ACS Publications. Most Trusted. Most Cited. Most Read
My Activity

Figure 1Loading Img

Conformational Adaptation and Selective Adatom Capturing of Tetrapyridyl-porphyrin Molecules on a Copper (111) Surface

View Author Information
Contribution from the Departments of Chemistry and Physics and Astronomy, University of British Columbia, Vancouver, BC V6T1Z4, Canada, Ecole Polytechnique Fédérale de Lausanne, Institut de Physique des Nanostructures, CH-1015 Lausanne, Switzerland, Lehrstuhl für Physikalische Chemie I, Ruhr-Universität Bochum, D-44780 Bochum, Germany, and Physik Department E20, Technische Universität München, D-85748 Garching, Germany
Cite this: J. Am. Chem. Soc. 2007, 129, 36, 11279–11285
Publication Date (Web):August 18, 2007
Copyright © 2007 American Chemical Society

    Article Views





    Other access options


    Abstract Image

    We present a combined low-temperature scanning tunneling microscopy and near-edge X-ray adsorption fine structure study on the interaction of tetrapyridyl-porphyrin (TPyP) molecules with a Cu(111) surface. A novel approach using data from complementary experimental techniques and charge density calculations allows us to determine the adsorption geometry of TPyP on Cu(111). The molecules are centered on “bridge” sites of the substrate lattice and exhibit a strong deformation involving a saddle-shaped macrocycle distortion as well as considerable rotation and tilting of the meso-substituents. We propose a bonding mechanism based on the pyridyl−surface interaction, which mediates the molecular deformation upon adsorption. Accordingly, a functionalization by pyridyl groups opens up pathways to control the anchoring of large organic molecules on metal surfaces and tune their conformational state. Furthermore, we demonstrate that the affinity of the terminal groups for metal centers permits the selective capture of individual iron atoms at low temperature.

    Read this article

    To access this article, please review the available access options below.

    Get instant access

    Purchase Access

    Read this article for 48 hours. Check out below using your ACS ID or as a guest.


    Access through Your Institution

    You may have access to this article through your institution.

    Your institution does not have access to this content. You can change your affiliated institution below.


    In papers with more than one author, the asterisk indicates the name of the author to whom inquiries about the paper should be addressed.

     University of British Columbia.

     Ecole Polytechnique Fédérale de Lausanne.

     Technische Universität München.


     Ruhr Universität Bochum.

     Current address:  Department of Physics and Astronomy, Western Washington University, Bellingham, WA 98225−9164.

    Cited By

    This article is cited by 118 publications.

