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α-CuV2O6 Nanowires: Hydrothermal Synthesis and Primary Lithium Battery Application

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Key Laboratory of Energy-Material Chemistry (Tianjin) and Engineering Research Center of Energy Storage & Conversion (Ministry of Education), Chemistry College, Nankai University, Tianjin 300071, People’s Republic of China
Cite this: J. Am. Chem. Soc. 2008, 130, 15, 5361–5367
Publication Date (Web):March 26, 2008
Copyright © 2008 American Chemical Society

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    We report on the synthesis, characterization, and electrochemical lithium intercalation of α-CuV2O6 nanowires, mesowires, and microrods that were prepared through a facile hydrothermal route. The diameters of the as-synthesized α-CuV2O6 nanowires, mesowires, and microrods were about 100 nm, 400 nm, and 1 µm, respectively. It was found that by simply controlling the hydrothermal reaction parameters, such as the reagent concentration and the dwell time, the transformation of microrods to nanowires was readily achieved via a “ripening−splitting” mechanism. Electrochemical measurements revealed that the as-prepared α-CuV2O6 nanowires and mesowires displayed high discharge capacities (447−514 mAh/g at 20 mA/g and 37 °C) and excellent high-rate capability. In particular, the α-CuV2O6 nanowires showed capacities much higher than those of α-CuV2O6 mesowires, microrods, and bulk particles. The mechanisms for the electrochemical lithium intercalation into the α-CuV2O6 nanowires were also discussed. From the Arrhenius plot of lithium intercalation into α-CuV2O6 nanowires, the activation energies were calculated to be 39.3 kJ/mol at 2.8 V (low lithium uptake) and 35.7 kJ/mol at 2.3 V (high lithium uptake). This result indicates that the α-CuV2O6 nanowires are promising cathode candidates for primary lithium batteries used in long-term implantable cardioverter defibrillators (ICD).

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    The illustration of the working principle and configuration of the implantable cardioverter defibrillators (ICD); the picture of the experimental setup; SEM images of α-CuV2O6 synthesized from different concentrations of the reactant; SEM images of α-CuV2O6 bulk particles obtained from solid-state reaction; XRD patterns and SEM images of α-CuV2O6 obtained at different reaction time; illustration of the possible phase transformation in the synthesis of α-CuV2O6 nanowires; discharge curves for the electrodes made from the as-prepared α-CuV2O6 nanowires and bulk particles at the current densities of 40 and 80 mA/g and the temperature of 37 °C; discharge curves for the electrode made from the as-prepared α-CuV2O6 nanowires at the current densities of 20 mA/g after equilibrated at 37 °C for 2 months; cyclic voltammogram (CV) of the electrode made form the α-CuV2O6 nanowires in the first cycle at a scan rate of 1.0 mV/s and the temperature of 37 °C; the survey XPS spectra of the electrode made from the α-CuV2O6 nanowires at different discharge states; XRD patterns and SEM images of the electrodes with α-CuV2O6 nanowires and bulk particles after discharging to the cutoff voltage of 2.0 V; the equivalent circuit for the electrochemical impedance spectrum; table of charge-transfer resistance (Rct) and exchange current (i0) of α-CuV2O6 nanowires and bulk particels measured at different discharge states and temperatures. This material is available free of charge via the Internet at

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    23. Liqiang Mai, Xiaocong Tian, Xu Xu, Liang Chang, and Lin Xu . Nanowire Electrodes for Electrochemical Energy Storage Devices. Chemical Reviews 2014, 114 (23) , 11828-11862.
    24. Qing Zhao, Yuxiang Hu, Kai Zhang, and Jun Chen . Potassium–Sulfur Batteries: A New Member of Room-Temperature Rechargeable Metal–Sulfur Batteries. Inorganic Chemistry 2014, 53 (17) , 9000-9005.
    25. Yemeng Ni, Yajing Yin, Ping Wu, Hui Zhang, and Chenxin Cai . Nitrogen/Carbon Atomic Ratio-Dependent Performances of Nitrogen-Doped Carbon-Coated Metal Oxide Nanocrystals for Anodes in Lithium-Ion Batteries. ACS Applied Materials & Interfaces 2014, 6 (10) , 7346-7355.
    26. Gongzheng Yang, Hao Cui, Guowei Yang, and Chengxin Wang . Self-Assembly of Co3V2O8 Multilayered Nanosheets: Controllable Synthesis, Excellent Li-Storage Properties, and Investigation of Electrochemical Mechanism. ACS Nano 2014, 8 (5) , 4474-4487.
