ACS Publications. Most Trusted. Most Cited. Most Read
Rational Design of Polynuclear Organometallic Assemblies from a Simple Heteromultifunctional Ligand

OR SEARCH CITATIONS

My Activity
Publications

Figure 1Loading Img
Download Hi-Res ImageDownload to MS-PowerPointCite This:J. Am. Chem. Soc. 2015, 137, 42, 13670-13678
    Article

    Rational Design of Polynuclear Organometallic Assemblies from a Simple Heteromultifunctional Ligand
    Click to copy article linkArticle link copied!

    View Author Information
    State Key Laboratory of Molecular Engineering of Polymers, Collaborative Innovation Center of Chemistry for Energy Materials, Department of Chemistry, Fudan University, Shanghai 200433, PR China
    *[email protected]
    Other Access OptionsSupporting Information (7)

    Journal of the American Chemical Society

    Cite this: J. Am. Chem. Soc. 2015, 137, 42, 13670–13678
    Click to copy citationCitation copied!
    https://doi.org/10.1021/jacs.5b08826
    Published October 6, 2015
    Copyright © 2015 American Chemical Society
    Request reuse permissions

    Abstract

    Click to copy section linkSection link copied!
    Abstract Image

    In modern coordination chemistry, supramolecular coordination complexes take advantage of ligand design to control the shapes and sizes of such architectures. Here we describe how to utilize starting building blocks and a multifunctional ligand to rationally design and synthesize different types of discrete assemblies. Using a hydroxamate ligand featuring two pair of chelating sites together with half-sandwich iridium and rhodium fragments, we were able to construct a series multinuclear organometallic macrocycles and cages through stepwise coordination-driven self-assembly. Experimental observations, supported by computational work, show that selective coordination modes were ascribed to the significant electronic density differences of the two chelating sites, (O,O′) and (N,N′). The results underline the advantages of the discrimination between soft and hard binding sites, and suggest that hydroxamic acids can be used as a versatile class of facile multifunctional scaffold for the construction of novel two-dimensional and three-dimensional architectures.

    Copyright © 2015 American Chemical Society

    Subjects

    what are subjects

    Read this article

    To access this article, please review the available access options below.

    Get instant access

    Purchase Access

    Read this article for 48 hours. Check out below using your ACS ID or as a guest.

    Recommended

    Access through Your Institution

    You may have access to this article through your institution.

    Your institution does not have access to this content. Add or change your institution or let them know you’d like them to include access.

    Supporting Information

    Click to copy section linkSection link copied!

    The Supporting Information is available free of charge on the ACS Publications website at DOI: 10.1021/jacs.5b08826.

    • Computational details, NMR spectra and crystallographic data. (PDF)

    • CIF files for complexes 1a·2H2O, 1a·4CH3CN, 1b·4CH3OH and 2b-C2h. (CIF)

    • CIF files for complexes OTf– ⊂ 3a-D2, 3b-C2h, 3b-D2 and OTf– ⊂ 3b-D2. (CIF)

    • CIF files for complexes 4-D2, 5, 6, 7. (CIF)

    • CIF files for complexes 9b, 10a, 10b and 11. (CIF)

    • CIF files. (CIF)

    • CIF files. (CIF)

    Terms & Conditions

    Most electronic Supporting Information files are available without a subscription to ACS Web Editions. Such files may be downloaded by article for research use (if there is a public use license linked to the relevant article, that license may permit other uses). Permission may be obtained from ACS for other uses through requests via the RightsLink permission system: http://pubs.acs.org/page/copyright/permissions.html.

    Cited By

    Click to copy section linkSection link copied!

    This article is cited by 62 publications.

