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Octadecanuclear Macrocycles and Nonanuclear Bowl-Shaped Structures Based on Two Analogous Pyridyl-Substituted Imidazole-4,5-dicarboxylate Ligands

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    Octadecanuclear Macrocycles and Nonanuclear Bowl-Shaped Structures Based on Two Analogous Pyridyl-Substituted Imidazole-4,5-dicarboxylate Ligands
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    Shanghai Key Laboratory of Molecular Catalysis and Innovative Material, Department of Chemistry, Fudan University, Shanghai 200433, P. R. China
    [email protected]
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    Journal of the American Chemical Society

    Cite this: J. Am. Chem. Soc. 2014, 136, 44, 15521–15524
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    https://doi.org/10.1021/ja5096914
    Published October 20, 2014
    Copyright © 2014 American Chemical Society
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    Abstract

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    Two types of unprecedented Cp*Rh-based (Cp* = η5-C5Me5) complexes, two octadecanuclear macrocycles, and a nonanuclear bowl-shaped complex have been synthesized from two analogous pyridyl-functionalized imidazole-4,5-dicarboxylate ligands, 2-(pyridin-4-yl)-1H-imidazole-4,5-dicarboxylate ligand and 2-(pyridin-3-yl)-1H-imidazole-4,5-dicarboxylate ligand, respectively.

    Copyright © 2014 American Chemical Society

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    Supporting Information

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    Experimental details, crystallographic data, and CIF files for complexes 3, 3′, 4, 5, 6, and 7. This material is available free of charge via the Internet at http://pubs.acs.org.

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    Cited By

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    This article is cited by 31 publications.

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    Journal of the American Chemical Society

    Cite this: J. Am. Chem. Soc. 2014, 136, 44, 15521–15524
    Click to copy citationCitation copied!
    https://doi.org/10.1021/ja5096914
    Published October 20, 2014
    Copyright © 2014 American Chemical Society
    Request reuse permissions

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