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Construction of Ultrastable Porphyrin Zr Metal–Organic Frameworks through Linker Elimination

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Department of Chemistry, Texas A&M University, College Station, Texas 77843, United States
Cite this: J. Am. Chem. Soc. 2013, 135, 45, 17105–17110
Publication Date (Web):October 14, 2013
Copyright © 2013 American Chemical Society

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    A series of highly stable MOFs with 3-D nanochannels, namely PCN-224 (no metal, Ni, Co, Fe), have been assembled with six-connected Zr6 cluster and metalloporphyrins by a linker-elimination strategy. The PCN-224 series not only exhibits the highest BET surface area (2600m2/g) among all the reported porphyrinic MOFs but also remains intact in pH = 0 to pH = 11 aqueous solution. Remarkably, PCN-224(Co) exhibits high catalytic activity for the CO2/propylene oxide coupling reaction and can be used as a recoverable heterogeneous catalyst.

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