    1. Jack A. Davies, Tanya K. Ronson, Jonathan R. Nitschke. Triamine and Tetramine Edge-Length Matching Drives Heteroleptic Triangular and Tetragonal Prism Assembly. Journal of the American Chemical Society 2024, 146 (8) , 5215-5223. https://doi.org/10.1021/jacs.3c11320
    2. Tsukasa Abe, Naoki Sanada, Keisuke Takeuchi, Atsushi Okazawa, Shuichi Hiraoka. Assembly of Six Types of Heteroleptic Pd2L4 Cages under Kinetic Control. Journal of the American Chemical Society 2023, 145 (51) , 28061-28074. https://doi.org/10.1021/jacs.3c09359
    3. Charlie T. McTernan, Jack A. Davies, Jonathan R. Nitschke. Beyond Platonic: How to Build Metal–Organic Polyhedra Capable of Binding Low-Symmetry, Information-Rich Molecular Cargoes. Chemical Reviews 2022, 122 (11) , 10393-10437. https://doi.org/10.1021/acs.chemrev.1c00763
    4. Hyunchul Kwon, Ewa Pietrasiak, Takashi Ohhara, Akiko Nakao, Boknam Chae, Chan-Cuk Hwang, Daesung Jung, In-Chul Hwang, Young Ho Ko, Kimoon Kim, Eunsung Lee. Programmable Synthesis of Silver Wheels. Inorganic Chemistry 2021, 60 (9) , 6403-6409. https://doi.org/10.1021/acs.inorgchem.1c00106
    5. Die Liu, Kaixiu Li, Mingzhao Chen, Tingting Zhang, Zhengguang Li, Jia-Fu Yin, Lipeng He, Jun Wang, Panchao Yin, Yi-Tsu Chan, Pingshan Wang. Russian-Doll-Like Molecular Cubes. Journal of the American Chemical Society 2021, 143 (6) , 2537-2544. https://doi.org/10.1021/jacs.0c11703
    6. Wenjuan Xu, Zhichao Shao, Chao Huang, Ruixue Xu, Bingzhe Dong, Hongwei Hou. Alkenone-enol-alkenone [2+2+2] Cyclotrimerization Producing Functional Coordination Polymers with Excellent Adsorption Performance. Inorganic Chemistry 2019, 58 (6) , 3959-3967. https://doi.org/10.1021/acs.inorgchem.9b00037
    7. Subhadeep Saha, Björn Holzapfel, Yen-Ting Chen, Kai Terlinden, Pascal Lill, Christos Gatsogiannis, Heinz Rehage, Guido H. Clever. Rational Design of an Amphiphilic Coordination Cage-Based Emulsifier. Journal of the American Chemical Society 2018, 140 (50) , 17384-17388. https://doi.org/10.1021/jacs.8b10991
    8. Semyon V. Dudkin, Nathan R. Erickson, Anna V. Vologzhanina, Valentin V. Novikov, Hannah M. Rhoda, Cole D. Holstrom, Yuriy V. Zatsikha, Mekhman S. Yusubov, Yan Z. Voloshin, and Victor N. Nemykin . Preparation, X-ray Structures, Spectroscopic, and Redox Properties of Di- and Trinuclear Iron–Zirconium and Iron–Hafnium Porphyrinoclathrochelates. Inorganic Chemistry 2016, 55 (22) , 11867-11882. https://doi.org/10.1021/acs.inorgchem.6b01936
    9. Witold M. Bloch, Yoko Abe, Julian J. Holstein, Claudia M. Wandtke, Birger Dittrich, and Guido H. Clever . Geometric Complementarity in Assembly and Guest Recognition of a Bent Heteroleptic cis-[Pd2LA2LB2] Coordination Cage. Journal of the American Chemical Society 2016, 138 (41) , 13750-13755. https://doi.org/10.1021/jacs.6b08694
    10. Ya-Pan Wu, Xue-Qian Wu, Jian-Fang Wang, Jun Zhao, Wen-Wen Dong, Dong-Sheng Li, and Qi-Chun Zhang . Assembly of Two Novel Cd3/(Cd3 + Cd5)-Cluster-Based Metal–Organic Frameworks: Structures, Luminescence, and Photocatalytic Degradation of Organic Dyes. Crystal Growth & Design 2016, 16 (4) , 2309-2316. https://doi.org/10.1021/acs.cgd.6b00093
    11. Wei-Guo Jia, Hui Zhang, Tai Zhang, Dong Xie, Shuo Ling, and En-Hong Sheng . Half-Sandwich Ruthenium Complexes with Schiff-Base Ligands: Syntheses, Characterization, and Catalytic Activities for the Reduction of Nitroarenes. Organometallics 2016, 35 (4) , 503-512. https://doi.org/10.1021/acs.organomet.5b00933
