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Low-Temperature Rapid Synthesis and Superconductivity of Fe-Based Oxypnictide Superconductors

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CAS Key Laboratory of Materials for Energy Conversion, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, P.R. China, and State Key Laboratory of Functional Materials for Informatics, Shanghai Institute of Microsystem and Information Technology, Chinese Academy of Sciences, Shanghai 200050, P.R. China
[email protected]
†Shanghai Institute of Ceramics.
‡Shanghai Institute of Microsystem and Information Technology.
Cite this: J. Am. Chem. Soc. 2010, 132, 10, 3260–3261
Publication Date (Web):February 19, 2010
https://doi.org/10.1021/ja100055k
Copyright © 2010 American Chemical Society
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Abstract

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Fe-based oxypnictide superconductors were successfully synthesized at lower reaction temperatures and with shorter reaction times made possible by starting with less stable compounds, which provide a larger driving force for reactions. Using ball-milled powders of intermediate compounds, phase-pure superconductors with Tc above 50 K were synthesized at 1173 K in 20 min. This method is particularly advantageous for retaining F, a volatile dopant that enhances superconductivity. Bulk superconductivity and high upper critical fields up to 392 T in Sm0.85Nd0.15FeAsO0.85F0.15 were demonstrated.

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Methods for sample preparation and Rietveld refinements, property measurements, resistivity−temperature measurements of selected samples at different magnetic fields and tabulation of Tconset. This material is available free of charge via the Internet at http://pubs.acs.org.

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