    1. Phillips Hutchison, Corey J. Kaminsky, Yogesh Surendranath, Sharon Hammes-Schiffer. Concerted Proton-Coupled Electron Transfer to a Graphite Adsorbed Metalloporphyrin Occurs by Band to Bond Electron Redistribution. ACS Central Science 2023, 9 (5) , 927-936.
    2. Aleksandr Baklanov, Johannes T. Küchle, David A. Duncan, Paul T. P. Ryan, Reinhard J. Maurer, Martin Schwarz, Eduardo Corral Rascon, Ignacio Piquero-Zulaica, Huynh Thien Ngo, Alexander Riss, Francesco Allegretti, Willi Auwärter. Zinc-Porphine on Coinage Metal Surfaces: Adsorption Configuration and Ligand-Induced Central Atom Displacement. The Journal of Physical Chemistry C 2023, 127 (15) , 7501-7512.
    3. Joris de la Rie, Mihaela Enache, Qiankun Wang, Wenbo Lu, Milan Kivala, Meike Stöhr. Self-Assembly of a Triphenylene-Based Electron Donor Molecule on Graphene: Structural and Electronic Properties. The Journal of Physical Chemistry C 2022, 126 (23) , 9855-9861.
    4. Tobias Wähler, Ralf Schuster, Jörg Libuda. Surface Structure Controls Self-Metalation: In-Situ IR Studies of Anchored Porphyrins on Atomically-Defined Cobalt Oxide Surfaces. The Journal of Physical Chemistry C 2020, 124 (39) , 21538-21548.
    5. Daniela Rolf, Christian Lotze, Constantin Czekelius, Benjamin W. Heinrich, Katharina J. Franke. Visualizing Intramolecular Distortions as the Origin of Transverse Magnetic Anisotropy. The Journal of Physical Chemistry Letters 2018, 9 (22) , 6563-6567.
    6. Martin Schwarz, Manuela Garnica, David A. Duncan, Alejandro Pérez Paz, Jacob Ducke, Peter S. Deimel, Pardeep K. Thakur, Tien-Lin Lee, Angel Rubio, Johannes V. Barth, Francesco Allegretti, Willi Auwärter. Adsorption Conformation and Lateral Registry of Cobalt Porphine on Cu(111). The Journal of Physical Chemistry C 2018, 122 (10) , 5452-5461.
    7. Michael Lepper, Tobias Schmitt, Martin Gurrath, Marco Raschmann, Liang Zhang, Michael Stark, Helen Hölzel, Norbert Jux, Bernd Meyer, M. Alexander Schneider, Hans-Peter Steinrück, and Hubertus Marbach . Adsorption Behavior of a Cyano-Functionalized Porphyrin on Cu(111) and Ag(111): From Molecular Wires to Ordered Supramolecular Two-Dimensional Aggregates. The Journal of Physical Chemistry C 2017, 121 (47) , 26361-26371.
    8. Borja Cirera, Olga Trukhina, Jonas Björk, Giovanni Bottari, Jonathan Rodríguez-Fernández, Alberto Martin-Jimenez, Mikhail K. Islyaikin, Roberto Otero, José M. Gallego, Rodolfo Miranda, Tomás Torres, and David Ecija . Long-Range Orientational Self-Assembly, Spatially Controlled Deprotonation, and Off-Centered Metalation of an Expanded Porphyrin. Journal of the American Chemical Society 2017, 139 (40) , 14129-14136.
    9. H. Aldahhak, M. Paszkiewicz, F. Allegretti, D. A. Duncan, S. Tebi, P. S. Deimel, P. Casado Aguilar, Y.-Q. Zhang, A. C. Papageorgiou, R. Koch, J. V. Barth, W. G. Schmidt, S. Müllegger, W. Schöfberger, F. Klappenberger, E. Rauls, and U. Gerstmann . X-ray Spectroscopy of Thin Film Free-Base Corroles: A Combined Theoretical and Experimental Characterization. The Journal of Physical Chemistry C 2017, 121 (4) , 2192-2200.
    10. Bettina Wagner, Natalie Dehnhardt, Martin Schmid, Benedikt P. Klein, Lukas Ruppenthal, Philipp Müller, Malte Zugermeier, J. Michael Gottfried, Sina Lippert, Marc-Uwe Halbich, Arash Rahimi-Iman, and Johanna Heine . Color Change Effect in an Organic–Inorganic Hybrid Material Based on a Porphyrin Diacid. The Journal of Physical Chemistry C 2016, 120 (49) , 28363-28373.
    11. Florian Albrecht, Felix Bischoff, Willi Auwärter, Johannes V. Barth, and Jascha Repp . Direct Identification and Determination of Conformational Response in Adsorbed Individual Nonplanar Molecular Species Using Noncontact Atomic Force Microscopy. Nano Letters 2016, 16 (12) , 7703-7709.
    12. Manuel Gruber, Fatima Ibrahim, Samy Boukari, Loïc Joly, Victor Da Costa, Michał Studniarek, Moritz Peter, Hironari Isshiki, Hashim Jabbar, Vincent Davesne, Jacek Arabski, Edwige Otero, Fadi Choueikani, Kai Chen, Philippe Ohresser, Wulf Wulfhekel, Fabrice Scheurer, Eric Beaurepaire, Mebarek Alouani, Wolfgang Weber, and Martin Bowen . Spin-Dependent Hybridization between Molecule and Metal at Room Temperature through Interlayer Exchange Coupling. Nano Letters 2015, 15 (12) , 7921-7926.
