logo

OR SEARCH CITATIONS

My Activity
Publications
CONTENT TYPES

Figure 1Loading Img
Download Hi-Res ImageDownload to MS-PowerPointCite This:J. Am. Chem. Soc. 2016, 138, 29, 9101-9104
RETURN TO ISSUEPREVCommunicationNEXT

A New Deep-Ultraviolet Transparent Orthophosphate LiCs2PO4 with Large Second Harmonic Generation Response

View Author Information
† Key Laboratory of Functional Materials and Devices for Special Environments of CAS, Xinjiang Key Laboratory of Electronic Information Materials and Devices, Xinjiang Technical Institute of Physics & Chemistry of CAS, 40-1 South Beijing Road, Urumqi 830011, China
‡ University of Chinese Academy of Sciences, Beijing 100049, China
§ Department of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, Illinois 60208-3113, United States
*[email protected]
*[email protected]
Cite this: J. Am. Chem. Soc. 2016, 138, 29, 9101–9104
Publication Date (Web):July 12, 2016
https://doi.org/10.1021/jacs.6b06053
Copyright © 2016 American Chemical Society
RIGHTS & PERMISSIONS
Article Views
1621
Altmetric
-
Citations
141
LEARN ABOUT THESE METRICS

Article Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.

Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.

The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated.

Read OnlinePDF (656 KB)
Supporting Info (2)»
SUBJECTS:

Abstract

Abstract Image

LiCs2PO4, a new deep-ultraviolet (UV) transparent material, was synthesized by the flux method. The material contains unusual edge-sharing LiO4-PO4 tetrahedra. It exhibits a very short absorption edge of λ = 174 nm and generates the largest powder second harmonic generation (SHG) response for deep-UV phosphates that do not contain additional anionic groups, i.e., 2.6 times that of KH2PO4 (KDP). First-principles electronic structure analyses confirm the experimental results and suggest that the strong SHG response may originate from the aligned nonbonding O-2p orbitals. The discovery and characterization of LiCs2PO4 provide a new insight into the structure–property relationships of phosphate-based nonlinear optical materials with large SHG responses and short absorption edges.

Supporting Information

ARTICLE SECTIONS
Jump To

The Supporting Information is available free of charge on the ACS Publications website at DOI: 10.1021/jacs.6b06053.

  • Experimental methods and additional tables and figures (PDF)

  • Crystallographic data (TXT)

Terms & Conditions

Electronic Supporting Information files are available without a subscription to ACS Web Editions. The American Chemical Society holds a copyright ownership interest in any copyrightable Supporting Information. Files available from the ACS website may be downloaded for personal use only. Users are not otherwise permitted to reproduce, republish, redistribute, or sell any Supporting Information from the ACS website, either in whole or in part, in either machine-readable form or any other form without permission from the American Chemical Society. For permission to reproduce, republish and redistribute this material, requesters must process their own requests via the RightsLink permission system. Information about how to use the RightsLink permission system can be found at http://pubs.acs.org/page/copyright/permissions.html.

Cited By

This article is cited by 141 publications.