    12. Zhen-Wu Shao, Chaozhi Xiong, Jiajie Yang, Zhewei Mei, Li Xiong, Wenjing Wu, Chong Liu. A Zr-hydroxamate metal–organic framework with intrinsic chelating sites for postsynthetic Pd metalation and Suzuki–Miyaura catalysis. Chemical Communications 2024, 60 (79) , 11100-11103. https://doi.org/10.1039/D4CC03895A
    13. Maksym Dekhtiarenko, György Szalóki, Vincent Croué, Jennifer Bou Zeid, David Canevet, Magali Allain, Vincent Carré, Frédéric Aubriet, Zoia Voitenko, Marc Sallé, Sébastien Goeb. Playing with the cavity size of exTTF-based self-assembled cages. Organic Chemistry Frontiers 2023, 10 (7) , 1803-1810. https://doi.org/10.1039/D3QO00214D
    14. Jack A. Davies, Andrew Tarzia, Tanya K. Ronson, Florian Auras, Kim E. Jelfs, Jonathan R. Nitschke. Tetramine Aspect Ratio and Flexibility Determine Framework Symmetry for Zn 8 L 6 Self‐Assembled Structures. Angewandte Chemie 2023, 135 (10) https://doi.org/10.1002/ange.202217987
    15. Jack A. Davies, Andrew Tarzia, Tanya K. Ronson, Florian Auras, Kim E. Jelfs, Jonathan R. Nitschke. Tetramine Aspect Ratio and Flexibility Determine Framework Symmetry for Zn 8 L 6 Self‐Assembled Structures. Angewandte Chemie International Edition 2023, 62 (10) https://doi.org/10.1002/anie.202217987
    16. Wen-Xi Gao, Peng-Fei Cui, Zheng Cui, Guo-Xin Jin. Half-Sandwich Rhodium and Iridium Complexes. 2022, 55-187. https://doi.org/10.1016/B978-0-12-820206-7.00144-X
    17. Ume Farwa, Neetu Singh, Junseong Lee. Self-assembly of supramolecules containing half-sandwich iridium units. Coordination Chemistry Reviews 2021, 445 , 213909. https://doi.org/10.1016/j.ccr.2021.213909
    18. Long Zhang, Yue‐Jian Lin, Zhen‐Hua Li, J. Fraser Stoddart, Guo‐Xin Jin. Coordination‐Driven Selective Formation of D 2 Symmetric Octanuclear Organometallic Cages. Chemistry – A European Journal 2021, 27 (37) , 9524-9528. https://doi.org/10.1002/chem.202101204
    19. Weibin Yu, Feng-Yi Qiu, Shi-Ting Luo, Hua-Tian Shi, Guozan Yuan, Xianwen Wei. Coordination assembly and host–guest chemistry of a triply interlocked [2]catenane. Inorganic Chemistry Frontiers 2021, 8 (9) , 2356-2364. https://doi.org/10.1039/D1QI00174D
    20. Cory E. Hauke, Timothy R. Cook. Self-Assembly Processes for the Construction of Supramolecular Coordination Compounds. 2021, 1074-1085. https://doi.org/10.1016/B978-0-08-102688-5.00084-2
    21. Lindsey J. Monger, Gerdur R. Runarsdottir, Sigridur G. Suman. Directed coordination study of [Pd(en)(H2O)2]2+ with hetero-tripeptides containing C-terminus methyl esters employing NMR spectroscopy. JBIC Journal of Biological Inorganic Chemistry 2020, 25 (5) , 811-825. https://doi.org/10.1007/s00775-020-01804-0
    22. Kazuya Kubo, Masashi Yoshitake, Norihisa Hoshino, Shin‐ichiro Noro, Tomoyuki Akutagawa, Takayoshi Nakamura. Stable Ferromagnetic Crystal of Two‐Dimensional Manganese‐Chromium Oxalate with Supramolecular Cation. European Journal of Inorganic Chemistry 2020, 2020 (17) , 1670-1675. https://doi.org/10.1002/ejic.202000149
    23. Bruno Therrien. Thermotropic Liquid-Crystalline Materials Based on Supramolecular Coordination Complexes. Inorganics 2020, 8 (1) , 2. https://doi.org/10.3390/inorganics8010002
    24. Devjanee Bardhan, Dillip Kumar Chand. Palladium(II)‐Based Self‐Assembled Heteroleptic Coordination Architectures: A Growing Family. Chemistry – A European Journal 2019, 25 (53) , 12241-12269. https://doi.org/10.1002/chem.201900831
    25. Kristina E. Ebbert, Laura Schneider, André Platzek, Christoph Drechsler, Bin Chen, Robin Rudolf, Guido H. Clever. Resolution of minor size differences in a family of heteroleptic coordination cages by trapped ion mobility ESI-MS. Dalton Transactions 2019, 48 (29) , 11070-11075. https://doi.org/10.1039/C9DT01814J