    13. Christian Steiner, Bettina D. Gliemann, Ute Meinhardt, Martin Gurrath, Bernd Meyer, Milan Kivala, and Sabine Maier . Self-Assembly and Stability of Hydrogen-Bonded Networks of Bridged Triphenylamines on Au(111) and Cu(111). The Journal of Physical Chemistry C 2015, 119 (46) , 25945-25955.
    14. Vladimir V. Korolkov, Simon A. Svatek, Alex Summerfield, James Kerfoot, Lixu Yang, Takashi Taniguchi, Kenji Watanabe, Neil R. Champness, Nicholas A. Besley, and Peter H. Beton . van der Waals-Induced Chromatic Shifts in Hydrogen-Bonded Two-Dimensional Porphyrin Arrays on Boron Nitride. ACS Nano 2015, 9 (10) , 10347-10355.
    15. Michael Lepper, Liang Zhang, Michael Stark, Stefanie Ditze, Dominik Lungerich, Norbert Jux, Wolfgang Hieringer, Hans-Peter Steinrück, and Hubertus Marbach . Role of Specific Intermolecular Interactions for the Arrangement of Ni(II)-5, 10, 15, 20-Tetraphenyltetrabenzoporphyrin on Cu(111). The Journal of Physical Chemistry C 2015, 119 (34) , 19897-19905.
    16. Yi-Qi Zhang, Jonas Björk, Peter Weber, Raphael Hellwig, Katharina Diller, Anthoula C. Papageorgiou, Seung Cheol Oh, Sybille Fischer, Francesco Allegretti, Svetlana Klyatskaya, Mario Ruben, Johannes V. Barth, and Florian Klappenberger . Unusual Deprotonated Alkynyl Hydrogen Bonding in Metal-Supported Hydrocarbon Assembly. The Journal of Physical Chemistry C 2015, 119 (17) , 9669-9679.
    17. Grażyna Antczak, Wojciech Kamiński, and Karina Morgenstern . Stabilizing CuPc Coordination Networks on Ag(100) by Ag Atoms. The Journal of Physical Chemistry C 2015, 119 (3) , 1442-1450.
    18. Tao Lin, Guowen Kuang, Weihua Wang, and Nian Lin . Two-Dimensional Lattice of Out-of-Plane Dinuclear Iron Centers Exhibiting Kondo Resonance. ACS Nano 2014, 8 (8) , 8310-8316.
    19. Jing-Ying Gu, Ting Chen, Lin Wang, Wei-Long Dong, Hui-Juan Yan, Dong Wang, and Li-Jun Wan . Electrostatic-Interaction-Induced Molecular Deposition of a Hybrid Bilayer on Au(111): A Scanning Tunneling Microscopy Study. Langmuir 2014, 30 (12) , 3502-3506.
    20. Vinícius Claudio Zoldan, Ricardo Faccio, Chunlei Gao, and André Avelino Pasa . Coupling of Cobalt–Tetraphenylporphyrin Molecules to a Copper Nitride Layer. The Journal of Physical Chemistry C 2013, 117 (31) , 15984-15990.
    21. Felix Bischoff, Knud Seufert, Willi Auwärter, Sushobhan Joshi, Saranyan Vijayaraghavan, David Écija, Katharina Diller, Anthoula C. Papageorgiou, Sybille Fischer, Francesco Allegretti, David A. Duncan, Florian Klappenberger, Florian Blobner, Runyuan Han, and Johannes V. Barth . How Surface Bonding and Repulsive Interactions Cause Phase Transformations: Ordering of a Prototype Macrocyclic Compound on Ag(111). ACS Nano 2013, 7 (4) , 3139-3149.
    22. Rubén González-Moreno, Aran Garcia-Lekue, Andrés Arnau, Marta Trelka, José M. Gallego, Roberto Otero, Alberto Verdini, Carlos Sánchez-Sánchez, Pedro L. de Andrés, José Ángel Martín-Gago, and Celia Rogero . Role of the Anchored Groups in the Bonding and Self-Organization of Macrocycles: Carboxylic versus Pyrrole Groups. The Journal of Physical Chemistry C 2013, 117 (15) , 7661-7668.
    23. Jie Xiao, Stefanie Ditze, Min Chen, Florian Buchner, Michael Stark, Martin Drost, Hans-Peter Steinrück, J. Michael Gottfried, and Hubertus Marbach . Temperature-Dependent Chemical and Structural Transformations from 2H-tetraphenylporphyrin to Copper(II)-Tetraphenylporphyrin on Cu(111). The Journal of Physical Chemistry C 2012, 116 (22) , 12275-12282.
    24. Mohammad Rashidi, Stefan Müllegger, Manuel Roithner, Wolfgang Schöfberger, and Reinhold Koch . Spectroscopic Scanning Tunneling Microscopy Studies of Single Surface-Supported Free-Base Corroles. Journal of the American Chemical Society 2012, 134 (1) , 91-94.
    25. Florian Buchner, Jie Xiao, Elisabeth Zillner, Min Chen, Michael Röckert, Stefanie Ditze, Michael Stark, Hans-Peter Steinrück, J. Michael Gottfried, and Hubertus Marbach . Diffusion, Rotation, and Surface Chemical Bond of Individual 2H-Tetraphenylporphyrin Molecules on Cu(111). The Journal of Physical Chemistry C 2011, 115 (49) , 24172-24177.
