logo

OR SEARCH CITATIONS

My Activity
Publications
CONTENT TYPES

Figure 1Loading Img
Download Hi-Res ImageDownload to MS-PowerPointCite This:J. Am. Chem. Soc. 2011, 133, 46, 18570-18573
RETURN TO ISSUEPREVCommunicationNEXT

Proton-Coupled Electron Shuttling in a Covalently Linked Ruthenium–Copper Heterodinuclear Complex

View Author Information
Department of Chemistry, Graduate School of Pure and Applied Sciences, University of Tsukuba, 1-1-1 Tennoudai, Tsukuba, Ibaraki 305-8571, Japan
Department of Material and Life Science, Graduate School of Engineering, Osaka University, and ALCA, Japan Science and Technology Agency, 2-1 Yamada-oka, Suita, Osaka 565-0871, Japan
Institute for Materials Chemistry and Engineering, Kyushu University, Motooka, Nishi-Ku, Fukuoka 819-0395, Japan
Department of Bioinsipired Science (WCU Project), Ewha Womans University, Seoul 120-750, South Korea
[email protected]; [email protected]
Cite this: J. Am. Chem. Soc. 2011, 133, 46, 18570–18573
Publication Date (Web):October 24, 2011
https://doi.org/10.1021/ja208141b
Copyright © 2011 American Chemical Society
RIGHTS & PERMISSIONS
Article Views
1767
Altmetric
-
Citations
16
LEARN ABOUT THESE METRICS

Article Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.

Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.

The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated.

Read OnlinePDF (1 MB)
Get e-Alerts
Supporting Info (2)»
SUBJECTS:

Abstract

Abstract Image

A heterodinuclear complex based on a RuII–TPA [TPA = tris(2-pyridylmethyl)amine] complex having a peripheral CuII(bpy)2 (bpy = 2,2′-bipyridine) group bonded through an amide linkage displayed reversible intramolecular electron transfer between the Ru and Cu complex units that can be controlled by protonation and deprotonation of the bridging amide moiety.

Supporting Information

ARTICLE SECTIONS
Jump To

Synthetic details, computational details, spectroscopic titrations, electrochemical data, complete ref 3c, and crystallographic data for 3·PF6 (CIF). This material is available free of charge via the Internet at http://pubs.acs.org.

Terms & Conditions

Most electronic Supporting Information files are available without a subscription to ACS Web Editions. Such files may be downloaded by article for research use (if there is a public use license linked to the relevant article, that license may permit other uses). Permission may be obtained from ACS for other uses through requests via the RightsLink permission system: http://pubs.acs.org/page/copyright/permissions.html.

Cited By

This article is cited by 16 publications.