    27. Shuquan Liang, Jiang Zhou, Guozhao Fang, Jing Liu, Yan Tang, Xilin Li, and Anqiang Pan . Ultrathin Na1.1V3O7.9 Nanobelts with Superior Performance as Cathode Materials for Lithium-Ion Batteries. ACS Applied Materials & Interfaces 2013, 5 (17) , 8704-8709.
    28. Zheng Chen, Veronica Augustyn, Xilai Jia, Qiangfeng Xiao, Bruce Dunn, and Yunfeng Lu . High-Performance Sodium-Ion Pseudocapacitors Based on Hierarchically Porous Nanowire Composites. ACS Nano 2012, 6 (5) , 4319-4327.
    29. H. Heli, H. Yadegari, and A. Jabbari . Investigation of the Lithium Intercalation Behavior of Nanosheets of LiV3O8 in an Aqueous Solution. The Journal of Physical Chemistry C 2011, 115 (21) , 10889-10897.
    30. Yan Sun, Chunsheng Li and Wenjun Zheng. Ionic Liquid-Assisted Hydrothermal Synthesis of Monoclinic Structured LaVO4 Nanowires through Topotactic Transformation from Hexagonal La(OH)3 Nanowires. Crystal Growth & Design 2010, 10 (1) , 262-267.
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    33. Jun Chen and Fangyi Cheng. Combination of Lightweight Elements and Nanostructured Materials for Batteries. Accounts of Chemical Research 2009, 42 (6) , 713-723.
    34. Shaoyan Zhang, Lijie Ci and Huiru Liu. Synthesis, Characterization, and Electrochemical Properties of Cu3V2O7(OH)2·2H2O Nanostructures. The Journal of Physical Chemistry C 2009, 113 (20) , 8624-8629.
    35. Christopher J. Patridge, Cherno Jaye, Hengsong Zhang, Amy C. Marschilok, Daniel A. Fischer, Esther S. Takeuchi and Sarbajit Banerjee . Synthesis, Structural Characterization, and Electronic Structure of Single-Crystalline CuxV2O5 Nanowires. Inorganic Chemistry 2009, 48 (7) , 3145-3152.
    36. Ning Ding, Shuhua Liu, Xuyong Feng, Haitao Gao, Xin Fang, Jing Xu, Wolfgang Tremel, Ingo Lieberwirth and Chunhua Chen. Hydrothermal Growth and Characterization of Nanostructured Vanadium-Based Oxides. Crystal Growth & Design 2009, 9 (4) , 1723-1728.
    37. Shu-Lei Chou, Jia-Zhao Wang, Jia-Zeng Sun, David Wexler, Maria Forsyth, Hua-Kun Liu, Douglas R. MacFarlane and Shi-Xue Dou . High Capacity, Safety, and Enhanced Cyclability of Lithium Metal Battery Using a V2O5 Nanomaterial Cathode and Room Temperature Ionic Liquid Electrolyte. Chemistry of Materials 2008, 20 (22) , 7044-7051.
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    41. P. Santhoshkumar, T. Subburaj, Dhanasekaran Vikraman, K. Karuppasamy, A. Kathalingam, Hyun-Seok Kim. High-performance nanoribbon-like CuV2O5 hybrid composite as a bifunctional electrode for rechargeable batteries. Journal of Alloys and Compounds 2023, 968 , 172096.
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    44. Junjie He, Chuanqi Feng, Zhihong Liu. Synthesis of 2D Zn3V3O8 sheets as novel anode material for lithium ion battery application. Ionics 2023, 29 (9) , 3451-3457.
    45. Siyi Kang, Chenxi Wang, Jingwei Chen, Tian Meng, Jiaqiang E. Progress on solvo/hydrothermal synthesis and optimization of the cathode materials of lithium-ion battery. Journal of Energy Storage 2023, 67 , 107515.
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    52. Liqiang Mai, Lin Xu, Wei Chen. Vanadate Nanomaterials for Electrochemical Energy Storage. 2023, 177-219.
    53. Liqiang Mai, Lin Xu, Wei Chen. Fundamentals of Vanadium-Based Nanomaterials. 2023, 1-15.
    54. Wen Ren, Mulan Qin, Yifan Zhou, Huang Zhou, Jue Zhu, Junan Pan, Jiang Zhou, Xinxin Cao, Shuquan Liang. Electrospun Na4Fe3(PO4)2(P2O7) nanofibers as free-standing cathodes for ultralong-life and high-rate sodium-ion batteries. Energy Storage Materials 2023, 54 , 776-783.
