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Preparation of Alkyl-Modified Silicon Nanosheets by Hydrosilylation of Layered Polysilane (Si6H6)

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Toyota Central R&D Laboratories., Inc., Nagakute, Aichi, 480-1192, Japan
SR Center, Ritsumeikan University, Noji-Higashi, Kusatsu, Shiga, 525-8577, Japan
Department of Applied Chemistry, Graduate School of Engineering, Hiroshima University, Higashi-Hiroshima, Hiroshima 739-8527, Japan
Cite this: J. Am. Chem. Soc. 2012, 134, 12, 5452–5455
Publication Date (Web):March 13, 2012
Copyright © 2012 American Chemical Society

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    Alkyl-modified crystalline silicon nanosheets 2 were synthesized and maintained the crystal structure of a Si(111) plane, in which the dangling silicon bond is stabilized by capping with the alkyl group. 2 was characterized using UV–vis, Fourier transform-infrared, and X-ray photoelectron spectroscopies; X-ray diffraction; and X-ray absorption near edge structure analysis. A model structure is proposed that has a periodicity through the nanosheet surface.

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