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Sieving of Hot Gases by Hyper-Cross-Linked Nanoscale-Hybrid Membranes

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Inorganic Membranes and Materials Science and Technology of Polymers, University of Twente, Faculty of Science and Technology, MESA+ Institute for Nanotechnology, P.O. Box 217, 7500 AE Enschede, The Netherlands
§ Chemical Process Engineering-AVT.CVT, RWTH Aachen University, Turmstrasse 46, 52056 Aachen, Germany
Cite this: J. Am. Chem. Soc. 2014, 136, 1, 330–335
Publication Date (Web):December 6, 2013
https://doi.org/10.1021/ja410047u
Copyright © 2013 American Chemical Society
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Abstract

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Macromolecular networks consisting of homogeneously distributed covalently bonded inorganic and organic precursors are anticipated to show remarkable characteristics, distinct from those of the individual constituents. A novel hyper-cross-linked ultrathin membrane is presented, consisting of a giant molecular network of alternating polyhedral oligomeric silsesquioxanes and aromatic imide bridges. The hybrid characteristics of the membrane are manifested in excellent gas separation performance at elevated temperatures, providing a new and key enabling technology for many important industrial scale applications.

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The full reaction scheme of the polyPOSS–imide; material analysis using differential scanning calorimetry, thermal gravimetric analysis, X-ray photoelectron spectroscopy and full infrared peak analysis. This material is available free of charge via the Internet at http://pubs.acs.org.

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