  1. Tuohetijiang Baiheti, Shujuan Han, Abudukadi Tudi, Zhihua Yang, Shilie Pan. Alignment of Polar Moieties Leading to Strong Second Harmonic Response in KCsMoP2O9. Chemistry of Materials 2020, 32 (7) , 3297-3303. https://doi.org/10.1021/acs.chemmater.0c00610
  2. Qingran Ding, Xiaomeng Liu, Sangen Zhao, Yusong Wang, Yanqiang Li, Lina Li, Shuai Liu, Zheshuai Lin, Maochun Hong, Junhua Luo. Designing a Deep-UV Nonlinear Optical Fluorooxosilicophosphate. Journal of the American Chemical Society 2020, 142 (14) , 6472-6476. https://doi.org/10.1021/jacs.0c00060
  3. Guangda Wu, Mengdi Fan, Chao Jiang, Feifei Chen, Fapeng Yu, Xiufeng Cheng, Xian Zhao. Noncentrosymmetric Orthophosphate YM3(PO4)3 (M = Sr, Ba) Crystals: Single Crystal Growth, Structure, and Properties. Crystal Growth & Design 2020, 20 (4) , 2390-2397. https://doi.org/10.1021/acs.cgd.9b01554
  4. Ming Wen, Hongping Wu, Xiaohong Wu. Influence of Cation on the Anion Frameworks and Properties of Four Lead Phosphates, A2PbBi2(PO4)2(P2O7) (A = Rb, Cs) and A2PbP2O7 (A = K, Rb). Inorganic Chemistry 2020, 59 (5) , 2945-2951. https://doi.org/10.1021/acs.inorgchem.9b03299
  5. Xiyue Cheng, ZhenHua Li, Xin-Tao Wu, Maochun Hong, Myung-Hwan Whangbo, Shuiquan Deng. Key Factors Controlling the Large Second Harmonic Generation in Nonlinear Optical Materials. ACS Applied Materials & Interfaces 2020, 12 (8) , 9434-9439. https://doi.org/10.1021/acsami.9b20023
  6. Zhiyong Bai, Chun-Li Hu, Lehui Liu, Lizhen Zhang, Yisheng Huang, Feifei Yuan, Zhoubin Lin. KMg(H2O)PO4: A Deep-Ultraviolet Transparent Nonlinear Optical Material Derived from KTiOPO4. Chemistry of Materials 2019, 31 (22) , 9540-9545. https://doi.org/10.1021/acs.chemmater.9b03950
  7. Bao-Lin Wu, Chun-Li Hu, Fei-Fei Mao, Ru-Ling Tang, Jiang-Gao Mao. Highly Polarizable Hg2+ Induced a Strong Second Harmonic Generation Signal and Large Birefringence in LiHgPO4. Journal of the American Chemical Society 2019, 141 (26) , 10188-10192. https://doi.org/10.1021/jacs.9b05125
  8. Guido Zichittella, Samuel Stähelin, Florian M. Goedicke, Javier Pérez-Ramírez. Selective Propylene Production via Propane Oxychlorination on Metal Phosphate Catalysts. ACS Catalysis 2019, 9 (6) , 5772-5782. https://doi.org/10.1021/acscatal.9b01315
  9. Jing Lu, Jia-Ning Yue, Lin Xiong, Wen-Kai Zhang, Ling Chen, Li-Ming Wu. Uniform Alignment of Non-π-Conjugated Species Enhances Deep Ultraviolet Optical Nonlinearity. Journal of the American Chemical Society 2019, 141 (20) , 8093-8097. https://doi.org/10.1021/jacs.9b03858
  10. Yunfei Li, Fei Liang, Huimin Song, Wang Liu, Zheshuai Lin, Guochun Zhang, Yicheng Wu. LiGaP2O7: A Potential UV Nonlinear-Optical Crystal. Inorganic Chemistry 2019, 58 (10) , 6597-6600. https://doi.org/10.1021/acs.inorgchem.9b00970
  11. Yutong Shi, Min Luo, Chensheng Lin, Guang Peng, Ning Ye. Two Deep Ultraviolet Hydrated Borate Crystals: Centrosymmetric LiRbB5O8(OH)·H2O and Non-Centrosymmetric K2B5O8(OH)·2H2O. Crystal Growth & Design 2019, 19 (5) , 3052-3059. https://doi.org/10.1021/acs.cgd.9b00365
  12. Yahui Li, Guopeng Han, Hongwei Yu, Hao Li, Zhihua Yang, Shilie Pan. Two Polar Molybdenum(VI) Iodates(V) with Large Second-Harmonic Generation Responses. Chemistry of Materials 2019, 31 (8) , 2992-3000. https://doi.org/10.1021/acs.chemmater.9b00521
  13. Xia-Yan Tang, Jin-Xiao Mi, Rong-Chuan Zhuang, Shuai-Hua Wang, Shao-Fan Wu, Yuanming Pan, Ya-Xi Huang. Rational Design and Synthesis of a Deep-Ultraviolet Nonlinear Optical Fluorinated Orthophosphate: BaZn(PO4)F. Inorganic Chemistry 2019, 58 (7) , 4508-4514. https://doi.org/10.1021/acs.inorgchem.9b00073
  14. Liling Cao, Yunxia Song, Guang Peng, Min Luo, Yi Yang, Chen-sheng Lin, Dan Zhao, Feng Xu, Zheshuai Lin, Ning Ye. Refractive Index Modulates Second-Harmonic Responses in RE8O(CO3)3(OH)15X (RE = Y, Lu; X = Cl, Br): Rare-Earth Halide Carbonates as Ultraviolet Nonlinear Optical Materials. Chemistry of Materials 2019, 31 (6) , 2130-2137. https://doi.org/10.1021/acs.chemmater.9b00068
  15. Yanqiang Li, Fei Liang, Sangen Zhao, Lina Li, Zhenyue Wu, Qingran Ding, Shuai Liu, Zheshuai Lin, Maochun Hong, Junhua Luo. Two Non-π-Conjugated Deep-UV Nonlinear Optical Sulfates. Journal of the American Chemical Society 2019, 141 (9) , 3833-3837. https://doi.org/10.1021/jacs.9b00138
  16. Donghong Lin, Min Luo, Chensheng Lin, Feng Xu, Ning Ye. KLi(HC3N3O3)·2H2O: Solvent-drop Grinding Method toward the Hydro-isocyanurate Nonlinear Optical Crystal. Journal of the American Chemical Society 2019, 141 (8) , 3390-3394. https://doi.org/10.1021/jacs.8b13280
  17. Bingqing Zhao, Bingxuan Li, Sangen Zhao, Xitao Liu, Zhenyue Wu, Yaoguo Shen, Xianfeng Li, Qingran Ding, Chengmin Ji, Junhua Luo. Physical Properties of a Promising Nonlinear Optical Crystal K3Ba3Li2Al4B6O20F. Crystal Growth & Design 2018, 18 (12) , 7368-7372. https://doi.org/10.1021/acs.cgd.8b01054
  18. Lin Xiong, Jie Chen, Jing Lu, Chun-Ya Pan, Li-Ming Wu. Monofluorophosphates: A New Source of Deep-Ultraviolet Nonlinear Optical Materials. Chemistry of Materials 2018, 30 (21) , 7823-7830. https://doi.org/10.1021/acs.chemmater.8b03310
  19. Yaoguo Shen, Yi Yang, Sangen Zhao, Xianfeng Li, Qingran Ding, Yanqiang Li, Shuai Liu, Zheshuai Lin, Junhua Luo. A Langbeinite-Type Yttrium Phosphate LiCs2Y2(PO4)3. Inorganic Chemistry 2018, 57 (21) , 13087-13091. https://doi.org/10.1021/acs.inorgchem.8b02491
  20. Jie Chen, Lin Xiong, Ling Chen, Li-Ming Wu. Ba2NaClP2O7: Unprecedented Phase Matchability Induced by Symmetry Breaking and Its Unique Fresnoite-Type Structure. Journal of the American Chemical Society 2018, 140 (43) , 14082-14086. https://doi.org/10.1021/jacs.8b10209
  21. Yi Yang, Yi Qiu, Pifu Gong, Qian Huang, Sangen Zhao, Siyang Luo, Junliang Sun, Zheshuai Lin. Synthesis, Structure, and Properties of the Non-Centrosymmeteric Compound LiNaRbB5O8(OH)2. Crystal Growth & Design 2018, 18 (10) , 5745-5749. https://doi.org/10.1021/acs.cgd.8b01073