    26. Geoffrey Rojas, Xumin Chen, Donna Kunkel, Matthias Bode, and Axel Enders . Temperature Dependence of Metal–Organic Heteroepitaxy. Langmuir 2011, 27 (23) , 14267-14271.
    27. Vincenzo Barone, Maurizio Casarin, Daniel Forrer, Susanna Monti, and Giacomo Prampolini . Molecular Dynamics Simulations of the Self-Assembly of Tetraphenylporphyrin-Based Monolayers and Bilayers at a Silver Interface. The Journal of Physical Chemistry C 2011, 115 (38) , 18434-18444.
    28. Martin Schmid, Johannes Zirzlmeier, Hans-Peter Steinrück, and J. Michael Gottfried . Interfacial Interactions of Iron(II) Tetrapyrrole Complexes on Au(111). The Journal of Physical Chemistry C 2011, 115 (34) , 17028-17035.
    29. Matthew S. Dyer, Abel Robin, Sam Haq, Rasmita Raval, Mats Persson, and Jiří Klimeš . Understanding the Interaction of the Porphyrin Macrocycle to Reactive Metal Substrates: Structure, Bonding, and Adatom Capture. ACS Nano 2011, 5 (3) , 1831-1838.
    30. Yiing Chin, Dwi Panduwinata, Maxine Sintic, Tze Jing Sum, Noel S. Hush, Maxwell J. Crossley, and Jeffrey R. Reimers . Atomic-Resolution Kinked Structure of an Alkylporphyrin on Highly Ordered Pyrolytic Graphite. The Journal of Physical Chemistry Letters 2011, 2 (2) , 62-66.
    31. Knud Seufert, Willi Auwärter, and Johannes V. Barth. Discriminative Response of Surface-Confined Metalloporphyrin Molecules to Carbon and Nitrogen Monoxide. Journal of the American Chemical Society 2010, 132 (51) , 18141-18146.
    32. David Écija, Knud Seufert, Daniel Heim, Willi Auwärter, Claudia Aurisicchio, Chiara Fabbro, Davide Bonifazi and Johannes V. Barth . Hierarchic Self-Assembly of Nanoporous Chiral Networks with Conformationally Flexible Porphyrins. ACS Nano 2010, 4 (8) , 4936-4942.
    33. Geoffrey Rojas, Xumin Chen, Cameron Bravo, Ji-Hyun Kim, Jae-Sung Kim, Jie Xiao, Peter A. Dowben, Yi Gao, Xiao Cheng Zeng, Wonyoung Choe and Axel Enders. Self-Assembly and Properties of Nonmetalated Tetraphenyl-Porphyrin on Metal Substrates. The Journal of Physical Chemistry C 2010, 114 (20) , 9408-9415.
    34. Benjamin W. Heinrich, Cristian Iacovita, Thomas Brumme, Deung-Jang Choi, Laurent Limot, Mircea V. Rastei, Werner A. Hofer, Jens Kortus and Jean-Pierre Bucher . Direct Observation of the Tunneling Channels of a Chemisorbed Molecule. The Journal of Physical Chemistry Letters 2010, 1 (10) , 1517-1523.
    35. Daniel Heim, David Écija, Knud Seufert, Willi Auwärter, Claudia Aurisicchio, Chiara Fabbro, Davide Bonifazi and Johannes V. Barth. Self-Assembly of Flexible One-Dimensional Coordination Polymers on Metal Surfaces. Journal of the American Chemical Society 2010, 132 (19) , 6783-6790.
    36. Joachim Reichert, Agustin Schiffrin, Willi Auwärter, Alexander Weber-Bargioni, Matthias Marschall, Martina Dell’Angela, Dean Cvetko, Gregor Bavdek, Albano Cossaro, Alberto Morgante and Johannes V. Barth . l-Tyrosine on Ag(111): Universality of the Amino Acid 2D Zwitterionic Bonding Scheme?. ACS Nano 2010, 4 (2) , 1218-1226.
    37. Min Li, Hai-Jun Xu, Ke Deng, Zhen Shen, Xiao-Zeng You, Qing-Dao Zeng and Chen Wang. Conformation-Dependent Stacking Behavior of Porphyrin Assemblies Observed by Using Scanning Tunneling Microscopy. The Journal of Physical Chemistry C 2010, 114 (4) , 1881-1884.
    38. Daniel Heim, Knud Seufert, Willi Auwärter, Claudia Aurisicchio, Chiara Fabbro, Davide Bonifazi and Johannes V. Barth . Surface-Assisted Assembly of Discrete Porphyrin-Based Cyclic Supramolecules. Nano Letters 2010, 10 (1) , 122-128.
    39. Stefan Müllegger, Wolfgang Schöfberger, Mohammad Rashidi, Lorenz M. Reith and Reinhold Koch. Spectroscopic STM Studies of Single Gold(III) Porphyrin Molecules. Journal of the American Chemical Society 2009, 131 (49) , 17740-17741.
    40. Florian Buchner, Karl-Georg Warnick, Thorsten Wölfle, Andreas Görling, Hans-Peter Steinrück, Wolfgang Hieringer and Hubertus Marbach . Chemical Fingerprints of Large Organic Molecules in Scanning Tunneling Microscopy: Imaging Adsorbate−Substrate Coupling of Metalloporphyrins. The Journal of Physical Chemistry C 2009, 113 (37) , 16450-16457.