    55. Mahmoud Mohamed Emara, S. M. Reda, Mohamad Awad El-Naggar, Mahmoud Ahmed Mousa. Magnetization and optical bandgap of Cu-Mn vanadate-oxide mixed phase nanostructures. Journal of Nanoparticle Research 2022, 24 (11)
    56. Yan Liu, Meng‐Yuan Su, Zhen‐Yi Gu, Kai‐Yang Zhang, Xiao‐Tong Wang, Miao Du, Jin‐Zhi Guo, Xing‐Long Wu. Advanced Lithium Primary Batteries: Key Materials, Research Progresses and Challenges. The Chemical Record 2022, 22 (10)
    57. Cuixia Cheng, Yinfang Cheng, Guosong Lai. Micro/nanostructured Bi 2 Mn 4 O 10 with hierarchical spindle morphology as a highly efficient anode material for lithium‐ion batteries. Journal of the American Ceramic Society 2022, 105 (10) , 6086-6095.
    58. Cuixia Cheng, Fang Chen, Yinfang Cheng, Guosong Lai. Bi2MoO6 hierarchical hollow microspheres with remarkable electrochemical performance. Ceramics International 2022, 48 (18) , 26393-26399.
    59. Ni Wen, Siyuan Chen, Qiuchen Lu, Yunbo Li, Qinghua Fan, Quan Kuang, Youzhong Dong, Yanming Zhao. Insights into the enhanced electrochemical performance of MnV 2 O 6 nanoflakes as an anode material for advanced lithium storage. Nanoscale 2022, 14 (29) , 10428-10438.
    60. Asim Khan, Basit Ali, Abid Inayat, Mohammad Rizwan Khan, Naushad Ahmad, Jehan Akbar, Ata‐ur‐Rehman, Kyung‐Wan Nam, Syed Mustansar Abbas. Lithium‐ion battery anode with high capacity retention derived from zinc vanadate and holey graphene. International Journal of Energy Research 2022, 46 (8) , 11200-11213.
    61. Lele Lu, Qiang Li, Jia Du, Wei Shi, Peng Cheng. Bimetallic cobalt-nickel coordination polymer electrocatalysts for enhancing oxygen evolution reaction. Chinese Chemical Letters 2022, 33 (6) , 2928-2932.
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    64. Joyita Banerjee, Kingshuk Dutta. An overview on the use of metal vanadium oxides and vanadates in supercapacitors and rechargeable batteries. International Journal of Energy Research 2022, 46 (4) , 3983-4000.
    65. Liming Ling, Xiwen Wang, Yu Li, Chenxiao Lin, Dong Xie, Min Zhang, Yan Zhang, Jinjia Wei, Huajie Xu, Faliang Cheng, Chuan Wu, Shiguo Zhang. Monoclinic Cu3(OH)2V2O7·2H2O nanobelts/reduced graphene oxide: A novel high-capacity and long-life composite for potassium-ion battery anodes. Journal of Energy Chemistry 2022, 66 , 140-151.
    66. Tzu-Ho Wu, Wei-Yuan Liang, Ya-Qi Lin. Facile synthesis of Cu−intercalated MnO2 nanoflakes cathode for enhanced energy storage in zinc−ion batteries. Journal of the Taiwan Institute of Chemical Engineers 2022, 131 , 104172.
    67. Fengyang Jing, Jian Pei, Yumin Zhou, Zhongzheng Qin, Bowen Cong, Ke Hua, Gang Chen. Hierarchical MnV2O4 double-layer hollow sandwich nanosheets confined by N-doped carbon layer as anode for high performance lithium-ion batteries. Journal of Colloid and Interface Science 2022, 607 , 538-545.
    68. Huixia He, Wenyu Wei, Yongling An, Jinkui Feng, Jianxi Xiao. Leaf-like copper oxide mesocrystals by collagen-assisted biomineralization show attractive biofunctional and electrochemical properties. Materials Advances 2022, 3 (1) , 245-253.
    69. Jingwei Liu, Daixi Xie, Xiufang Xu, Luozhen Jiang, Rui Si, Wei Shi, Peng Cheng. Reversible formation of coordination bonds in Sn-based metal-organic frameworks for high-performance lithium storage. Nature Communications 2021, 12 (1)
    70. Huixia He, Caihong Fu, Yongling An, Jinkui Feng, Jianxi Xiao. Biofunctional hollow γ-MnO 2 microspheres by a one-pot collagen-templated biomineralization route and their applications in lithium batteries. RSC Advances 2021, 11 (59) , 37040-37048.