  22. Zhaohui Chen, Yuan Fang, Wenyao Zhang, Wenqiang Chen, Xuefang Lu, Qun Jing, Ming-Hsien Lee. ALiZnP2O7 (A = Rb, Cs): Two Mixed Alkali Zinc Pyrophosphates Featuring a [Li2Zn2P4O20]14– Anionic Skeleton. Inorganic Chemistry 2018, 57 (17) , 10568-10575. https://doi.org/10.1021/acs.inorgchem.8b01140
  23. Bing-Hua Lei, Zhihua Yang, Hongwei Yu, Chao Cao, Zhi Li, Cong Hu, Kenneth R. Poeppelmeier, Shilie Pan. Module-Guided Design Scheme for Deep-Ultraviolet Nonlinear Optical Materials. Journal of the American Chemical Society 2018, 140 (34) , 10726-10733. https://doi.org/10.1021/jacs.8b03057
  24. Bingbing Zhang, Guopeng Han, Ying Wang, Xinglong Chen, Zhihua Yang, Shilie Pan. Expanding Frontiers of Ultraviolet Nonlinear Optical Materials with Fluorophosphates. Chemistry of Materials 2018, 30 (15) , 5397-5403. https://doi.org/10.1021/acs.chemmater.8b02223
  25. Yahui Li, Hongping Wu, Bingbing Zhang, Zhihua Yang, Guopeng Han, Shilie Pan. Mo6+ Cation Enrichment of the Structure Chemistry of Iodates: Syntheses, Structures, and Calculations of Ba(MoO2)2(IO3)4O, Ba3[(MoO2)2(IO3)4O(OH)4]·2H2O, and Sr[(MoO2)6(IO4)2O4]·H2O. Inorganic Chemistry 2018, 57 (15) , 9376-9384. https://doi.org/10.1021/acs.inorgchem.8b01365
  26. Lizhen Zhang, Hui Wu, Yanping Lin, FeiFei Yuan, Yisheng Huang, Shijia Sun, Bing Teng, Lingyun Li, Zhoubin Lin. From Sr2Nb2O7 to CaxSr2–xNb2O7: An Effective Enhancement of Nonlinear Optical Activity by a Simple Way of Cation Substituting. Crystal Growth & Design 2018, 18 (7) , 4140-4149. https://doi.org/10.1021/acs.cgd.8b00584
  27. Maierhaba Abudoureheman, Xiaobo Pan, Shujuan Han, Yilimiranmu Rouzhahong, Zhihua Yang, Hongping Wu, Shilie Pan. MIMIIP3O9 (MI = Rb, MII = Cd, Mg, Ca; MI = Cs, MII = Pb, Sr; MI = K, MII = Mg): Cation Substitution Application in Cyclophosphate Family and Nonlinear Optical Properties. Inorganic Chemistry 2018, 57 (12) , 7372-7379. https://doi.org/10.1021/acs.inorgchem.8b01017
  28. Min Luo, Fei Liang, Yunxia Song, Dan Zhao, Ning Ye, Zheshuai Lin. Rational Design of the First Lead/Tin Fluorooxoborates MB2O3F2 (M = Pb, Sn), Containing Flexible Two-Dimensional [B6O12F6]∞ Single Layers with Widely Divergent Second Harmonic Generation Effects. Journal of the American Chemical Society 2018, 140 (22) , 6814-6817. https://doi.org/10.1021/jacs.8b04333
  29. Qiang Bian, Zhihua Yang, Yanchao Wang, Miriding Mutailipu, Yanming Ma, Shilie Pan. Computer-Assisted Design of a Superior Be2BO3F Deep-Ultraviolet Nonlinear-Optical Material. Inorganic Chemistry 2018, 57 (10) , 5716-5719. https://doi.org/10.1021/acs.inorgchem.8b00557
  30. Min Luo, Fei Liang, Yunxia Song, Dan Zhao, Feng Xu, Ning Ye, Zheshuai Lin. M2B10O14F6 (M = Ca, Sr): Two Noncentrosymmetric Alkaline Earth Fluorooxoborates as Promising Next-Generation Deep-Ultraviolet Nonlinear Optical Materials. Journal of the American Chemical Society 2018, 140 (11) , 3884-3887. https://doi.org/10.1021/jacs.8b01263
  31. Sangen Zhao, Xiaoyan Yang, Yi Yang, Xiaojun Kuang, Fengqi Lu, Pai Shan, Zhihua Sun, Zheshuai Lin, Maochun Hong, and Junhua Luo . Non-Centrosymmetric RbNaMgP2O7 with Unprecedented Thermo-Induced Enhancement of Second Harmonic Generation. Journal of the American Chemical Society 2018, 140 (5) , 1592-1595. https://doi.org/10.1021/jacs.7b12518
  32. Qun Jing, Guang Yang, Zhaohui Chen, Xiaoyu Dong, and Yunjing Shi . A Joint Strategy To Evaluate the Microscopic Origin of the Second-Harmonic-Generation Response in Nonpolar ABCO3F Compounds. Inorganic Chemistry 2018, 57 (3) , 1251-1258. https://doi.org/10.1021/acs.inorgchem.7b02689
  33. Miriding Mutailipu, Zhiqing Xie, Xin Su, Min Zhang, Ying Wang, Zhihua Yang, Muhammad Ramzan Saeed Ashraf Janjua, and Shilie Pan . Chemical Cosubstitution-Oriented Design of Rare-Earth Borates as Potential Ultraviolet Nonlinear Optical Materials. Journal of the American Chemical Society 2017, 139 (50) , 18397-18405. https://doi.org/10.1021/jacs.7b11263
  34. Kui Wu, Bingbing Zhang, Zhihua Yang, and Shilie Pan . New Compressed Chalcopyrite-like Li2BaMIVQ4 (MIV = Ge, Sn; Q = S, Se): Promising Infrared Nonlinear Optical Materials. Journal of the American Chemical Society 2017, 139 (42) , 14885-14888. https://doi.org/10.1021/jacs.7b08966
  35. Ying Wang, Lin Li, Shujuan Han, Bing-Hua Lei, Maierhaba Abudoureheman, Zhihua Yang, and Shilie Pan . Linear-to-λ-Shape P–O–P Bond Transmutation in Polyphosphates with Infinite (PO3)∞ Chain. Inorganic Chemistry 2017, 56 (17) , 10139-10142. https://doi.org/10.1021/acs.inorgchem.7b01540
  36. Hongping Wu, Hongwei Yu, Shilie Pan, and P. Shiv Halasyamani . Deep-Ultraviolet Nonlinear-Optical Material K3Sr3Li2Al4B6O20F: Addressing the Structural Instability Problem in KBe2BO3F2. Inorganic Chemistry 2017, 56 (15) , 8755-8758. https://doi.org/10.1021/acs.inorgchem.7b01517
  37. Bing-Ping Yang, Chun-Li Hu, Fei-Fei Mao, Xiang Xu, and Jiang-Gao Mao . Two Barium Gold Iodates: Syntheses, Structures, and Properties of Polar BaAu(IO3)5 and Nonpolar HBa4Au(IO3)12 Materials. Inorganic Chemistry 2017, 56 (12) , 7230-7236. https://doi.org/10.1021/acs.inorgchem.7b00872
  38. Zhaohui Chen, Zhizhong Zhang, Xiaoyu Dong, Yunjing Shi, Yaqin Liu, and Qun Jing . Li3VO4: A Promising Mid-Infrared Nonlinear Optical Material with Large Laser Damage Threshold. Crystal Growth & Design 2017, 17 (5) , 2792-2800. https://doi.org/10.1021/acs.cgd.7b00250
  39. Maierhaba Abudoureheman, Shujuan Han, Ying Wang, Bing-Hua Lei, Zhihua Yang, and Shilie Pan . A3Sr2P7O21 (A = Rb, Cs): Two Polyphosphates Based on Different Types of P–O Chains and Ring Structures. Inorganic Chemistry 2017, 56 (7) , 3939-3945. https://doi.org/10.1021/acs.inorgchem.6b03032
  40. Hongping Wu, Hongwei Yu, Weiguo Zhang, Jacqueline Cantwell, Kenneth R. Poeppelmeier, Shilie Pan, and P. Shiv Halasyamani . Top-Seeded Solution Crystal Growth and Linear and Nonlinear Optical Properties of Ba4B11O20F. Crystal Growth & Design 2017, 17 (3) , 1404-1410. https://doi.org/10.1021/acs.cgd.6b01857
