ACS Publications. Most Trusted. Most Cited. Most Read
CONTENT TYPES

Figure 1Loading Img

System Message

The ACS Publications site will be temporarily unavailable for planned maintenance on Friday, Oct. 15 starting at 6:00 pm ET for up to 4 hours. We apologize for this inconvenience.

Interactive Forces between Sodium Dodecyl Sulfate-Suspended Single-Walled Carbon Nanotubes and Agarose Gels

View Author Information
Department of Environmental Engineering Sciences and Department of Chemical Engineering, University of Florida, Gainesville, Florida 32611, United States
Cite this: J. Am. Chem. Soc. 2013, 135, 47, 17758–17767
Publication Date (Web):October 28, 2013
https://doi.org/10.1021/ja4052526
Copyright © 2013 American Chemical Society
Article Views
2492
Altmetric
-
Citations
LEARN ABOUT THESE METRICS
Read OnlinePDF (2 MB)
Supporting Info (1)»

Abstract

Abstract Image

Selective adsorption onto agarose gels has become a powerful method to separate single-walled carbon nanotubes (SWCNTs). A better understanding of the nature of the interactive forces and specific sites responsible for adsorption should lead to significant improvements in the selectivity and yield of these separations. A combination of nonequilibrium and equilibrium studies are conducted to explore the potential role that van der Waals, ionic, hydrophobic, π–π, and ion–dipole interactions have on the selective adsorption between agarose and SWCNTs suspended with sodium dodecyl sulfate (SDS). The results demonstrate that any modification to the agarose gel surface and, consequently, the permanent dipole moments of agarose drastically reduces the retention of SWCNTs. Because these permanent dipoles are critical to retention and the fact that SDS–SWCNTs function as macro-ions, it is proposed that ion–dipole forces are the primary interaction responsible for adsorption. The selectivity of adsorption may be attributed to variations in polarizability between nanotube types, which create differences in both the structure and mobility of surfactant. These differences affect the enthalpy and entropy of adsorption, and both play an integral part in the selectivity of adsorption. The overall adsorption process shows a complex behavior that is not well represented by the Langmuir model; therefore, calorimetric data should be used to extract thermodynamic information.

Supporting Information

ARTICLE SECTIONS
Jump To

Additional text and six figures showing characterization of SWCNT suspensions; adsorption isotherms, elution curves, and absorbance spectra for all gels used in nonequilibrium studies; and expanded details on mass fraction calculations. This material is available free of charge via the Internet at http://pubs.acs.org.

Terms & Conditions

Most electronic Supporting Information files are available without a subscription to ACS Web Editions. Such files may be downloaded by article for research use (if there is a public use license linked to the relevant article, that license may permit other uses). Permission may be obtained from ACS for other uses through requests via the RightsLink permission system: http://pubs.acs.org/page/copyright/permissions.html.

Cited By


This article is cited by 36 publications.

