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Programmed Coassembly of One-Dimensional Binary Superstructures by Liquid Soft Confinement

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Key Laboratory of Green Printing, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, People’s Republic of China
Beijing Engineering Research Center of Nanomaterials for Green Printing Technology, Beijing National Laboratory for Molecular Sciences, Beijing 100190, People’s Republic of China
§ Department of Chemistry, University of Chinese Academy of Sciences, Beijing 100049, People’s Republic of China
State Key Laboratory of Nonlinear Mechanics, Institute of Mechanics, Chinese Academy of Sciences, Beijing 100190, People’s Republic of China
Research Center for Green Printing Nanophotonic Materials, Suzhou University of Science and Technology, Suzhou 215009, People’s Republic of China
Cite this: J. Am. Chem. Soc. 2018, 140, 1, 18–21
Publication Date (Web):December 19, 2017
https://doi.org/10.1021/jacs.7b09738
Copyright © 2017 American Chemical Society
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Supporting Info (7)»

Abstract

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Precise control of particles co-assembly has attracted great attention for fabricating intricate structures and functional materials. However, achieving precise co-assembly of one-dimensional (1D) binary superstructures remains challenging due to the constrained thermodynamic stability and lack of general strategies to control the 1D ordered arrangement of mixed particles. Here, we propose a facile strategy to achieve programmed co-assembly of 1D binary superstructures by liquid soft confinement without particle modification or external field. It reveals that binary particles undergo stepwise confinement and programmed co-assembly in the gradually shrinking and spatially tunable liquid soft confinement. Through tuning the liquid confined space and particles composition, diverse 1D binary superstructures with precisely controlled periodicity, orientation and symmetry are achieved, which shows generality for various particles of different sizes and materials. This work provides a promising route to refined patterning and manufacturing complex materials.

Supporting Information

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The Supporting Information is available free of charge on the ACS Publications website at DOI: 10.1021/jacs.7b09738.

  • Materials and methods, supplementary Discussion and Figures  (PDF)

  • Video S1: Simulation of the programmed co-assembly process from binary particles (AVI)

  • Video S2: Formation of grafting 1D binary superstructures (AVI)

  • Video S3: Formation of segmented 1D binary superstructures (AVI)

  • Video S4: 1D assembly of large particles in the liquid confinement (AVI)

  • Video S5: Elongation of the assembly region with controlled orientation (AVI)

  • Video S6: Formation of asymmetric 1D binary superstructures (AVI)

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This article is cited by 17 publications.

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