  41. Hongwei Yu, Joshua Young, Hongping Wu, Weiguo Zhang, James M. Rondinelli, and P. Shiv Halasyamani . M4Mg4(P2O7)3 (M = K, Rb): Structural Engineering of Pyrophosphates for Nonlinear Optical Applications. Chemistry of Materials 2017, 29 (4) , 1845-1855. https://doi.org/10.1021/acs.chemmater.7b00167
  42. Yaoguo Shen, Sangen Zhao, Bingqing Zhao, Chengmin Ji, Lina Li, Zhihua Sun, Maochun Hong, and Junhua Luo . Strong Nonlinear-Optical Response in the Pyrophosphate CsLiCdP2O7 with a Short Cutoff Edge. Inorganic Chemistry 2016, 55 (22) , 11626-11629. https://doi.org/10.1021/acs.inorgchem.6b02278
  43. Yaoguo Shen, Yi Yang, Sangen Zhao, Bingqing Zhao, Zheshuai Lin, Chengmin Ji, Lina Li, Ping Fu, Maochun Hong, and Junhua Luo . Deep-Ultraviolet Transparent Cs2LiPO4 Exhibits an Unprecedented Second Harmonic Generation. Chemistry of Materials 2016, 28 (19) , 7110-7116. https://doi.org/10.1021/acs.chemmater.6b03333
  44. Dulal Musib, Md Kausar Raza, Salam Sujata Devi, Mithun Roy. A reversible, benzothiazole-based “Turn-on” fluorescence sensor for selective detection of Zn2+ ions in vitro. Journal of Chemical Sciences 2020, 132 (1) https://doi.org/10.1007/s12039-020-1745-z
  45. Fei Yang, Lei Wang, Yuwei Ge, Ling Huang, Daojiang Gao, Jian Bi, Guohong Zou. K4Sb(SO4)3Cl: The first apatite-type sulfate ultraviolet nonlinear optical material with sharply enlarged birefringence. Journal of Alloys and Compounds 2020, 834 , 155154. https://doi.org/10.1016/j.jallcom.2020.155154
  46. Hongping Wu, Bingbing Zhang, Hongwei Yu, Zhanggui Hu, Jiyang Wang, Yicheng Wu, P. Shiv Halasyamani. Designing Silicates as Deep‐UV Nonlinear Optical (NLO) Materials using Edge‐Sharing Tetrahedra. Angewandte Chemie International Edition 2020, 59 (23) , 8922-8926. https://doi.org/10.1002/anie.202001855
  47. Ping Wei, Wenqiang Chen, Qun Jing, Ming-Hsien Lee, Zhaohui Chen. Effects of P2O7 clusters arrangement on second harmonic generation responses of pyrophosphates. Journal of Alloys and Compounds 2020, 827 , 153922. https://doi.org/10.1016/j.jallcom.2020.153922
  48. Ming Wen, Hongping Wu, Hongwei Yu, Xiaohong Wu. The first rare-earth lead phosphates Pb3AP3O12 (A=Sc, Gd) with remarkable SHG enhancement. Journal of Solid State Chemistry 2020, 286 , 121276. https://doi.org/10.1016/j.jssc.2020.121276
  49. Yaoguo Shen, Xiaoling Xue, Renwen Yan, Hong Lin. Synthesis, characterizations and theoretical analysis of a noncentrosymmetric sulfate. Inorganic Chemistry Communications 2020, 116 , 107899. https://doi.org/10.1016/j.inoche.2020.107899
  50. Jingjing Xu, Hongping Wu, Hongwei Yu, Zhanggui Hu, Jiyang Wang, Yicheng Wu. Syntheses, characterization and calculations of LimAnM6O15 (A=Rb, Cs; M=Si, Ge; m+n=6). Science China Materials 2020, 10 https://doi.org/10.1007/s40843-020-1310-1
  51. Xinglong Chen, Hongil Jo, Kang Min Ok. Lead Mixed Oxyhalides Satisfying All Fundamental Requirements for High‐Performance Mid‐Infrared Nonlinear Optical Materials. Angewandte Chemie 2020, 132 (19) , 7584-7590. https://doi.org/10.1002/ange.202002291
  52. Xinglong Chen, Hongil Jo, Kang Min Ok. Lead Mixed Oxyhalides Satisfying All Fundamental Requirements for High‐Performance Mid‐Infrared Nonlinear Optical Materials. Angewandte Chemie International Edition 2020, 59 (19) , 7514-7520. https://doi.org/10.1002/anie.202002291
  53. Hao Wang, Lei Geng, Yun-Jian Wang, Hong-Yan Lu, Chang-Yu Meng. Synthesis, characterization, and properties of two new phosphate crystals MZnAl(PO4)2 (M = Na, K) with 3D framework tunnel structures. Journal of Alloys and Compounds 2020, 820 , 153176. https://doi.org/10.1016/j.jallcom.2019.153176
  54. Hongping Wu, Shiwei Liu, Shichao Cheng, Hongwei Yu, Zhanggui Hu, Jiyang Wang, Yicheng Wu. Syntheses, characterization, and theoretical calculation of Rb2Mg3(P2O7)2 polymorphs with deep-ultraviolet cutoff edges. Science China Materials 2020, 63 (4) , 593-601. https://doi.org/10.1007/s40843-019-1221-0
  55. Yaoguo Shen, Xiaoling Xue, Wenyuan Tu, Zhiqun Liu, Renwen Yan, Hong Zhang, Junrong Jia. Synthesis, Crystal Structure, and Characterization of a Noncentrosymmetric Sulfate Cs 2 Ca 2 (SO 4 ) 3. European Journal of Inorganic Chemistry 2020, 2020 (10) , 854-858. https://doi.org/10.1002/ejic.202000025
  56. Hongping Wu, Bingbing Zhang, Hongwei Yu, Zhanggui Hu, Jiyang Wang, Yicheng Wu, P. Shiv Halasyamani. Designing Silicates as Deep‐UV Nonlinear Optical Materials using Edge‐sharing Tetrahedra. Angewandte Chemie 2020, https://doi.org/10.1002/ange.202001855
  57. Na Li, Xuefang Lu, Qun Jing, Ping Wei, Lu Qi, Zhongqi Jiang, Zhaohui Chen. β-Ba(PO3)2 with DUV cut-off edge and large birefringence. Materials Letters 2020, 262 , 127076. https://doi.org/10.1016/j.matlet.2019.127076
  58. Xun Chen, Yue Han, Qi Wei, Jie Pan, Song-De Han, Li Wei, Guo-Ming Wang. Ultraviolet nonlinear optical crystal: (NH4)ZnPO4. Inorganic Chemistry Communications 2020, 113 , 107803. https://doi.org/10.1016/j.inoche.2020.107803
  59. Xiao-Han Zhang, Bing-Ping Yang, Jin Chen, Chun-Li Hu, Zhi Fang, Zujian Wang, Jiang-Gao Mao. A new iodate-phosphate Pb 2 (IO 3 )(PO 4 ) achieving great improvement in birefringence activated by (IO 3 ) − groups. Chemical Communications 2020, 56 (4) , 635-638. https://doi.org/10.1039/C9CC08739G
  60. Zhongqi Jiang, Wenqiang Chen, Qun Jing, Ming-Hsien Lee, Zhaohui Chen. [NH4]12[(MoO2)2O(HPO4)2]4[PO4]Cl·0.5H2O: A mixed phosphomolybdate with nonlinear optical properties. Inorganica Chimica Acta 2020, 499 , 119198. https://doi.org/10.1016/j.ica.2019.119198
  61. Feng Xu, Guang Peng, Chensheng Lin, Dan Zhao, Bingxuan Li, Ge Zhang, Shunda Yang, Ning Ye. Na 3 Sc 2 (PO 4 ) 2 F 3 : rational design and synthesis of an alkali rare-earth phosphate fluoride as an ultraviolet nonlinear optical crystal with an enlarged birefringence. Journal of Materials Chemistry C 2020, 457 https://doi.org/10.1039/D0TC00281J