    26. Hong-Gang Zhang, Yu-Chang Du, Hua Yang, Man-Yun Zhuang, Da-Cheng Li, Jian-Min Dou. A new family of {Co 4 Ln 8 } metallacrowns with a butterfly-shaped structure. Inorganic Chemistry Frontiers 2019, 6 (7) , 1904-1908. https://doi.org/10.1039/C9QI00661C
    27. Yaqin Wang, Xinxin Xu, Luyao Liu, Jin Chen, Guimei Shi. A coordination polymer-derived Co 3 O 4 /Co–N@NMC composite material as a Zn–air battery cathode electrocatalyst and microwave absorber. Dalton Transactions 2019, 48 (21) , 7150-7157. https://doi.org/10.1039/C8DT03792B
    28. András Ozsváth, Etelka Farkas, Róbert Diószegi, Péter Buglyó. Versatility and trends in the interaction between Pd( ii ) and peptide hydroxamic acids. New Journal of Chemistry 2019, 43 (21) , 8239-8249. https://doi.org/10.1039/C9NJ00296K
    29. Udit Kumar, Shilpa Jose, Dhanaraj Divya, Pitchavel Vidhyapriya, Natarajan Sakthivel, Bala. Manimaran. Self-assembly of manganese( i ) based thiolato bridged dinuclear metallacycles: synthesis, characterization, cytotoxicity evaluation and CO-releasing studies. New Journal of Chemistry 2019, 43 (19) , 7520-7531. https://doi.org/10.1039/C8NJ06271D
    30. Wen-Xi Gao, Hai-Ning Zhang, Guo-Xin Jin. Supramolecular catalysis based on discrete heterometallic coordination-driven metallacycles and metallacages. Coordination Chemistry Reviews 2019, 386 , 69-84. https://doi.org/10.1016/j.ccr.2019.01.023
    31. Madhan Ramesh, Galmari Venkatachalam. Half‒Sandwich (η6‒p‒Cymene) Ruthenium(II) complexes bearing 5‒Amino‒1‒Methyl‒3‒Phenylpyrazole Schiff base ligands: Synthesis, structure and catalytic transfer hydrogenation of ketones. Journal of Organometallic Chemistry 2019, 880 , 47-55. https://doi.org/10.1016/j.jorganchem.2018.10.029
    32. Jiyong Hu, Shufang Chen, Ruina Mao, Chunli Liao, Hao Yang, Jin'an Zhao. Cytotoxicity, dual-targeting apoptosis induction evaluation of multinuclear cu complexes based on pyrazine-benzimidazole derivative. Journal of Inorganic Biochemistry 2018, 186 , 246-256. https://doi.org/10.1016/j.jinorgbio.2018.06.014
    33. M. Karthikeyan, R. Govindarajan, Chowan Ashok Kumar, Udit Kumar, Bala. Manimaran. Rectangular and hammock shaped ester functionalized chalcogenolato-bridged rhenium(I) tetranuclear metallacyclophanes. Journal of Organometallic Chemistry 2018, 866 , 27-34. https://doi.org/10.1016/j.jorganchem.2018.04.002
    34. Shao-Chuan Li, Ting Zhang, Xing-Ping Deng, Xiao-Qing Guo, Li-Peng Zhou, Fang Guo, Qing-Fu Sun. Squaric acid-directed transformation of metal-organic macrocycles. Inorganic Chemistry Communications 2018, 92 , 69-73. https://doi.org/10.1016/j.inoche.2018.04.008
    35. Qi-Jia Fan, Yue-Jian Lin, F. Ekkehardt Hahn, Guo-Xin Jin. Host–guest capability of a three-dimensional heterometallic macrocycle. Dalton Transactions 2018, 47 (7) , 2240-2246. https://doi.org/10.1039/C7DT04453D
    36. Li-Long Dang, Yue-Jian Lin, Guo-Xin Jin. Controllable assembly of rectangular macrocycles bearing different numbers of unsaturated sites based on half-sandwich iridium fragments. Dalton Transactions 2018, 47 (18) , 6378-6385. https://doi.org/10.1039/C8DT00461G
    37. Bei-Bei Guo, Wen-Xi Gao, Yue-Jian Lin, Guo-Xin Jin. Construction of half-sandwich multinuclear complexes including tunnel architectures via C–H-activation-directed assembly. Dalton Transactions 2018, 47 (23) , 7701-7708. https://doi.org/10.1039/C8DT01140K