    41. Agustin Schiffrin, Joachim Reichert, Yan Pennec, Willi Auwärter, Alexander Weber-Bargioni, Matthias Marschall, Martina Dell’Angela, Dean Cvetko, Gregor Bavdek, Albano Cossaro, Alberto Morgante and Johannes V. Barth . Self-Assembly of l-Methionine on Cu(111): Steering Chiral Organization by Substrate Reactivity and Thermal Activation. The Journal of Physical Chemistry C 2009, 113 (28) , 12101-12108.
    42. Ziliang Shi and Nian Lin. Porphyrin-Based Two-Dimensional Coordination Kagome Lattice Self-Assembled on a Au(111) Surface. Journal of the American Chemical Society 2009, 131 (15) , 5376-5377.
    43. Kai Iketaki, Kaname Kanai, Akihiro Shimizu, Takashi Kubo, Zhi-Hong Wang, Yukio Ouchi, Yasushi Morita, Kazuhiro Nakasuji and Kazuhiko Seki. Scanning Tunneling Microscopy Study of a Phenalenyl-Based Singlet Biradical on Graphite. The Journal of Physical Chemistry C 2009, 113 (4) , 1515-1519.
    44. M. Eichberger, M. Marschall, J. Reichert, A. Weber-Bargioni, W. Auwärter, R. L. C. Wang, H. J. Kreuzer, Y. Pennec, A. Schiffrin and J. V. Barth . Dimerization Boosts One-Dimensional Mobility of Conformationally Adapted Porphyrins on a Hexagonal Surface Atomic Lattice. Nano Letters 2008, 8 (12) , 4608-4613.
    45. Soichiro Yoshimoto and Takahiro Sawaguchi. Electrostatically Controlled Nanostructure of Cationic Porphyrin Diacid on Sulfate/Bisulfate Adlayer at Electrochemical Interface. Journal of the American Chemical Society 2008, 130 (47) , 15944-15949.
    46. Stefan Kuck, Germar Hoffmann, Martin Bröring, Martin Fechtel, Markus Funk and Roland Wiesendanger . “Naked” Iron-5,10,15-triphenylcorrole on Cu(111): Observation of Chirality on a Surface and Manipulation of Multiple Conformational States by STM. Journal of the American Chemical Society 2008, 130 (43) , 14072-14073.
    47. U. Schlickum, R. Decker, F. Klappenberger, G. Zoppellaro, S. Klyatskaya, W. Auwärter, S. Neppl, K. Kern, H. Brune, M. Ruben and J. V. Barth . Chiral Kagomé Lattice from Simple Ditopic Molecular Bricks. Journal of the American Chemical Society 2008, 130 (35) , 11778-11782.
    48. Yun Bai,, Florian Buchner,, Matthew T. Wendahl,, Ina Kellner,, Andreas Bayer,, Hans-Peter Steinrück,, Hubertus Marbach, and, J. Michael Gottfried. Direct Metalation of a Phthalocyanine Monolayer on Ag(111) with Coadsorbed Iron Atoms. The Journal of Physical Chemistry C 2008, 112 (15) , 6087-6092.
    49. Matthew A. Stoodley, Benedikt P. Klein, Michael Clarke, Leon B.S. Williams, Luke A. Rochford, Pilar Ferrer, David C. Grinter, Alex Saywell, David A. Duncan. Adsorption structure of iron phthalocyanine and titanyl phthalocyanine on Cu(1 1 1). Inorganica Chimica Acta 2023, 557 , 121679.
    50. Isheta Majumdar, Francesco Goto, Alberto Calloni, Guglielmo Albani, Lamberto Duò, Marco Finazzi, Franco Ciccacci:, Gianlorenzo Bussetti. Porphyrin central metal ion driven self-assembling in heterogeneous ZnTPP – CoTPP films grown on Fe(0 0 1)-p(1 × 1)O. Applied Surface Science 2023, 636 , 157807.
    51. Hongxing Yuan, Xinhao Wan, Jianqi Ye, Tuotuo Ma, Fangyuan Ma, Jie Gao, Wei Gao, Dan Wen. Molecular Engineering of Noble Metal Aerogels Boosting Electrocatalytic Oxygen Reduction. Advanced Functional Materials 2023, 33 (37)
    52. José J. Ortiz-Garcia, Rebecca C. Quardokus. Influence of local chemical environment and external perturbations of porphyrins on surfaces. Journal of Vacuum Science & Technology A 2023, 41 (3)
    53. Hao Tang, Corentin Durand, Roland Coratger. Adsorption of single metallic atoms on self-assembled molecular domain of terephthalic acid. Surfaces and Interfaces 2021, 25 , 101170.
    54. Laëtitia Farinacci, Gelavizh Ahmadi, Michael Ruby, Gaël Reecht, Benjamin W. Heinrich, Constantin Czekelius, Felix von Oppen, Katharina J. Franke. Interfering Tunneling Paths through Magnetic Molecules on Superconductors: Asymmetries of Kondo and Yu-Shiba-Rusinov Resonances. Physical Review Letters 2020, 125 (25)