  62. Ming Wen, Cong Hu, Hongping Wu, Zhihua Yang, Xiaohong Wu, Shilie Pan. Three diphosphates, α-Li 2 Na 2 P 2 O 7 , Li 8 Pb 3 Ba(P 2 O 7 ) 4 and Li 7 Rb(P 2 O 7 ) 2 : influences of co-substitution on the crystal structure. Dalton Transactions 2020, 49 https://doi.org/10.1039/D0DT01070G
  63. Zhi Fang, Bingping Yang, Chunli Hu, Jianggao Mao. Hybridization-activated new deep ultraviolet transparent nonlinear optical material Ba 11 [Al(PO 4 ) 4 ](P 2 O 7 )(PO 4 ) 3 with balanced overall performance and parsimony-forbidden structure. Journal of Materials Chemistry C 2019, 7 (48) , 15162-15165. https://doi.org/10.1039/C9TC05648C
  64. Yadong Li. A solid-state chemist’s eye for the development of materials science in China. Science China Materials 2019, 62 (12) , 1783-1787. https://doi.org/10.1007/s40843-019-1194-0
  65. Kun Chai, Hongyi Li. Synthesis, characterization and theoretical calculation of a noncentrosymmetric compound, Cs0.92B0.92Si5.08O12. Journal of Physics and Chemistry of Solids 2019, 135 , 109109. https://doi.org/10.1016/j.jpcs.2019.109109
  66. Yunfei Li, Fei Liang, Huimin Song, Wang Liu, Zheshuai Lin, Guochun Zhang, Yicheng Wu. LiCsPbP2O7: A new alkali metal lead pyrophosphate featuring two dimensional [LiP2O7]∞ layer. Journal of Solid State Chemistry 2019, 280 , 120823. https://doi.org/10.1016/j.jssc.2019.06.028
  67. D. Vidhya, S. Ramalingam, S. Periandy, R. Aarthi. Crystal property and spectroscopic investigation on electro-optic and physico-chemical properties of NLO crystal; 3-(3,4-Dihydroxyphenyl)-L-Alanine. Heliyon 2019, 5 (12) , e03055. https://doi.org/10.1016/j.heliyon.2019.e03055
  68. Dan Zhao, Ya-Li Xue, Shi-Rui Zhang, Lin-Ying Shi, Bao-Zhong Liu, Yan-Ping Fan, Qing-Xia Yao, Shao-Jie Dai. Non-concentration quenching, good thermal stability and high quantum efficiency of K 5 Y(P 2 O 7 ) 2 :Eu 3+ /Tb 3+ phosphors with a novel two-dimensional layer structure. Journal of Materials Chemistry C 2019, 7 (45) , 14264-14274. https://doi.org/10.1039/C9TC04977K
  69. Qian Wang, Lei Wang, Xiaoyu Zhao, Ling Huang, Daojiang Gao, Jian Bi, Xin Wang, Guohong Zou. Centrosymmetric K 2 SO 4 ·(SbF 3 ) 2 and noncentrosymmetric Rb 2 SO 4 ·(SbF 3 ) 2 resulting from cooperative effects of lone pair and cation size. Inorganic Chemistry Frontiers 2019, 6 (11) , 3125-3132. https://doi.org/10.1039/C9QI01036J
  70. Shuaishuai Hu, Zhi Su. Two new tin( iv )-containing phosphate fluorides with two types of Sn( iv )–P–O–F frameworks and short cutoff edges. New Journal of Chemistry 2019, 43 (41) , 16127-16130. https://doi.org/10.1039/C9NJ04424H
  71. Jun Sun, Hongping Wu, Miriding Mutailipu, Zhihua Yang, Shilie Pan. Structural insights into three phosphates with distinct polyanionic configurations. Dalton Transactions 2019, 48 (35) , 13406-13412. https://doi.org/10.1039/C9DT02842K
  72. Kang Liu, Huimin Zhou, Peng Wang, Jia Fang, Hongmei Li, Maoqi Cao, Xiaohui Gao, Xiaoqing Qiu, Min Liu. Bismuth vanadate single crystal particles modified with tungsten for efficient photoeletrochemical water oxidation. Catalysis Today 2019, 335 , 511-519. https://doi.org/10.1016/j.cattod.2019.02.018
  73. Meng Wang, Dequan Wei, Lanju Liang, Xin Yan, Kaikai Lv. Centrosymmetric Rb2Mg3(SO4)4 and non-centrosymmetric Cs2Mg3(SO4)4 with a phase-matching nonlinear optical response. Inorganic Chemistry Communications 2019, 107 , 107486. https://doi.org/10.1016/j.inoche.2019.107486
  74. Naouel Boudghene Stambouli, Tarik Ouahrani, Michael Badawi, Ali H. Reshak, Sihem Azizi. Untangling electronic, optical and bonding properties of hexagonal bismuth borate SrBi2B2O7 crystal for ultraviolet opto-electronic applications: An ab initio study. Journal of Alloys and Compounds 2019, 803 , 1127-1135. https://doi.org/10.1016/j.jallcom.2019.06.346
  75. Huimin Song, Shengzi Zhang, Yunfei Li, Wang Liu, Zheshuai Lin, Jiyong Yao, Guochun Zhang. Syntheses, crystal structures, and characterizations of three new pyrophosphates CsNaZnP2O7, RbNaZnP2O7, and RbLiMgP2O7. Solid State Sciences 2019, 95 , 105940. https://doi.org/10.1016/j.solidstatesciences.2019.105940
  76. Kaichuang Chen, Yi Yang, Guang Peng, Shunda Yang, Tao Yan, Huixin Fan, Zheshuai Lin, Ning Ye. A 2 Bi 2 (SO 4 ) 2 Cl 4 (A = NH 4 , K, Rb): achieving a subtle balance of the large second harmonic generation effect and sufficient birefringence in sulfate nonlinear optical materials. Journal of Materials Chemistry C 2019, 7 (32) , 9900-9907. https://doi.org/10.1039/C9TC03105G
  77. Yang Zhong, Pai Shan, Tongqing Sun, Zhenpeng Hu, Hongde Liu, Shiguo Liu, Yongfa Kong, Jingjun Xu. Growth and theoretical study on the deep-ultraviolet transparent β-CsBa 2 (PO 3 ) 5 nonlinear optical crystal. CrystEngComm 2019, 21 (32) , 4690-4695. https://doi.org/10.1039/C9CE00636B
  78. Ming Wen, Hongping Wu, Zhihua Yang, Xiaohong Wu, Shilie Pan. An alkali metal phosphate RbPbBi 2 (PO 4 ) 3 with three kinds of disorder: the effect of isolated soft cation units on the crystal structure. Inorganic Chemistry Frontiers 2019, 6 (8) , 2050-2054. https://doi.org/10.1039/C9QI00591A
  79. Peng Ren, Yun Yang, Shilie Pan. The first barium lead oxychloride Ba27Pb8O8Cl54 with new isolated [Pb4O4] clusters. Journal of Molecular Structure 2019, 1190 , 23-28. https://doi.org/10.1016/j.molstruc.2019.03.028
  80. Lingyun Dong, Xusheng Ge, Pengfei Zhang, Qian Li, Sufang Sun, Shigang Shen. Further Example of Diphosphates: Synthesis and Characterization of K 2 Li 2 P 2 O 7. Zeitschrift für anorganische und allgemeine Chemie 2019, 645 (14) , 944-948. https://doi.org/10.1002/zaac.201900045
  81. Zhiyong Bai, Lehui Liu, Lizhen Zhang, Yisheng Huang, Feifei Yuan, Zhoubin Lin. K 2 SrP 4 O 12 : a deep-UV transparent cyclophosphate as a nonlinear optical crystal. Chemical Communications 2019, 55 (58) , 8454-8457. https://doi.org/10.1039/C9CC04192C
  82. Shujuan Han, Hao Li, Zhihua Yang, H. H. Yu, Shilie Pan. Three new phosphates, Cs8Pb4(P2O7)4, CsLi7(P2O7)2 and LiCa(PO3)3: structural comparison, characterization and theoretical calculation. Dalton Transactions 2019, 48 (24) , 8948-8954. https://doi.org/10.1039/C9DT01739A