    38. Qiong Wu, Yanbing Han, Zhichao Shao, Junxia Li, Hongwei Hou. Stable Fe( ii )-based coordination polymers: synthesis, structural diversity and catalytic applications in homo-coupling reactions. Dalton Transactions 2018, 47 (24) , 8063-8069. https://doi.org/10.1039/C8DT01839A
    39. Francisco Aznarez, Wen-Xi Gao, Yue-Jian Lin, F. Ekkehardt Hahn, Guo-Xin Jin. Preparation of polynuclear NHC complexes by post-synthetic modification of half-sandwich rhodium and iridium complexes bearing C-azolato ligands. Dalton Transactions 2018, 47 (28) , 9442-9452. https://doi.org/10.1039/C8DT02212G
    40. Zhilong Jiang, Yiming Li, Ming Wang, Die Liu, Jie Yuan, Mingzhao Chen, Jun Wang, George R. Newkome, Wei Sun, Xiaopeng Li, Pingshan Wang. Constructing High‐Generation Sierpiński Triangles by Molecular Puzzling. Angewandte Chemie 2017, 129 (38) , 11608-11613. https://doi.org/10.1002/ange.201705480
    41. Zhilong Jiang, Yiming Li, Ming Wang, Die Liu, Jie Yuan, Mingzhao Chen, Jun Wang, George R. Newkome, Wei Sun, Xiaopeng Li, Pingshan Wang. Constructing High‐Generation Sierpiński Triangles by Molecular Puzzling. Angewandte Chemie International Edition 2017, 56 (38) , 11450-11455. https://doi.org/10.1002/anie.201705480
    42. Sheng-Li Huang, T.S. Andy Hor, Guo-Xin Jin. Photodriven single-crystal-to-single-crystal transformation. Coordination Chemistry Reviews 2017, 346 , 112-122. https://doi.org/10.1016/j.ccr.2016.06.009
    43. Ying‐Ying Zhang, Wen‐Xi Gao, Yue‐Jian Lin, Li‐Wei Mi, Guo‐Xin Jin. Syntheses, Structures, and Solution Studies of Multicomponent Macrocycles and Cages Based on Versatile Ligands. Chemistry – A European Journal 2017, 23 (46) , 11133-11140. https://doi.org/10.1002/chem.201702244
    44. Ying-Ying Zhang, Wen-Xi Gao, Lin Lin, Guo-Xin Jin. Recent advances in the construction and applications of heterometallic macrocycles and cages. Coordination Chemistry Reviews 2017, 344 , 323-344. https://doi.org/10.1016/j.ccr.2016.09.010
    45. Lin Lin, Qi-Jia Fan, Guo-Xin Jin. Half-sandwich rhodium and iridium fragments and carboxylate ligands as building blocks for the formation of metallamacrocycles. Journal of Organometallic Chemistry 2017, 829 , 85-91. https://doi.org/10.1016/j.jorganchem.2016.11.014
    46. D. Stíbal, B. Therrien. Organometallic Chemistry in Directed Assembly. 2017, 305-329. https://doi.org/10.1016/B978-0-12-409547-2.12592-2
    47. Xiu-Xiu Li, Qing-Ya He, Fanghui Wu, Guozan Yuan, Wei-Bin Yu. A novel organometallic macrocycle based on half-sandwich ruthenium motif. Inorganica Chimica Acta 2017, 454 , 54-57. https://doi.org/10.1016/j.ica.2016.03.001
    48. Witold M. Bloch, Guido H. Clever. Integrative self-sorting of coordination cages based on ‘naked’ metal ions. Chemical Communications 2017, 53 (61) , 8506-8516. https://doi.org/10.1039/C7CC03379F
    49. Mingzhao Chen, Jun Wang, Sourav Chakraborty, Die Liu, Zhilong Jiang, Qianqian Liu, Jun Yan, Hong Zhong, George R. Newkome, Pingshan Wang. Metallosupramolecular 3D assembly of dimetallic Zn 4 [RuL 2 ] 2 and trimetallic Fe 2 Zn 2 [RuL 2 ] 2. Chem. Commun. 2017, 53 (80) , 11087-11090. https://doi.org/10.1039/C7CC05577C
    50. Bei-Bei Guo, Yue-Jian Lin, Guo-Xin Jin. Controllable construction of half-sandwich octanuclear complexes based on pyridyl-substituted ligands with conjugated centers. Dalton Transactions 2017, 46 (25) , 8190-8197. https://doi.org/10.1039/C7DT00836H
    51. Xiao-Yan Tang, Hong Yu, Bin-Bin Gao, Jian-Ping Lang. [Cd(H 2 O) 6 ]@{Cd 6 Cl 4 (nico) 12 [Hg(Tab) 2 (μ-Cl)] 2 }: a heterometallic host–guest icosidodecahedron cage via hierarchical assembly. Dalton Transactions 2017, 46 (43) , 14724-14727. https://doi.org/10.1039/C7DT02679J
