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Stepwise Construction of Discrete Heterometallic Coordination Cages Based on Self-Sorting Strategy
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    Stepwise Construction of Discrete Heterometallic Coordination Cages Based on Self-Sorting Strategy
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    Shanghai Key Laboratory of Molecular Catalysis and Innovative Material, Department of Chemistry, Fudan University, 200433, Shanghai, P. R. China
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    Journal of the American Chemical Society

    Cite this: J. Am. Chem. Soc. 2014, 136, 8, 2982–2985
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    https://doi.org/10.1021/ja412667t
    Published February 6, 2014
    Copyright © 2014 American Chemical Society

    Abstract

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    A chelation-directed self-sorting synthesis of a series of cationic heterometallic coordination cages (HCCs) with tunable sizes is described. Two complexation modes were found in the cage-forming process. Metal-anchoring host–guest behavior and size-selective in-cage catalytic activities were found for the HCCs.

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    Supporting Information

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    Experimental procedures, characterization data, catalytic study, mechanistic study, kinetic investigation and crystallographic data for [HCC-1][OTf]8, [HCC-2][OTf]8, {AgOTf [HCC-1][OTf]8}, {AgOTf [HCC-6][OTf]8}, and {pyrazine [HCC-5][OTf]8} (in CIF format). This material is available free of charge via the Internet at http://pubs.acs.org.

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