  1. Fritz Weisser, Sebastian Plebst, Stephan Hohloch, Margarethe van der Meer, Sinja Manck, Felix Führer, Vanessa Radtke, Daniel Leichnitz, and Biprajit Sarkar . Tuning Ligand Effects and Probing the Inner-Workings of Bond Activation Steps: Generation of Ruthenium Complexes with Tailor-Made Properties. Inorganic Chemistry 2015, 54 (10) , 4621-4635. https://doi.org/10.1021/ic502807d
  2. Sai-Ho Lee, Chris Tsz-Leung Chan, Keith Man-Chung Wong, Wai Han Lam, Wai-Ming Kwok, and Vivian Wing-Wah Yam . Design and Synthesis of Bipyridine Platinum(II) Bisalkynyl Fullerene Donor–Chromophore–Acceptor Triads with Ultrafast Charge Separation. Journal of the American Chemical Society 2014, 136 (28) , 10041-10052. https://doi.org/10.1021/ja5040073
  3. Lina Ding, Lung Wa Chung, and Keiji Morokuma . Excited-State Proton Transfer Controls Irreversibility of Photoisomerization in Mononuclear Ruthenium(II) Monoaquo Complexes: A DFT Study. Journal of Chemical Theory and Computation 2014, 10 (2) , 668-675. https://doi.org/10.1021/ct400982r
  4. Dinesh Maity, Chanchal Bhaumik, Srikanta Karmakar, and Sujoy Baitalik . Photoinduced Electron and Energy Transfer and pH-Induced Modulation of the Photophysical Properties in Homo- and Heterobimetallic Complexes of Ruthenium(II) and Rhodium(III) Based on a Heteroditopic Phenanthroline–Terpyridine Bridge. Inorganic Chemistry 2013, 52 (14) , 7933-7946. https://doi.org/10.1021/ic400449c
  5. Shyamal Das, Debasish Saha, Srikanta Karmakar, and Sujoy Baitalik . Effect of pH on the Photophysical and Redox Properties of a Ruthenium(II) Mixed Chelate Derived from Imidazole-4,5-dicarboxylic Acid and 2,2′-Bipyridine: An Experimental and Theoretical Investigation. The Journal of Physical Chemistry A 2012, 116 (21) , 5216-5226. https://doi.org/10.1021/jp300820p
  6. Takahiko Kojima. Development of functionality of metal complexes based on proton-coupled electron transfer. Dalton Transactions 2020, 49 (22) , 7284-7293. https://doi.org/10.1039/D0DT00898B
  7. Mariia Karpacheva, Frederik J. Malzner, Cedric Wobill, Annika Büttner, Edwin C. Constable, Catherine E. Housecroft. Cuprophilia: Dye-sensitized solar cells with copper(I) dyes and copper(I)/(II) redox shuttles. Dyes and Pigments 2018, 156 , 410-416. https://doi.org/10.1016/j.dyepig.2018.04.033
  8. Nicolas Queyriaux, Eugen S. Andreiadis, Stéphane Torelli, Jacques Pecaut, Brad S. Veldkamp, Eric A. Margulies, Michael R. Wasielewski, Murielle Chavarot-Kerlidou, Vincent Artero. CuAAC-based assembly and characterization of a ruthenium–copper dyad containing a diimine–dioxime ligand framework. Faraday Discussions 2017, 198 , 251-261. https://doi.org/10.1039/C6FD00204H
  9. Vivian Wing-Wah Yam. Metal-Based Molecular Functional Materials - From Discrete Metal Complexes to Supramolecular Assembly, Nanostructures and Functions. Bulletin of Japan Society of Coordination Chemistry 2017, 69 (0) , 21-28. https://doi.org/10.4019/bjscc.69.21
  10. Marek B. Majewski, Jeremy G. Smith, Michael O. Wolf, Brian O. Patrick. Long-Lived, Emissive Excited States in Direct and Amide-Linked Thienyl-Substituted Ru II Complexes. European Journal of Inorganic Chemistry 2016, 2016 (10) , 1470-1479. https://doi.org/10.1002/ejic.201501436
  11. Dinesh Maity, Sourav Mardanya, Srikanta Karmakar, Sujoy Baitalik. pH-Induced processes in wire-like multichromophoric homo- and heterotrimetallic complexes of Fe( ii ), Ru( ii ), and Os( ii ). Dalton Transactions 2015, 44 (21) , 10048-10059. https://doi.org/10.1039/C5DT00708A
  12. Francis D'Souza, Hiroshi Imahori. Preface — Special Issue in Honor of Professor Shunichi Fukuzumi. Journal of Porphyrins and Phthalocyanines 2015, 19 (01-03) , i-xvi. https://doi.org/10.1142/S1088424615020010
  13. Sai-Ho Lee, Chris Tsz-Leung Chan, Keith Man-Chung Wong, Wai Han Lam, Wai-Ming Kwok, Vivian Wing-Wah Yam. Synthesis and photoinduced electron transfer in platinum( ii ) bis(N-(4-ethynylphenyl)carbazole)bipyridine fullerene complexes. Dalton Trans. 2014, 43 (47) , 17624-17634. https://doi.org/10.1039/C4DT01397B
  14. Shunichi Fukuzumi. Electron-transfer properties of high-valent metal-oxo complexes. Coordination Chemistry Reviews 2013, 257 (9-10) , 1564-1575. https://doi.org/10.1016/j.ccr.2012.07.021
  15. Debasish Saha, Shyamal Das, Srikanta Karmakar, Supriya Dutta, Sujoy Baitalik. Synthesis, structural characterization and anion-, cation- and solvent-induced tuning of photophysical properties of a bimetallic Ru(ii) complex: combined experimental and DFT/TDDFT investigation. RSC Advances 2013, 3 (38) , 17314. https://doi.org/10.1039/c3ra41114a
  16. Shyamal Das, Debasish Saha, Sourav Mardanya, Sujoy Baitalik. A combined experimental and DFT/TDDFT investigation of structural, electronic, and pH-induced tuning of photophysical and redox properties of osmium(ii) mixed-chelates derived from imidazole-4,5-dicarboxylic acid and 2,2′-bipyridine. Dalton Transactions 2012, 41 (39) , 12296. https://doi.org/10.1039/c2dt31321a

Pair your accounts.

Export articles to Mendeley

Get article recommendations from ACS based on references in your Mendeley library.

Pair your accounts.

Export articles to Mendeley

Get article recommendations from ACS based on references in your Mendeley library.

You’ve supercharged your research process with ACS and Mendeley!

STEP 1:
Click to create an ACS ID

Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

OOPS

You have to login with your ACS ID befor you can login with your Mendeley account.

MENDELEY PAIRING EXPIRED
Your Mendeley pairing has expired. Please reconnect

This website uses cookies to improve your user experience. By continuing to use the site, you are accepting our use of cookies. Read the ACS privacy policy.

CONTINUE