    55. Marta Penconi, Rossella Yivlialin, Gianlorenzo Bussetti, Lamberto Duò, Alberto Bossi, Alessio Orbelli Biroli. Customised porphyrin coating films for graphite electrode protection: An investigation on the role of peripheral groups by coupled AFM and cyclic voltammetry techniques. Applied Surface Science 2020, 507 , 145055.
    56. Vladimir V. Arslanov, Maria A. Kalinina, Elizaveta V. Ermakova, Oleg A. Raitman, Yulia G. Gorbunova, Oleg E. Aksyutin, Alexander G. Ishkov, Vladimir A. Grachev, Aslan Yu. Tsivadze. Hybrid materials based on graphene derivatives and porphyrin metal-organic frameworks. Russian Chemical Reviews 2019, 88 (8) , 775-799.
    57. Arnulf Stein, Daniela Rolf, Christian Lotze, Constantin Czekelius, Katharina J Franke, Petra Tegeder. Electronic structure of an iron porphyrin derivative on Au(1 1 1). Journal of Physics: Condensed Matter 2019, 31 (4) , 044002.
    58. Martin Schwarz, David A. Duncan, Manuela Garnica, Jacob Ducke, Peter S. Deimel, Pardeep K. Thakur, Tien-Lin Lee, Francesco Allegretti, Willi Auwärter. Quantitative determination of a model organic/insulator/metal interface structure. Nanoscale 2018, 10 (46) , 21971-21977.
    59. Michael Lepper, Julia Köbl, Liang Zhang, Manuel Meusel, Helen Hölzel, Dominik Lungerich, Norbert Jux, Abner de Siervo, Bernd Meyer, Hans‐Peter Steinrück, Hubertus Marbach. Kontrolle der Selbstmetallierungsrate von Tetraphenylporphyrinen auf Cu(111) durch Funktionalisierung mit Cyangruppen. Angewandte Chemie 2018, 130 (32) , 10230-10236.
    60. Michael Lepper, Julia Köbl, Liang Zhang, Manuel Meusel, Helen Hölzel, Dominik Lungerich, Norbert Jux, Abner de Siervo, Bernd Meyer, Hans‐Peter Steinrück, Hubertus Marbach. Controlling the Self‐Metalation Rate of Tetraphenylporphyrins on Cu(111) via Cyano Functionalization. Angewandte Chemie International Edition 2018, 57 (32) , 10074-10079.
    61. Harald Zaglmayr, Thomas Lackner, Lidong Sun, Peter Zeppenfeld. Growth of tetraphenyl-porphyrin thin films on Ag(111). Synthetic Metals 2017, 228 , 64-69.
    62. Xianwen Chen, Shulai Lei, Christian Lotze, Constantin Czekelius, Beate Paulus, Katharina J. Franke. Conformational adaptation and manipulation of manganese tetra(4-pyridyl)porphyrin molecules on Cu(111). The Journal of Chemical Physics 2017, 146 (9)
    63. Michael Lepper, Julia Köbl, Tobias Schmitt, Martin Gurrath, Abner de Siervo, M. Alexander Schneider, Hans-Peter Steinrück, Bernd Meyer, Hubertus Marbach, Wolfgang Hieringer. “Inverted” porphyrins: a distorted adsorption geometry of free-base porphyrins on Cu(111). Chemical Communications 2017, 53 (58) , 8207-8210.
    64. . Physisorbed Layers at Interfaces. 2016, 168-251.
    65. Liang Zhang, Michael Lepper, Michael Stark, Ralf Schuster, Dominik Lungerich, Norbert Jux, Hans‐Peter Steinrück, Hubertus Marbach. 2 H ‐Tetrakis(3,5‐di‐ tert ‐butyl)phenylporphyrin on a Cu(110) Surface: Room‐Temperature Self‐Metalation and Surface‐Reconstruction‐Facilitated Self‐Assembly. Chemistry – A European Journal 2016, 22 (10) , 3347-3354.
    66. Cici Wang, Qitang Fan, Yong Han, José I. Martínez, José A. Martín-Gago, Weijia Wang, Huanxin Ju, J. Michael Gottfried, Junfa Zhu. Metalation of tetraphenylporphyrin with nickel on a TiO 2 (110)-1 × 2 surface. Nanoscale 2016, 8 (2) , 1123-1132.
    67. B. Cirera, L. Đorđević, R. Otero, J. M. Gallego, D. Bonifazi, R. Miranda, D. Ecija. Dysprosium-carboxylate nanomeshes with tunable cavity size and assembly motif through ionic interactions. Chemical Communications 2016, 52 (75) , 11227-11230.
    68. Yuxu Wang, Kun Zhou, Ziliang Shi, Yu-qiang Ma. Structural reconstruction and spontaneous formation of Fe polynuclears: a self-assembly of Fe–porphyrin coordination chains on Au(111) revealed by scanning tunneling microscopy. Physical Chemistry Chemical Physics 2016, 18 (21) , 14273-14278.
    69. J. Michael Gottfried. Surface chemistry of porphyrins and phthalocyanines. Surface Science Reports 2015, 70 (3) , 259-379.
    70. Willi Auwärter, David Écija, Florian Klappenberger, Johannes V. Barth. Porphyrins at interfaces. Nature Chemistry 2015, 7 (2) , 105-120.
