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Highly Enantioselective Insertion of Carbenoids into O−H Bonds of Phenols:  An Efficient Approach to Chiral α-Aryloxycarboxylic Esters

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    Highly Enantioselective Insertion of Carbenoids into O−H Bonds of Phenols:  An Efficient Approach to Chiral α-Aryloxycarboxylic Esters
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    State Key Laboratory and Institute of Elemento-organic Chemistry, Nankai University, Tianjin 300071, China, and Institute of Fine Chemicals, East China University of Science and Technology, Shanghai 200237, China
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    Cite this: J. Am. Chem. Soc. 2007, 129, 42, 12616–12617
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    https://doi.org/10.1021/ja074729k
    Published September 29, 2007
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    Abstract

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    A highly efficient copper-catalyzed asymmetric carbenoid insertion into O−H bonds of phenols has been realized by using chiral spiro bisoxazoline ligands, affording α-aryloxypropionates and the related propionic acids in high yields with excellent enantiomeric excesses.

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     East China University of Science and Technology.

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     Nankai University.

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    Cite this: J. Am. Chem. Soc. 2007, 129, 42, 12616–12617
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