  83. Fengjiao Guo, Jian Han, Jianian Cheng, Zhihua Yang, Tushagu Abudouwufu, Hongwei Yu, Shilie Pan. Cs 2 Zn 5 (PO 4 ) 4 and Cs 3 La(PO 4 ) 2 : Two Cs-Containing Phosphates with Three-Dimensional Frameworks. European Journal of Inorganic Chemistry 2019, 2019 (19) , 2462-2467. https://doi.org/10.1002/ejic.201900241
  84. Kun Chai, Shichao Cheng, Hongyi Li, Bin Dai. Modulation of perovskite-related frameworks induced by alkaline earth metals in phosphate fluorides A 2 MPO 4 F (A = K, Rb; M = Ba, Ca). New Journal of Chemistry 2019, 43 (20) , 7839-7845. https://doi.org/10.1039/C9NJ01051C
  85. Fangfang He, Yalan Deng, Xiaoyu Zhao, Ling Huang, Daojiang Gao, Jian Bi, Xin Wang, Guohong Zou. RbSbSO 4 Cl 2 : an excellent sulfate nonlinear optical material generated due to the synergistic effect of three asymmetric chromophores. Journal of Materials Chemistry C 2019, 7 (19) , 5748-5754. https://doi.org/10.1039/C9TC01249D
  86. Yi Yang, Yi Qiu, Pifu Gong, Lei Kang, Gaomin Song, Xiaomeng Liu, Junliang Sun, Zheshuai Lin. Lone‐Pair Enhanced Birefringence in an Alkaline‐Earth Metal Tin(II) Phosphate BaSn 2 (PO 4 ) 2. Chemistry – A European Journal 2019, 25 (22) , 5648-5651. https://doi.org/10.1002/chem.201806108
  87. Qiong Liu, Cong Hu, Xin Su, Maierhaba Abudoureheman, Shilie Pan, Zhihua Yang. LiGeBO 4 : a nonlinear optical material with a balance between deep-ultraviolet cut-off edge and large SHG response induced by hand-in-hand tetrahedra. Inorganic Chemistry Frontiers 2019, 6 (4) , 914-919. https://doi.org/10.1039/C8QI01377B
  88. Shuaishuai Hu, Shuwei Li, Zhi Su. RbB 11 O 16 (OH) 2 : First Hydroxyl Rubidium Borate with the B‐O 2D Layer Featuring Large Birefringence in the Rb‐B‐O‐H System. ChemistrySelect 2019, 4 (12) , 3446-3449. https://doi.org/10.1002/slct.201900691
  89. Wenqiang Chen, Qun Jing, Qiaoqiao Zhang, Ming-Hsien Lee, Xuefang Lu, Ping Wei, Zhaohui Chen. A New Cadmium-Based Pb 2 Cd 3 (PO 4 ) 2 (P 2 O 7 ) with Two Types of Isolated P-O Groups. European Journal of Inorganic Chemistry 2019, 2019 (9) , 1273-1278. https://doi.org/10.1002/ejic.201900002
  90. Pratik Das, Nimai Pathak, Sumanta Mukherjee, Muhammed Shafeeq, Smruti Dash, Ramakant M. Kadam. Investigating Cationic Distribution, Defect Structure and Phosphor Characteristics of Na 2 Sm 2 Ca 6 (PO 4 ) 6 F 2. ChemistrySelect 2019, 4 (9) , 2766-2773. https://doi.org/10.1002/slct.201803695
  91. Jianian Cheng, Binghua Lei, Chen Zhou, Shilie Pan, Zhihua Yang. Adjustable optical nonlinearity in d 10 cations containing chalcogenides via dp hybridization interaction. Dalton Transactions 2019, 48 (8) , 2592-2597. https://doi.org/10.1039/C8DT04889D
  92. Naizheng Wang, Fei Liang, Yi Yang, Shengzi Zhang, Zheshuai Lin. A new ultraviolet transparent hydra-cyanurate K 2 (C 3 N 3 O 3 H) with strong optical anisotropy from delocalized π-bonds. Dalton Transactions 2019, 48 (7) , 2271-2274. https://doi.org/10.1039/C8DT05018J
  93. Ming Wen, Hongping Wu, Shichao Cheng, Jun Sun, Zhihua Yang, Xiaohong Wu, Shilie Pan. Experimental characterization and first principles calculations of linear and nonlinear optical properties of two orthophosphates A 3 Al 2 (PO 4 ) 3 (A = Rb, K). Inorganic Chemistry Frontiers 2019, 6 (2) , 504-510. https://doi.org/10.1039/C8QI01249K
  94. Qiaoqiao Zhang, Hahaer Mushahali, Haiming Duan, Ming-Hsien Lee, Qun Jing. The linear and nonlinear optical response of CsGeX3 (X=Cl, Br, and I): The finite field and first-principles investigation. Optik 2019, 179 , 89-98. https://doi.org/10.1016/j.ijleo.2018.10.159
  95. Xueyan Zhang, Shichao Cheng, Ming Wen, Hongyi Li, Jun Zhang. Two new mixed metal borates with the large birefringence in borates system confirmed by a disordered crystal optical calculation method. Journal of Alloys and Compounds 2019, 771 , 595-601. https://doi.org/10.1016/j.jallcom.2018.08.266
  96. Guohong Zou, Zhien Lin, Hongmei Zeng, Hongil Jo, Seong-Ji Lim, Tae-Soo You, Kang Min Ok. Cs 3 VO(O 2 ) 2 CO 3 : an exceptionally thermostable carbonatoperoxovanadate with an extremely large second-harmonic generation response. Chemical Science 2018, 9 (48) , 8957-8961. https://doi.org/10.1039/C8SC03672A
  97. Guopeng Han, Ying Wang, Bingbing Zhang, Shilie Pan. Fluorooxoborates: Ushering in a New Era of Deep Ultraviolet Nonlinear Optical Materials. Chemistry - A European Journal 2018, 24 (67) , 17638-17650. https://doi.org/10.1002/chem.201802787
  98. Yanqiang Li, Sangen Zhao, Pai Shan, Xianfeng Li, Qingran Ding, Shuai Liu, Zhenyue Wu, Sasa Wang, Lina Li, Junhua Luo. Li 8 NaRb 3 (SO 4 ) 6 ·2H 2 O as a new sulfate deep-ultraviolet nonlinear optical material. Journal of Materials Chemistry C 2018, 6 (45) , 12240-12244. https://doi.org/10.1039/C8TC04361B
  99. Chao Wu, Gang Yang, Mark G. Humphrey, Chi Zhang. Recent advances in ultraviolet and deep-ultraviolet second-order nonlinear optical crystals. Coordination Chemistry Reviews 2018, 375 , 459-488. https://doi.org/10.1016/j.ccr.2018.02.017
  100. Xuefang Lu, Ronglan Wu, Qun Jing, Wenqiang Chen, Yunjing Shi, Xiaoyu Dong, Ming-Hsien Lee, Zhaohui Chen. Non-centrosymmetric BaNaP3O9 with a short deep-ultraviolet cutoff edge. Journal of Alloys and Compounds 2018, 764 , 170-176. https://doi.org/10.1016/j.jallcom.2018.06.066
  101. Tuohetijiang Baiheti, Hao Li, Zhihua Yang, Shujuan Han, Ying Wang, Shilie Pan. Two noncentrosymmetric polyphosphates featuring infinite one-dimensional (PO3)∞ chain, LiMP2O6 (M = Rb, Cs): Synthesis, structure and optical properties. Journal of Solid State Chemistry 2018, 266 , 150-154. https://doi.org/10.1016/j.jssc.2018.07.015
  102. Qiaoqiao Zhang, Qun Jing, Haiming Duan, Haibin Cao. The relationship between covalent bonds and the optical response in a nonpolar family ATeMoO 6 (A=Mg, Zn, Cd): A Berry-phase investigation. Journal of Solid State Chemistry 2018, 264 , 22-28. https://doi.org/10.1016/j.jssc.2018.04.031
