyrimidine nucleosides and their analogues

Organoquecksilber-Verbindungen in der organischen Synthese

Über Acidität und Olefinierungsreaktionen von α-(Diphenylphosphino)carbonylverbindungen

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