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Dynamic Optical Properties of CH3NH3PbI3 Single Crystals As Revealed by One- and Two-Photon Excited Photoluminescence Measurements

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Institute for Chemical Research, Kyoto University, Uji, Kyoto 611-0011, Japan
Cite this: J. Am. Chem. Soc. 2015, 137, 33, 10456–10459
Publication Date (Web):August 11, 2015
https://doi.org/10.1021/jacs.5b04503
Copyright © 2015 American Chemical Society

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    Abstract

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    The dynamic optical properties of perovskite CH3NH3PbI3 single crystals were studied by means of time-resolved photoluminescence (PL) spectroscopy at room temperature. The PL peak under one-photon excitation exhibits a red-shift with elapsing time, while two-photon PL is time-independent and appears at lower energy levels. The low-energy two-photon PL can be attributed to emissions from the localized states because of strong band-to-band absorption and photon re-absorption of the emitted light in the interior region. We revealed that the PL behaviors can be explained by the diffusion of photocarriers generated in the near-surface region to the interior region. The excitation fluence dependence of the one-photon PL dynamics is also discussed in terms of the electron–hole radiative recombination and carrier diffusion effects.

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    • Sample preparation and experimental method (PDF)

    • X-ray crystallographic data for MAPbI3(CIF)

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