  103. Mei-Si Zhang, Li-Xian Chang, Li Wang, Mehriban Hojahmat, Maierhaba Abudoureheman. Synthesis, structure and electronic structure calculation of a new perovskite-type phosphate fluoride K 2 BaPO 4 F. Inorganic Chemistry Communications 2018, 93 , 110-114. https://doi.org/10.1016/j.inoche.2018.05.013
  104. Zhiqing Xie, Xin Su, Hanqin Ding, Hongyi Li. Crystal structures and theoretical studies of polyphosphate LiZnP3O9 for nonlinear optical applications. Journal of Solid State Chemistry 2018, 262 , 313-319. https://doi.org/10.1016/j.jssc.2018.03.032
  105. Seung-Jin Oh, Seong-Ji Lim, Tae-Soo You, Kang Min Ok. From a Metastable Layer to a Stable Ring: A Kinetic Study for Transformation Reactions of Li 2 Mo 3 TeO 12 to Polyoxometalates. Chemistry - A European Journal 2018, 24 (26) , 6712-6716. https://doi.org/10.1002/chem.201704755
  106. Yi Yang, Pifu Gong, Siyang Luo, Qian Huang, Zheshuai Lin. Synthesis, crystal structure and characterizations of a new diphosphate Rb2CaP2O7. Journal of Alloys and Compounds 2018, 744 , 370-374. https://doi.org/10.1016/j.jallcom.2018.02.113
  107. Xiyue Cheng, Myung-Hwan Whangbo, Guo-Cong Guo, Maochun Hong, Shuiquan Deng. The Large Second-Harmonic Generation of LiCs 2 PO 4 is caused by the Metal-Cation-Centered Groups. Angewandte Chemie 2018, 130 (15) , 3997-4001. https://doi.org/10.1002/ange.201711465
  108. Xiyue Cheng, Myung-Hwan Whangbo, Guo-Cong Guo, Maochun Hong, Shuiquan Deng. The Large Second-Harmonic Generation of LiCs 2 PO 4 is caused by the Metal-Cation-Centered Groups. Angewandte Chemie International Edition 2018, 57 (15) , 3933-3937. https://doi.org/10.1002/anie.201711465
  109. Ying Wang, Bingbing Zhang, Zhihua Yang, Shilie Pan. Cation-Tuned Synthesis of Fluorooxoborates: Towards Optimal Deep-Ultraviolet Nonlinear Optical Materials. Angewandte Chemie 2018, 130 (8) , 2172-2176. https://doi.org/10.1002/ange.201712168
  110. Ying Wang, Bingbing Zhang, Zhihua Yang, Shilie Pan. Cation-Tuned Synthesis of Fluorooxoborates: Towards Optimal Deep-Ultraviolet Nonlinear Optical Materials. Angewandte Chemie International Edition 2018, 57 (8) , 2150-2154. https://doi.org/10.1002/anie.201712168
  111. Chen Xue, Yang Zou, Shao-Xian Liu, Xiao-Ming Ren, Zheng-Fang Tian. Two different types of channels exhibiting distinct proton transport behavior in an open-framework aluminophosphate. Journal of Solid State Chemistry 2018, 258 , 695-701. https://doi.org/10.1016/j.jssc.2017.11.041
  112. Qian Wang, Chensheng Lin, Guohong Zou, Mengjiao Liu, Daojiang Gao, Jian Bi, Ling Huang. K2[B3O3(OH)5]: A new deep-UV nonlinear optical crystal with isolated [B3O3(OH)5]2- anionic groups. Journal of Alloys and Compounds 2018, 735 , 677-683. https://doi.org/10.1016/j.jallcom.2017.11.174
  113. Jun-Ling Song, Tian-Shuo Guo, Zhong-Yu Shi, Yu-Zhuo Wang, Jian-Qiu Cui, Jian-Han Zhang, Chi Zhang. Syntheses, Crystal Structures and Luminescent Properties of Two New Heterometallic Phosphates: Sn 2 Ge(PO 4 ) 2 (OH) 2 and Sn 2 Mn(PO 4 ) 2. ChemistrySelect 2018, 3 (4) , 1019-1023. https://doi.org/10.1002/slct.201702844
  114. Ailijiang Abudurusuli, Kui Wu, Shilie Pan. Four new quaternary chalcogenides A 2 Ba 7 Sn 4 Q 16 (A = Li, Na; Q = S, Se): syntheses, crystal structures determination, nonlinear optical performances investigation. New Journal of Chemistry 2018, 42 (5) , 3350-3355. https://doi.org/10.1039/C7NJ04288D
  115. Ming Wen, Cong Hu, Zhihua Yang, Xiaohong Wu, Shilie Pan. K 2 TeP 2 O 8 : a new telluro-phosphate with a pentagonal Te–P–O layer structure. Dalton Transactions 2018, 47 (28) , 9453-9458. https://doi.org/10.1039/C8DT01576G
  116. Sangen Zhao, Yi Yang, Yaoguo Shen, Xiaodong Wang, Qingran Ding, Xianfeng Li, Yanqiang Li, Lina Li, Zheshuai Lin, Junhua Luo. A beryllium-free deep-UV nonlinear optical material CsNaMgP 2 O 7 with honeycomb-like topological layers. Journal of Materials Chemistry C 2018, 6 (15) , 3910-3916. https://doi.org/10.1039/C8TC00415C
  117. Wenyao Zhang, Qun Jing, Yuan Fang, Zhaohui Chen. Synthesis, Structure, and Properties of Nonlinear Optical Crystal Na 2 SiF 6. Zeitschrift für anorganische und allgemeine Chemie 2017, 643 (22) , 1739-1743. https://doi.org/10.1002/zaac.201700322
  118. Yuan Fang, Zhaohui Chen, Yunjing Shi, Wenyao Zhang, Xiaoyu Dong. Li1.52Na4.48Cd8(PO4)2(P2O7)4: A new mixed-anion diphosphate containing four types of dimensions groups. Inorganic Chemistry Communications 2017, 86 , 253-257. https://doi.org/10.1016/j.inoche.2017.09.007
  119. Guopeng Han, Ying Wang, Xin Su, Zhihua Yang, Shilie Pan. Growth, Properties, and Theoretical Analysis of M2LiVO4 (M = Rb, Cs) Crystals: Two Potential Mid-Infrared Nonlinear Optical Materials. Scientific Reports 2017, 7 (1) https://doi.org/10.1038/s41598-017-02117-0
  120. Xuefei Wang, Ying Wang, Bingbing Zhang, Fangfang Zhang, Zhihua Yang, Shilie Pan. CsB 4 O 6 F: A Congruent-Melting Deep-Ultraviolet Nonlinear Optical Material by Combining Superior Functional Units. Angewandte Chemie 2017, 129 (45) , 14307-14311. https://doi.org/10.1002/ange.201708231
  121. Xuefei Wang, Ying Wang, Bingbing Zhang, Fangfang Zhang, Zhihua Yang, Shilie Pan. CsB 4 O 6 F: A Congruent-Melting Deep-Ultraviolet Nonlinear Optical Material by Combining Superior Functional Units. Angewandte Chemie International Edition 2017, 56 (45) , 14119-14123. https://doi.org/10.1002/anie.201708231
  122. Ailijiang Abudurusuli, Hanqin Ding, Kui Wu. Synthesis and characterization of two lead-containing metal chalcogenides: Ba5Pb2Sn3S13 and Ba6PbSn3Se13. Journal of Solid State Chemistry 2017, 255 , 133-138. https://doi.org/10.1016/j.jssc.2017.08.019
  123. S. K. Mishra, R. S. Ningthoujam, R. Mittal, R. K. Vatsa, M. Zbiri, K. Shitaljit Sharma, B. P. Singh, P. U. Sastry, T. Hansen, H. Schober, S. L. Chaplot. Neutron diffraction reveals the existence of confined water in triangular and hexagonal channels of modified YPO4 at elevated temperatures. Physical Review Materials 2017, 1 (4) https://doi.org/10.1103/PhysRevMaterials.1.046002