  1. Sophia Zanoni, Brennan P. Watts, Kevin Tvrdy. Single-Walled Carbon Nanotube Chiral Selectivity Exhibited by Commercially Available Hydrogels of Varying Composition. ACS Applied Materials & Interfaces 2021, 13 (28) , 33635-33643. https://doi.org/10.1021/acsami.1c06961
  2. Christopher A. Holt, Betty Cottyn, Stephanie Baumberger, Krisztina Kovacs-Schreiner, A. John Blacker. High-Throughput Analysis of Lignin by Agarose Gel Electrophoresis. Journal of Agricultural and Food Chemistry 2020, 68 (48) , 14297-14306. https://doi.org/10.1021/acs.jafc.0c06308
  3. Georgios Nikiforidis, Shofarul Wustoni, David Ohayon, Victor Druet, Sahika Inal. A Self-standing Organic Supercapacitor to Power Bioelectronic Devices. ACS Applied Energy Materials 2020, 3 (8) , 7896-7907. https://doi.org/10.1021/acsaem.0c01299
  4. Wenchao Xiang, Natalie Preisig, Christiane Laine, Tuomo Hjelt, Blaise L. Tardy, Cosima Stubenrauch, Orlando J. Rojas. Surface Activity and Foaming Capacity of Aggregates Formed between an Anionic Surfactant and Non-Cellulosics Leached from Wood Fibers. Biomacromolecules 2019, 20 (6) , 2286-2294. https://doi.org/10.1021/acs.biomac.9b00243
  5. Han Li, Georgy Gordeev, Oisin Garrity, Stephanie Reich, Benjamin S. Flavel. Separation of Small-Diameter Single-Walled Carbon Nanotubes in One to Three Steps with Aqueous Two-Phase Extraction. ACS Nano 2019, 13 (2) , 2567-2578. https://doi.org/10.1021/acsnano.8b09579
  6. Lili Zhou, Xiaofeng Liu, Huaping Li. Release of Retained Single-Walled Carbon Nanotubes in Gels. Langmuir 2018, 34 (40) , 12224-12232. https://doi.org/10.1021/acs.langmuir.8b02403
  7. Jia Xu, Robert Mueller, Eric Hazelbaker, Yang Zhao, Jean-Claude J. Bonzongo, Justin G. Clar, Sergey Vasenkov, and Kirk J. Ziegler . Strongly Bound Sodium Dodecyl Sulfate Surrounding Single-Wall Carbon Nanotubes. Langmuir 2017, 33 (20) , 5006-5014. https://doi.org/10.1021/acs.langmuir.7b00758
  8. Rishabh M. Jain, Micha Ben-Naim, Markita P. Landry, and Michael S. Strano . Competitive Binding in Mixed Surfactant Systems for Single-Walled Carbon Nanotube Separation. The Journal of Physical Chemistry C 2015, 119 (39) , 22737-22745. https://doi.org/10.1021/acs.jpcc.5b07947
  9. Justin G. Clar, Sarah A. Gustitus, Sejin Youn, Carlos A. Silvera Batista, Kirk. J. Ziegler, and Jean Claude J. Bonzongo . Unique Toxicological Behavior from Single-Wall Carbon Nanotubes Separated via Selective Adsorption on Hydrogels. Environmental Science & Technology 2015, 49 (6) , 3913-3921. https://doi.org/10.1021/es505925m
  10. Won Gyun Moon, Gil-Pyo Kim, Minzae Lee, Hyeon Don Song, and Jongheop Yi . A Biodegradable Gel Electrolyte for Use in High-Performance Flexible Supercapacitors. ACS Applied Materials & Interfaces 2015, 7 (6) , 3503-3511. https://doi.org/10.1021/am5070987
  11. Justin G. Clar, Tianyu Yuan, Yang Zhao, Jean-Claude J. Bonzongo, and Kirk J. Ziegler . Evaluation of Critical Parameters in the Separation of Single-Wall Carbon Nanotubes through Selective Adsorption onto Hydrogels. The Journal of Physical Chemistry C 2014, 118 (28) , 15495-15505. https://doi.org/10.1021/jp503594h
  12. Joseph B. Miller, John M. Harris, and Erik K. Hobbie . Purifying Colloidal Nanoparticles through Ultracentrifugation with Implications for Interfaces and Materials. Langmuir 2014, 30 (27) , 7936-7946. https://doi.org/10.1021/la404675v
  13. Benjamin S. Flavel, Katherine E. Moore, Moritz Pfohl, Manfred M. Kappes, and Frank Hennrich . Separation of Single-Walled Carbon Nanotubes with a Gel Permeation Chromatography System. ACS Nano 2014, 8 (2) , 1817-1826. https://doi.org/10.1021/nn4062116