    71. Ting-Feng Yi, Liying Qiu, Jin-Peng Qu, Hongyan Liu, Jun-Hong Zhang, Yan-Rong Zhu. Towards high-performance cathodes: Design and energy storage mechanism of vanadium oxides-based materials for aqueous Zn-ion batteries. Coordination Chemistry Reviews 2021, 446 , 214124.
    72. Jianying Meng, Shuchao Zhang, Xin Liu, Shenglin Zhong, Zhengguang Zou. Facile synthesis of 3D urchin-like V6O13 microflowers as cathode materials for high-capacity and high-rate lithium-ion batteries. Journal of Electroanalytical Chemistry 2021, 900 , 115742.
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    74. Baohe Yuan, Lilei Zhang, Xianghong Ge, Heng Qi, Qi Xu, Lulu Chen, Erjun Liang, Baojun Li, Juan Guo. The study of zirconium vanadate as a cathode material for lithium ion batteries. RSC Advances 2021, 11 (38) , 23533-23540.
    75. Hyeong Chul Roh, In Yea Kim, Tae Young Ahn, Hae-Won Cheong, Young Soo Yoon. Influence of temperature on performance of CuV2O6 cathode for high voltage thermal battery. Journal of the Korean Ceramic Society 2021, 58 (4) , 507-518.
    76. Muhammad Ashraf, Ibrahim Khan, Nadeem Baig, Abdulmajeed H. Hendi, Muhammad Fahad Ehsan, Nafeesa Sarfraz. A Bifunctional 2D Interlayered β‐Cu 2 V 2 O 7 /Zn 2 V 2 O 6 (CZVO) Heterojunction for Solar‐Driven Nonsacrificial Dye Degradation and Water Oxidation. Energy Technology 2021, 9 (7)
    77. Maryam Ghiyasiyan-Arani, Masoud Salavati-Niasari. Synergic and coupling effect between SnO 2 nanoparticles and hierarchical AlV 3 O 9 microspheres toward emerging electrode materials for lithium-ion battery devices. Inorganic Chemistry Frontiers 2021, 8 (11) , 2735-2748.
    78. Zhuangzhuang Wang, Wenwei Sun, Dejian Tang, Weilin Liu, Fancheng Meng, Xiangfeng Wei, Jiehua Liu. In situ interfacial architecture of lithium vanadate-based cathode for printable lithium batteries. iScience 2021, 24 (6) , 102666.
    79. Mengmeng Cui, Xingjie Lu, Taofang Zeng, Olim Ruzimuradov, Dong Fang, Caiju Li, Fengxian Li, Yichun Liu, Rui Bao, Jianhong Yi. Effect of anions on the copper vanadate structure during ion-exchange and its lithium storage performance. Journal of Alloys and Compounds 2021, 862 , 158576.
    80. Deepika Jamwal, Aashima Sharma, Rohini Kanwar, Surinder Kumar Mehta. The multifaceted dimensions of potent nanostructures: a comprehensive review. Materials Chemistry Frontiers 2021, 5 (7) , 2967-2995.
    81. S. Rajkumar, E. Elanthamilan, J. Princy Merlin. Facile synthesis of Zn3V2O8 nanostructured material and its enhanced supercapacitive performance. Journal of Alloys and Compounds 2021, 861 , 157939.
    82. Jinzhe Liu, Peilin Zhang, Weiwei Wang, Chencheng Zhou, Jiaojiao Zhou, Jing Wu, Kuang Li, Yuchen Lei, Luyang Chen. Zn 3 V 3 O 8 /NC hybrid microspheres self-assembled by layered porous nanosheets as a superior anode material for lithium/sodium-ion batteries. Dalton Transactions 2021, 50 (11) , 4017-4027.
    83. Shreenivasa L, Yogeeshwari R.T, Viswanatha R, Yogesh K, Ashoka S. Sucrose-assisted rapid synthesis of multifunctional CrVO4 nanoparticles: a new high-performance cathode material for lithium ion batteries. Ionics 2021, 27 (1) , 39-48.
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    85. Xue Jiang, Baorui Jia, Deyin Zhang, Haoyang Wu, Aiming Chu, Xuanhui Qu, Mingli Qin. Hydrothermal synthesis of new CuVO2 delafossite hexagonal nanoplates. Ceramics International 2020, 46 (18) , 28219-28226.
    86. Zhiyong Zhou, Jun Zhang, Siyuan Chen, Heng Yao, Yanming Zhao, Quan Kuang, Qinghua Fan, Youzhong Dong. The electrochemical performanceand multielectron reaction mechanism of NiV2O6 as anovel anode material for lithium-ion batteries. Electrochimica Acta 2020, 359 , 136979.