  124. Tong-Ying Chang, Chun-Li Hu, Dong Yan, Jiang-Gao Mao. (H 3 O)Ca 2 Zn 3.5 (PO 4 ) 4 and Ba 2 Cd 3 (PO 4 ) 2 (HPO 4 ) 2 : Syntheses, crystal structures and characterizations of two mixed metal phosphates. Journal of Solid State Chemistry 2017, 251 , 19-25. https://doi.org/10.1016/j.jssc.2017.04.008
  125. Zhi Li, Qiong Liu, Ying Wang, Toshiaki Iitaka, Haibin Su, Takami Tohyama, Zhihua Yang, Shilie Pan. Second-harmonic generation in noncentrosymmetric phosphates. Physical Review B 2017, 96 (3) https://doi.org/10.1103/PhysRevB.96.035205
  126. Kui Wu, Shilie Pan. Li2HgMS4 (M = Si, Ge, Sn): New Quaternary Diamond-Like Semiconductors for Infrared Laser Frequency Conversion. Crystals 2017, 7 (4) , 107. https://doi.org/10.3390/cryst7040107
  127. Bing-Hua Lei, Zhihua Yang, Shilie Pan. Enhancing optical anisotropy of crystals by optimizing bonding electron distribution in anionic groups. Chemical Communications 2017, 53 (19) , 2818-2821. https://doi.org/10.1039/C6CC09986F
  128. Dongdong Xu, Fangfang Zhang, Yanzhou Sun, Zhihua Yang, Binghua Lei, Lili Liu, Shilie Pan. LiRb 2 LaB 2 O 6 : a new rare-earth borate with a MOF-5-like topological structure and a short UV cut-off edge. Dalton Transactions 2017, 46 (1) , 193-199. https://doi.org/10.1039/C6DT04243K
  129. Ruru Ma, Yun Yang, Shilie Pan, Yanzhou Sun, Zhihua Yang. Structure comparison and optical properties of Na 7 Mg 4.5 (P 2 O 7 ) 4 : a sodium magnesium phosphate with isolated P 2 O 7 units. New Journal of Chemistry 2017, 41 (9) , 3399-3404. https://doi.org/10.1039/C6NJ03986C
  130. Yanzhou Sun, Zhihua Yang, Dianwei Hou, Shilie Pan. Theoretical investigation on the balance between large band gap and strong SHG response in BMO 4 (M = P and As) crystals. RSC Advances 2017, 7 (5) , 2804-2809. https://doi.org/10.1039/C6RA26568E
  131. Lin Li, Ying Wang, Bing-Hua Lei, Shujuan Han, Zhihua Yang, Hongyi Li, Shilie Pan. LiRb 2 PO 4 : a new deep-ultraviolet nonlinear optical phosphate with a large SHG response. Journal of Materials Chemistry C 2017, 5 (2) , 269-274. https://doi.org/10.1039/C6TC04565K
  132. Xiangyu Zhang, Hongping Wu, Qiong Liu, Xiaoyu Dong, Yunlei Chen, Zhihua Yang, Xiao-Dong Wen, Shilie Pan. Application of the dimensional reduction formalism to Pb 9−x Ba x [Li 2 (P 2 O 7 ) 2 (P 4 O 13 ) 2 ] (x = 0, 2, 6, 7): a series of phosphates with two types of isolated polyphosphate groups. Dalton Transactions 2017, 46 (14) , 4678-4684. https://doi.org/10.1039/C7DT00509A
  133. Chao Wu, Longhua Li, Gang Yang, Junling Song, Bing Yan, Mark G. Humphrey, Long Zhang, Jianda Shao, Chi Zhang. Low-temperature-flux syntheses of ultraviolet-transparent borophosphates Na 4 MB 2 P 3 O 13 (M = Rb, Cs) exhibiting a second-harmonic generation response. Dalton Transactions 2017, 46 (37) , 12605-12611. https://doi.org/10.1039/C7DT02649H
  134. Xiaobo Pan, Ming Wen, Guijie He, Hongyi Li, Dianzeng Jia. Syntheses, structures and properties of metal phosphates Pb 2 Mg(PO 4 ) 2 , Pb 4 Zn 8 (PO 4 ) 8 and α-BaZn 2 (PO 4 ) 2. Dalton Transactions 2017, 46 (46) , 16034-16040. https://doi.org/10.1039/C7DT03055J
  135. Chao Wu, Longhua Li, Junling Song, Gang Yang, Mark G. Humphrey, Chi Zhang. Solvent-controlled syntheses of mixed-alkali-metal borates exhibiting UV nonlinear optical properties. Inorganic Chemistry Frontiers 2017, 4 (4) , 692-700. https://doi.org/10.1039/C7QI00001D
  136. Leyan Nian, Junben Huang, Kui Wu, Zhi Su, Zhihua Yang, Shilie Pan. BaCu 2 M IV Q 4 (M IV = Si, Ge, and Sn; Q = S, Se): synthesis, crystal structures, optical performances and theoretical calculations. RSC Advances 2017, 7 (47) , 29378-29385. https://doi.org/10.1039/C7RA05022D
  137. Rui-Huan Duan, Peng-Fei Liu, Hua Lin, Y. J. Zheng, Ju-Song Yu, Xin-Tao Wu, Shang-Xiong Huang-Fu, Ling Chen. Ba 6 Li 2 CdSn 4 S 16 : lithium substitution simultaneously enhances band gap and SHG intensity. Journal of Materials Chemistry C 2017, 5 (28) , 7067-7074. https://doi.org/10.1039/C7TC01811H
  138. Bingqing Zhao, Yi Yang, Sangen Zhao, Yaoguo Shen, Xianfeng Li, Lina Li, Chengmin Ji, Zheshuai Lin, Junhua Luo. A new phase-matchable nonlinear optical silicate: Rb 2 ZnSi 3 O 8. Journal of Materials Chemistry C 2017, 5 (42) , 11025-11029. https://doi.org/10.1039/C7TC03000B
  139. Wei-Long Zhang, Zhen-Gang Guo, Yun-Long Yu, Lin-Qing Jiang, Wen-Dan Cheng. Syntheses and Characterizations of Three Bismuth(III)-Containing Mixed-Metal Phosphates:Ba 2 Bi 2 M II (PO 4 ) 4 (M= Mn, Ni, Cu). ChemistrySelect 2016, 1 (16) , 5347-5352. https://doi.org/10.1002/slct.201601034
  140. Yuqiao Zhou, Liling Cao, Chensheng Lin, Min Luo, Tao Yan, Ning Ye, Wendan Cheng. AMgPO 4 ·6H 2 O (A = Rb, Cs): strong SHG responses originated from orderly PO 4 groups. Journal of Materials Chemistry C 2016, 4 (39) , 9219-9226. https://doi.org/10.1039/C6TC03295H
  141. Maierhaba Abudoureheman, Shujuan Han, Bing-Hua Lei, Zhihua Yang, Xifa Long, Shilie Pan. KPb 2 (PO 3 ) 5 : a novel nonlinear optical lead polyphosphate with a short deep-UV cutoff edge. Journal of Materials Chemistry C 2016, 4 (45) , 10630-10637. https://doi.org/10.1039/C6TC03424A

Pair your accounts.

Export articles to Mendeley

Get article recommendations from ACS based on references in your Mendeley library.

Pair your accounts.

Export articles to Mendeley

Get article recommendations from ACS based on references in your Mendeley library.

You’ve supercharged your research process with ACS and Mendeley!

STEP 1:
Click to create an ACS ID

Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

OOPS

You have to login with your ACS ID befor you can login with your Mendeley account.

MENDELEY PAIRING EXPIRED
Your Mendeley pairing has expired. Please reconnect

This website uses cookies to improve your user experience. By continuing to use the site, you are accepting our use of cookies. Read the ACS privacy policy.

CONTINUE