    71. Katharina Diller, Florian Klappenberger, Francesco Allegretti, Anthoula C. Papageorgiou, Sybille Fischer, David A. Duncan, Reinhard J. Maurer, Julian A. Lloyd, Seung Cheol Oh, Karsten Reuter, Johannes V. Barth. Temperature-dependent templated growth of porphine thin films on the (111) facets of copper and silver. The Journal of Chemical Physics 2014, 141 (14)
    72. Florian Klappenberger. Two-dimensional functional molecular nanoarchitectures – Complementary investigations with scanning tunneling microscopy and X-ray spectroscopy. Progress in Surface Science 2014, 89 (1) , 1-55.
    73. H. Marbach, H.-P. Steinrück. Studying the dynamic behaviour of porphyrins as prototype functional molecules by scanning tunnelling microscopy close to room temperature. Chem. Commun. 2014, 50 (65) , 9034-9048.
    74. Cici Wang, Qitang Fan, Shanwei Hu, Huanxin Ju, Xuefei Feng, Yong Han, Haibin Pan, Junfa Zhu, J. Michael Gottfried. Coordination reaction between tetraphenylporphyrin and nickel on a TiO 2 (110) surface. Chem. Commun. 2014, 50 (61) , 8291-8294.
    75. Dennis van Vörden, Manfred Lange, Johannes Schaffert, Maren C. Cottin, Merlin Schmuck, Roberto Robles, Heiko Wende, Christian A. Bobisch, Rolf Möller. Surface‐Induced Dechlorination of FeOEPCl on Cu(111). ChemPhysChem 2013, 14 (15) , 3472-3475.
    76. José M. Gallego, Roberto Otero, Rodolfo Miranda. The Growth of Organic Nanomaterials by Molecular Self‐Assembly at Solid Surfaces. 2013, 421-446.
    77. K. Diller, F. Klappenberger, F. Allegretti, A. C. Papageorgiou, S. Fischer, A. Wiengarten, S. Joshi, K. Seufert, D. Écija, W. Auwärter, J. V. Barth. Investigating the molecule-substrate interaction of prototypic tetrapyrrole compounds: Adsorption and self-metalation of porphine on Cu(111). The Journal of Chemical Physics 2013, 138 (15)
    78. Nobuo Ueno, Satoshi Kera, Kaname Kanai. Fundamental Electronic Structure of Organic Solids and Their Interfaces by Photoemission Spectroscopy and Related Methods. 2013, 173-217.
    79. Thanh Hai Phan, Klaus Wandelt. Self-assembly of metal free porphyrin layers at copper-electrolyte interfaces: Dependence on substrate symmetry. Surface Science 2013, 607 , 82-91.
    80. Khaoula Boukari, Philippe Sonnet, Eric Duverger. DFT‐D Studies of Single Porphyrin Molecule on Doped Boron Silicon Surfaces. ChemPhysChem 2012, 13 (17) , 3945-3951.
    81. C. S. Guo, L. Sun, K. Hermann, C. F. Hermanns, M. Bernien, W. Kuch. X-ray absorption from large molecules at metal surfaces: Theoretical and experimental results for Co-OEP on Ni(100). The Journal of Chemical Physics 2012, 137 (19)
    82. Niko Pavliček, Benoit Fleury, Mathias Neu, Judith Niedenführ, Coral Herranz-Lancho, Mario Ruben, Jascha Repp. Atomic Force Microscopy Reveals Bistable Configurations of Dibenzo[a,h]thianthrene and their Interconversion Pathway. Physical Review Letters 2012, 108 (8)
    83. K. Diller, F. Klappenberger, M. Marschall, K. Hermann, A. Nefedov, Ch. Wöll, J. V. Barth. Self-metalation of 2H-tetraphenylporphyrin on Cu(111): An x-ray spectroscopy study. The Journal of Chemical Physics 2012, 136 (1)
    84. Javier Saiz-Poseu, Alberto Martínez-Otero, Thomas Roussel, Joseph K.-H. Hui, Mavis L. Montero, Roberto Urcuyo, Mark J. MacLachlan, Jordi Faraudo, Daniel Ruiz-Molina. Self-assembly of a catechol-based macrocycle at the liquid–solid interface: experiments and molecular dynamics simulations. Physical Chemistry Chemical Physics 2012, 14 (34) , 11937.
    85. Albano Cossaro, Dean Cvetko, Luca Floreano. Amino–carboxylic recognition on surfaces: from 2D to 2D + 1 nano-architectures. Physical Chemistry Chemical Physics 2012, 14 (38) , 13154.
    86. Giovanni Di Santo, Stephan Blankenburg, Carla Castellarin‐Cudia, Mattia Fanetti, Patrizia Borghetti, Luigi Sangaletti, Luca Floreano, Alberto Verdini, Elena Magnano, Federica Bondino, Carlo A. Pignedoli, Manh‐Thuong Nguyen, Roberto Gaspari, Daniele Passerone, Andrea Goldoni. Supramolecular Engineering through Temperature‐Induced Chemical Modification of 2 H ‐Tetraphenylporphyrin on Ag(111): Flat Phenyl Conformation and Possible Dehydrogenation Reactions. Chemistry – A European Journal 2011, 17 (51) , 14354-14359.
