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Patterning Graphene through the Self-Assembled Templates: Toward Periodic Two-Dimensional Graphene Nanostructures with Semiconductor Properties

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Departments of Chemistry, Computer Science, Mechanical Engineering and Materials Science, and Smalley Institute for Nanoscale Science and Technology, Rice University, MS 222, 6100 Main Street, Houston, Texas 77005
[email protected]
†Department of Chemistry.
‡Departments of Computer Science, Mechanical Engineering and Materials Science, and Smalley Institute for Nanoscale Science and Technology.
Cite this: J. Am. Chem. Soc. 2010, 132, 42, 14730–14732
Publication Date (Web):October 1, 2010
https://doi.org/10.1021/ja105426h
Copyright © 2010 American Chemical Society
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    Abstract

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    Periodic graphene nanostructures are fabricated via patterning graphene through the self-assembled monolayers of monodisperse colloidal microspheres. The resulting structures exhibit promising electronic properties featuring high conductivities and ON−OFF ratios up to 10. The apparent advantages of the presented method are the possibilities of fabricating periodic graphene nanostructures with different periodicities, ranging from ∼100 nm to several μm, and also varying the periodicity and the neck width independently. The use of the presented method yields graphene nanostructures with variable electronic properties.

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