    87. L. Shreenivasa, R. Viswanatha, Sriram Ganesan, Yogesh Kalegowda, Mahaveer D. Kurkuri, S. Ashoka. Scalable chemical approach to prepare crystalline Mn2V2O7 nanoparticles: introducing a new long-term cycling cathode material for lithium-ion battery. Journal of Materials Science: Materials in Electronics 2020, 31 (22) , 19638-19646.
    88. Xueying Luo, Mingwu Xiang, Yan Li, Junming Guo, Xiaofang Liu, Hongli Bai, Wei Bai, Changwei Su. Surface-orientation for boosting the high-rate and cyclability of spinel LiNi0.02Mn1.98O4 cathode material. Vacuum 2020, 179 , 109505.
    89. A. M. Golubev, J. Nuss, R. K. Kremer, E. E. Gordon, M.-H. Whangbo, C. Ritter, L. Weber, S. Wessel. Two-dimensional magnetism in α − CuV 2 O 6 . Physical Review B 2020, 102 (1)
    90. Shude Liu, Ling Kang, Jong Min Kim, Young Tea Chun, Jian Zhang, Seong Chan Jun. Recent Advances in Vanadium‐Based Aqueous Rechargeable Zinc‐Ion Batteries. Advanced Energy Materials 2020, 10 (25)
    91. X. Xu, F. Xiong, J. Meng, Q. An, L. Mai. Multi-electron reactions of vanadium-based nanomaterials for high-capacity lithium batteries: challenges and opportunities. Materials Today Nano 2020, 10 , 100073.
    92. Kalani Periyapperuma, Elisabetta Arca, Steve Harvey, Chunmei Ban, Anthony Burrell, Douglas R. MacFarlane, Cristina Pozo-Gonzalo, Maria Forsyth, Patrick C. Howlett. Towards high rate Li metal anodes: enhanced performance at high current density in a superconcentrated ionic liquid. Journal of Materials Chemistry A 2020, 8 (7) , 3574-3579.
    93. L. Shreenivasa, K. Yogesh, S. A. Prashanth, R. Viswanatha, S. Ashoka. Enhancement of cycling stability and capacity of lithium secondary battery by engineering highly porous AlV3O9. Journal of Materials Science 2020, 55 (4) , 1648-1658.
    94. Yanping Zhou, Xianghua Zhang, Yanjing Liu, Xinxin Xie, Xianhong Rui, Xiong Zhang, Yuezhan Feng, Xiaojun Zhang, Yan Yu, Kama Huang. A High‐Temperature Na‐Ion Battery: Boosting the Rate Capability and Cycle Life by Structure Engineering. Small 2020, 16 (7)
    95. Xin Yu, Fang Hu, Fuhan Cui, Jun Zhao, Chao Guan, Kai Zhu. The displacement reaction mechanism of the CuV 2 O 6 nanowire cathode for rechargeable aqueous zinc ion batteries. Dalton Transactions 2020, 49 (4) , 1048-1055.
    96. Linqiao Liang, Mingwu Xiang, Wei Bai, Junming Guo, Changwei Su, Lingyan Yang, Hongli Bai, Xiaofang Liu. Electrochemical properties and kinetics of Li–Cu co-doping LiMn2O4 cathode materials. Journal of Materials Science: Materials in Electronics 2020, 31 (1) , 286-297.
    97. Gomathy Jayamani, K. Thirumalai, M. Swaminathan, M. Shanthi. Solar-light assisted photocatalytic mineralization of tartrazine dye using Bi2S3-ZnVO4 nanocomposite. Materials Today: Proceedings 2020, 29 , 1104-1118.
    98. Hao Zheng, Qing Zhang, Hong Gao, Wei Sun, Haimin Zhao, Chuanqi Feng, Jianfeng Mao, Zaiping Guo. Synthesis of porous MoV2O8 nanosheets as anode material for superior lithium storage. Energy Storage Materials 2019, 22 , 128-137.
    99. A-Young Kim, Ryanda Enggar Anugrah Ardhi, Guicheng Liu, Ji Young Kim, Hyun-Jin Shin, Dongjin Byun, Joong Kee Lee. Hierarchical hollow dual Core–Shell carbon nanowall-encapsulated p–n SnO/SnO2 heterostructured anode for high-performance lithium-ion-based energy storage. Carbon 2019, 153 , 62-72.
    100. Hongyu Zhang, Yaling Rong, Wei Jia, Hui Chai, Yali Cao. Simple solvent-free synthesis of rod-like Cu-doped V2O5 for high storage capacity cathode materials of lithium ion batteries. Journal of Alloys and Compounds 2019, 802 , 139-145.
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