  14. Yao Guo, Tao Wang, Xingxing Chen, Dongling Wu. Agar-based porous electrode and electrolyte for flexible symmetric supercapacitors with ultrahigh energy density. Journal of Power Sources 2021, 507 , 230252. https://doi.org/10.1016/j.jpowsour.2021.230252
  15. Syed Shaheen Shah, Emre Cevik, Md. Abdul Aziz, Talal F. Qahtan, Ayhan Bozkurt, Zain H. Yamani. Jute Sticks Derived and Commercially Available Activated Carbons for Symmetric Supercapacitors with Bio‐electrolyte: A Comparative Study. Synthetic Metals 2021, 277 , 116765. https://doi.org/10.1016/j.synthmet.2021.116765
  16. Laura Wieland, Han Li, Christian Rust, Jianhui Chen, Benjamin S. Flavel. Carbon Nanotubes for Photovoltaics: From Lab to Industry. Advanced Energy Materials 2021, 11 (3) , 2002880. https://doi.org/10.1002/aenm.202002880
  17. M. Dolan, B.P. Watts, K. Tvrdy. Tailored synthesis of hydrogel media for chirality separation of single walled carbon nanotubes. Carbon 2021, 171 , 597-609. https://doi.org/10.1016/j.carbon.2020.08.074
  18. Sweejiang Yoo, Wenhui Yi, Asif Khalid, Jinhai Si, Xun Hou. Temperature-dependent Oxidation of Carbon Nanotubes for Metal/Semiconductor Separation. Chemistry Letters 2020, 49 (10) , 1154-1158. https://doi.org/10.1246/cl.200402
  19. Emre Cevik, Seyda Tugba Gunday, Ayhan Bozkurt, Rachid Amine, Khalil Amine. Bio-inspired redox mediated electrolyte for high performance flexible supercapacitor applications over broad temperature domain. Journal of Power Sources 2020, 474 , 228544. https://doi.org/10.1016/j.jpowsour.2020.228544
  20. Wei Su, Dehua Yang, Jiaming Cui, Futian Wang, Xiaojun Wei, Weiya Zhou, Hiromichi Kataura, Sishen Xie, Huaping Liu. Ultrafast wafer-scale assembly of uniform and highly dense semiconducting carbon nanotube films for optoelectronics. Carbon 2020, 163 , 370-378. https://doi.org/10.1016/j.carbon.2020.03.032
  21. Huaping Li, Lili Zhou, Tao Wu. Sodium dodecyl benzene sulfonate for single-walled carbon nanotubes separation in gel chromatography. Diamond and Related Materials 2018, 88 , 189-192. https://doi.org/10.1016/j.diamond.2018.07.016
  22. Jia-Ying Yang, Xin-Yu Jiang, Fei-Peng Jiao, Jin-Gang Yu. The oxygen-rich pentaerythritol modified multi-walled carbon nanotube as an efficient adsorbent for aqueous removal of alizarin yellow R and alizarin red S. Applied Surface Science 2018, 436 , 198-206. https://doi.org/10.1016/j.apsusc.2017.12.029
  23. Kai Zhu, Shuling Zhang, Jiashuang Luan, Yongfeng Mu, Yinlong Du, Guibin Wang. Fabrication of ultrafiltration membranes with enhanced antifouling capability and stable mechanical properties via the strategies of blending and crosslinking. Journal of Membrane Science 2017, 539 , 116-127. https://doi.org/10.1016/j.memsci.2017.05.061
  24. Lisha Fan, Yun Shen Zhou, Meng Meng Wang, Jean-François Silvain, Yong Feng Lu. Seed-free deposition of large-area adhesive diamond films on copper surfaces processed and patterned by femtosecond lasers. Thin Solid Films 2017, 636 , 499-505. https://doi.org/10.1016/j.tsf.2017.06.058
  25. Pingli He, Brendan Meany, Chunyan Wang, Yanmei Piao, Hyejin Kwon, Shunliu Deng, YuHuang Wang. Capillary electrophoresis of covalently functionalized single‐chirality carbon nanotubes. ELECTROPHORESIS 2017, 38 (13-14) , 1669-1677. https://doi.org/10.1002/elps.201600570
  26. Teng Zhang, Shuangming Du, Wanchang Sun, Jumei Zhang, Libin Niu, Xiaohu Hua. New practical method of homogeneous dispersion of multi-walled carbon nanotubes (MWCNTs) into Mg matrix composites. IOP Conference Series: Materials Science and Engineering 2017, 182 , 012028. https://doi.org/10.1088/1757-899X/182/1/012028
