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Solubility of Flurbiprofen in Supercritical Carbon Dioxide

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Instituto de Biologia Experimental e Tecnológica, Aptd. 12-2780 Oeiras, Portugal, and Dep. de Engenharia Química, FCT, Universidade de Coimbra, Pólo IIPinhal de Marrocos, 3030-290 Coimbra, Portugal
Cite this: J. Chem. Eng. Data 2004, 49, 3, 449–452
Publication Date (Web):March 19, 2004
https://doi.org/10.1021/je034099b
Copyright © 2004 American Chemical Society
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Abstract

Equilibrium solubility of flurbiprofen, a nonsteroidal antiinflammatory agent, in supercritical carbon dioxide was measured by a static analytical method in the pressure range from (8.0 to 25.0) MPa, at temperatures of (303.0, 313.0, and 323.0) K. The cosolvent effect of ethanol in the solubility of the bioactive compound in supercritical carbon dioxide was investigated at 18 MPa and 313 K. The results obtained have a potential application in supercritical processes for this drug. Experimental solubility data were correlated with an empirical density-based Chrastil model.

†

 Instituto de Biologia Experimental e Tecnológica.

‡

 Universidade de Coimbra.

*

 To whom correspondence should be addressed. E-mail:  [email protected] itqb.unl.pt. Fax:  +351 21 4421161.

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