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Room-Temperature Activation of Hydrogen by Semi-immobilized Frustrated Lewis Pairs in Microporous Polymer Networks

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    Room-Temperature Activation of Hydrogen by Semi-immobilized Frustrated Lewis Pairs in Microporous Polymer Networks
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    † Department of Chemistry, Functional Materials, Technische Universität Berlin, Hardenbergstraße 40, 10623 Berlin, Germany
    ‡ Department of Chemistry, Organic Chemistry/Sustainable Synthetic Methods, Technische Universität Berlin, Straße des 17. Juni 115, 10623 Berlin, Germany
    *[email protected]
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    Cite this: J. Am. Chem. Soc. 2017, 139, 10, 3615–3618
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    https://doi.org/10.1021/jacs.6b13147
    Published March 1, 2017
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    Abstract

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    Porous polymer networks based on sterically encumbered triphenylphosphine motifs, mimicking the basic sites employed in frustrated Lewis pair (FLP) chemistry, were synthesized via Yamamoto polymerization and their interactions with the strong Lewis acid B(C6F5)3 probed. The combinations yield semi-immobilized FLPs, which are able to cleave dihydrogen heterolytically at ambient temperature and low hydrogen pressure.

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    The Supporting Information is available free of charge on the ACS Publications website at DOI: 10.1021/jacs.6b13147.

    • Experimental details on synthesis of monomers and polymers and hydrogen activation; 13C NMR of polymers and molecular model compounds; fluorescence spectra and TGA of the polymers, including Figures S1–S4 (PDF)

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    Cite this: J. Am. Chem. Soc. 2017, 139, 10, 3615–3618
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