  27. Gil-Pyo Kim, Ho-Hyun Sun, Arumugam Manthiram. Design of a sectionalized MnO2-Co3O4 electrode via selective electrodeposition of metal ions in hydrogel for enhanced electrocatalytic activity in metal-air batteries. Nano Energy 2016, 30 , 130-137. https://doi.org/10.1016/j.nanoen.2016.10.003
  28. Atsushi Hirano, Tomoshi Kameda, Yohei Yomogida, Momoyo Wada, Takeshi Tanaka, Hiromichi Kataura. Origin of the Surfactant-Dependent Redox Chemistry of Single-Wall Carbon Nanotubes. ChemNanoMat 2016, 2 (9) , 911-920. https://doi.org/10.1002/cnma.201600190
  29. E.S. Kastrisianaki-Guyton, L. Chen, S.E. Rogers, T. Cosgrove, J.S. van Duijneveldt. Adsorption of sodium dodecylsulfate on single-walled carbon nanotubes characterised using small-angle neutron scattering. Journal of Colloid and Interface Science 2016, 472 , 1-7. https://doi.org/10.1016/j.jcis.2016.03.026
  30. Zhan Wang, Yan Jin, Chongyang Shen, Tiantian Li, Yuanfang Huang, Baoguo Li, . Spontaneous Detachment of Colloids from Primary Energy Minima by Brownian Diffusion. PLOS ONE 2016, 11 (1) , e0147368. https://doi.org/10.1371/journal.pone.0147368
  31. Yang Zhao, Justin G. Clar, Luping Li, Jia Xu, Tianyu Yuan, Jean-Claude J. Bonzongo, Kirk J. Ziegler. Selective desorption of high-purity (6,5) SWCNTs from hydrogels through surfactant modulation. Chemical Communications 2016, 52 (14) , 2928-2931. https://doi.org/10.1039/C5CC08530F
  32. Adam B. Phillips, Michael J. Heben. Activated complex model and surfactant reorganization during SWCNT separations on hydrogels. Carbon 2015, 95 , 330-337. https://doi.org/10.1016/j.carbon.2015.08.007
  33. Iskandar Yahya, Francesco Bonaccorso, Steven K. Clowes, Andrea C. Ferrari, S.R.P. Silva. Temperature dependent separation of metallic and semiconducting carbon nanotubes using gel agarose chromatography. Carbon 2015, 93 , 574-594. https://doi.org/10.1016/j.carbon.2015.05.036
  34. Liang Fang, Chen Zhao, Yani Chen, Leimei Sheng, Kang An, Liming Yu, Wei Ren, Xinluo Zhao. Single-chirality separation of ultra-thin semiconducting arc discharge single-walled carbon nanotubes. Carbon 2015, 91 , 408-415. https://doi.org/10.1016/j.carbon.2015.05.007
  35. Racha El-Debs, Reine Nehmé, Bérengère Claude, Solène Motteau, Anne Togola, Catherine Berho, Philippe Morin. Coated capillaries with highly charged polyelectrolytes and carbon nanotubes co-aggregated with sodium dodecyl sulphate for the analysis of sulfonylureas by capillary electrophoresis. Journal of Chromatography A 2014, 1367 , 161-166. https://doi.org/10.1016/j.chroma.2014.09.047
  36. Varun Shenoy Gangoli, Juyan Azhang, Taryn T. Willett, Sean A. Gelwick, Erik H. Haroz, Junichiro Kono, Robert H. Hauge, Michael S. Wong. Using Nonionic Surfactants for Production of Semiconductor-Type Carbon Nanotubes by Gel-Based Affinity Chromatography. Nanomaterials and Nanotechnology 2014, 4 , 19. https://doi.org/10.5772/58828

Pair your accounts.

Export articles to Mendeley

Get article recommendations from ACS based on references in your Mendeley library.

Pair your accounts.

Export articles to Mendeley

Get article recommendations from ACS based on references in your Mendeley library.

You’ve supercharged your research process with ACS and Mendeley!

STEP 1:
Click to create an ACS ID

Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

MENDELEY PAIRING EXPIRED
Your Mendeley pairing has expired. Please reconnect

This website uses cookies to improve your user experience. By continuing to use the site, you are accepting our use of cookies. Read the ACS privacy policy.

CONTINUE