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Static Relative Dielectric Permittivities of Ionic Liquids at 25 °C

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† Department of Physical Chemistry II, Faculty of Chemistry and Biochemistry, Ruhr-University Bochum, D-44780 Bochum, Germany
‡ Department of Chemical Engineering, Laboratory of Analytical Chemistry, Åbo Akademi University, Biskopsgatan 8, Turku/Åbo Finland
*E-mail: [email protected]
Cite this: J. Chem. Eng. Data 2011, 56, 4, 1494–1499
Publication Date (Web):February 16, 2011
https://doi.org/10.1021/je101184s
Copyright © 2011 American Chemical Society
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Abstract

For understanding solvation by ionic liquids, it is mandatory to characterize their static relative dielectric permittivities ε (“static dielectric constants”). Exploiting the definition of ε in terms of the zero-frequency limit of the frequency-dependent dielectric dispersion curve, the static dielectric constant of an electrically conducting liquid can be extrapolated from dielectric relaxation spectra in the microwave regime. On the basis of this method, we report dielectric constants of 42 ionic liquids at 25 °C.

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