    87. Florian Buchner, Elisabeth Zillner, Michael Röckert, Stefanie Gläßel, Hans‐Peter Steinrück, Hubertus Marbach. Substrate‐Mediated Phase Separation of Two Porphyrin Derivatives on Cu(111). Chemistry – A European Journal 2011, 17 (37) , 10226-10229.
    88. Chr. Hamann, R. Woltmann, I-Po Hong, N. Hauptmann, S. Karan, R. Berndt. Ultrahigh vacuum deposition of organic molecules by electrospray ionization. Review of Scientific Instruments 2011, 82 (3)
    89. Marta Trelka, Christian Urban, Celia Rogero, Paula de Mendoza, Eva Mateo-Marti, Yang Wang, Iñaki Silanes, David Écija, Manuel Alcamí, Felix Yndurain, Andrés Arnau, Fernando Martín, Antonio M. Echavarren, JoséÁngel Martín-Gago, José María Gallego, Roberto Otero, Rodolfo Miranda. Surface assembly of porphyrin nanorods with one-dimensional zinc–oxygen spinal cords. CrystEngComm 2011, 13 (18) , 5591.
    90. N. Schmidt, C. Hub, J.-F. Gnichwitz, W. Hieringer, A. Hirsch, R. H. Fink. Structure, morphology and interface properties of ultrathin SnTTBPP(OH)2-films adsorbed on Ag(100). Physical Chemistry Chemical Physics 2011, 13 (20) , 9839.
    91. Armin Gölzhäuser, Christof Wöll. Interfacial Systems Chemistry: Out of the Vacuum—Through the Liquid—Into the Cell. ChemPhysChem 2010, 11 (15) , 3201-3213.
    92. Philip Donovan, Abel Robin, Matthew S. Dyer, Mats Persson, Rasmita Raval. Unexpected Deformations Induced by Surface Interaction and Chiral Self‐Assembly of Co II ‐Tetraphenylporphyrin (Co‐TPP) Adsorbed on Cu(110): A Combined STM and Periodic DFT Study. Chemistry – A European Journal 2010, 16 (38) , 11641-11652.
    93. Stefan Mohnani, Davide Bonifazi. Supramolecular architectures of porphyrins on surfaces: The structural evolution from 1D to 2D to 3D to devices. Coordination Chemistry Reviews 2010, 254 (19-20) , 2342-2362.
    94. Norman Anja Schmidt, Rainer Fink, Wolfgang Hieringer. Assignment of near-edge x-ray absorption fine structure spectra of metalloporphyrins by means of time-dependent density-functional calculations. The Journal of Chemical Physics 2010, 133 (5)
    95. Willi Auwärter, Knud Seufert, Florian Klappenberger, Joachim Reichert, Alexander Weber-Bargioni, Alberto Verdini, Dean Cvetko, Martina Dell’Angela, Luca Floreano, Albano Cossaro, Gregor Bavdek, Alberto Morgante, Ari P. Seitsonen, Johannes V. Barth. Site-specific electronic and geometric interface structure of Co-tetraphenyl-porphyrin layers on Ag(111). Physical Review B 2010, 81 (24)
    96. Thomas Waldmann, Robert Reichert, Harry E. Hoster. Substrate Registry in Disordered Layers of Large Molecules. ChemPhysChem 2010, 11 (7) , 1513-1517.
    97. Zhi-Yong Yang, Colm Durkan. Edge and terrace structure of CoTPP on Au(1 1 1) investigated by ultra-high vacuum scanning tunnelling microscopy at room temperature. Surface Science 2010, 604 (7-8) , 660-665.
    98. Ziliang Shi, Nian Lin. Self-Assembly of a Two-Dimensional Bimetallic Coordination Framework and Dynamic Control of Reversible Conversions to Homo-Metallic Hydrogen-Bond Arrays. ChemPhysChem 2010, 11 (1) , 97-100.
    99. Soichiro Yoshimoto, Nagao Kobayashi. Supramolecular Nanostructures of Phthalocyanines and Porphyrins at Surfaces Based on the “Bottom-Up Assembly”. 2010, 137-167.
    100. Florian Buchner. Multicomponent Adlayers of Tetraphenylporphyrins on Ag(111). 2010, 101-128.
    Load all citations

    Pair your accounts.

    Export articles to Mendeley

    Get article recommendations from ACS based on references in your Mendeley library.

    Pair your accounts.

    Export articles to Mendeley

    Get article recommendations from ACS based on references in your Mendeley library.

    You’ve supercharged your research process with ACS and Mendeley!

    STEP 1:
    Click to create an ACS ID

    Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

    Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

    Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

    Your Mendeley pairing has expired. Please reconnect