    52. Malgorzata Ostrowska, Igor O. Fritsky, Elzbieta Gumienna-Kontecka, Anna V. Pavlishchuk. Metallacrown-based compounds: Applications in catalysis, luminescence, molecular magnetism, and adsorption. Coordination Chemistry Reviews 2016, 327-328 , 304-332. https://doi.org/10.1016/j.ccr.2016.04.017
    53. Jia-Ming Li, Kun-Huan He, Zhong-Feng Shi, Hui-Yuan Gao, Yi-Min Jiang. Synthesis, crystal structures, and thermal and spectroscopic properties of two Cd(II) metal-organic frameworks with a versatile ligand. Zeitschrift für Naturforschung B 2016, 71 (8) , 909-917. https://doi.org/10.1515/znb-2016-0077
    54. Mohanad Darawsheh, Leoni A. Barrios, Olivier Roubeau, Simon J. Teat, Guillem Aromí. Guest‐, Light‐ and Thermally‐Modulated Spin Crossover in [Fe II 2 ] Supramolecular Helicates. Chemistry – A European Journal 2016, 22 (25) , 8635-8645. https://doi.org/10.1002/chem.201601080
    55. Sreenivasulu Bandi, Sagarika Samantray, Rajan Deepan Chakravarthy, Amlan K. Pal, Garry S. Hanan, Dillip Kumar Chand. Double‐Decker Coordination Cages. European Journal of Inorganic Chemistry 2016, 2016 (17) , 2816-2827. https://doi.org/10.1002/ejic.201600259
    56. Wei-Guo Jia, Hui Zhang, Tai Zhang, Shuo Ling. Synthesis, structures and catalytic activities of half-sandwich ruthenium complexes based on Schiff Base ligands. Inorganic Chemistry Communications 2016, 66 , 15-18. https://doi.org/10.1016/j.inoche.2016.02.001
    57. K. Alison Rinderspacher. Six-Membered Ring Systems. 2016, 439-492. https://doi.org/10.1016/B978-0-08-100755-6.00013-2
    58. Wei-Bin Yu, Qing-Ya He, Hua-Tian Shi, Xianwen Wei. Heterogeneous catalysis of water oxidation supported by a novel metallamacrocycle. New Journal of Chemistry 2016, 40 (3) , 2354-2361. https://doi.org/10.1039/C5NJ02931G
    59. Jordan Holmes, Christopher M. Pask, Mark A. Fox, Charlotte E. Willans. Tethered N-heterocyclic carbene–carboranes: unique ligands that exhibit unprecedented and versatile coordination modes at rhodium. Chemical Communications 2016, 52 (38) , 6443-6446. https://doi.org/10.1039/C6CC01650B
    60. Jing-Jing Liu, Yue-Jian Lin, Zhen-Hua Li, Guo-Xin Jin. Self-assembled half-sandwich polyhedral cages via flexible Schiff-base ligands: an unusual macrocycle-to-cage conversion. Dalton Transactions 2016, 45 (35) , 13675-13679. https://doi.org/10.1039/C6DT02393B
    61. Yue-Jian Lin, Wei-Long Shan, Guo-Xin Jin. A nonanuclear triangular macrocycle and a linear heptanuclear heterometallic complex based on a 2-substituted imidazole-4,5-dicarboxylate ligand. Dalton Transactions 2016, 45 (32) , 12680-12684. https://doi.org/10.1039/C6DT02460B
    62. Prodip Howlader, Partha Sarathi Mukherjee. Face and edge directed self-assembly of Pd 12 tetrahedral nano-cages and their self-sorting. Chemical Science 2016, 7 (9) , 5893-5899. https://doi.org/10.1039/C6SC02012G
    Download PDF
    Go to Journal of the American Chemical Society
    Get e-Alerts
    Get e-Alerts

    Journal of the American Chemical Society

    Cite this: J. Am. Chem. Soc. 2015, 137, 42, 13670–13678
    Click to copy citationCitation copied!
    https://doi.org/10.1021/jacs.5b08826
    Published October 6, 2015
    Copyright © 2015 American Chemical Society
    Request reuse permissions

    Article Views

    4019

    Altmetric

    -

    Citations

    62
    Learn about these metrics

    Article Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.

    Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.

    The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated.