ACS Publications. Most Trusted. Most Cited. Most Read
My Activity

Convenient Preparation of trans-Arylalkenes via Palladium(II)-Catalyzed Isomerization of cis-Arylalkenes

View Author Information
University Chemical Laboratory, Lensfield Road, Cambridge CB2 1EW, U.K. [email protected]
Cite this: J. Org. Chem. 2002, 67, 13, 4627–4629
Publication Date (Web):June 7, 2002
Copyright © 2002 American Chemical Society

    Article Views





    Read OnlinePDF (38 KB)
    Supporting Info (1)»


    Abstract Image

    A convenient method for the isomerization of cis-arylalkenes to their trans isomers using a palladium(II) catalyst is described. The reaction conditions are mild and general across a range of arylalkenes. The synthesis of a trans-resveratrol derivative from a mixture of alkene isomers was also completed.


     To whom correspondence should be addressed. Fax:  +44 (01223) 336362.

    Supporting Information Available

    Jump To

    Experimental procedures and spectral data for all compounds are provided. This material is available free of charge via the Internet at

    Terms & Conditions

    Most electronic Supporting Information files are available without a subscription to ACS Web Editions. Such files may be downloaded by article for research use (if there is a public use license linked to the relevant article, that license may permit other uses). Permission may be obtained from ACS for other uses through requests via the RightsLink permission system:

    Cited By

    This article is cited by 142 publications.

    1. Wei Wang, Shuying He, Yuqing Zhong, Jianhui Chen, Cheng Cai, Yanshu Luo, Yuanzhi Xia. Cobalt-Catalyzed Z to E Geometrical Isomerization of 1,3-Dienes. The Journal of Organic Chemistry 2022, 87 (7) , 4712-4723.
    2. Biswajit Sen, Saikat Roy, Sujay Garai, Sayan Roy, Anakuthil Anoop, Saumen Hajra. Stereochemistry of the Benzylidene γ-Butyrolactone Dictates the Reductive Heck Cyclization Mode in the Asymmetric Synthesis of Aryltetralin Lignans: A Detailed Experimental and Theoretical Study. The Journal of Organic Chemistry 2022, 87 (6) , 3910-3921.
    3. Tomáš Neveselý, Max Wienhold, John J. Molloy, Ryan Gilmour. Advances in the E → Z Isomerization of Alkenes Using Small Molecule Photocatalysts. Chemical Reviews 2022, 122 (2) , 2650-2694.
    4. Yusei Nakashima, Junki Matsumoto, Takashi Nishikata. Iron-Catalyzed Stereoconvergent Tertiary Alkylation of (E)- and (Z)-Mixed Internal Olefins with Functionalized Tertiary Alkyl Halides. ACS Catalysis 2021, 11 (18) , 11526-11531.
    5. Jonathan H. George. Biomimetic Dearomatization Strategies in the Total Synthesis of Meroterpenoid Natural Products. Accounts of Chemical Research 2021, 54 (8) , 1843-1855.
    6. Rei Matsuura, Malkanthi K. Karunananda, Mingyu Liu, Nhi Nguyen, Donna G. Blackmond, Keary M. Engle. Mechanistic Studies of Pd(II)-Catalyzed E/Z Isomerization of Unactivated Alkenes: Evidence for a Monometallic Nucleopalladation Pathway. ACS Catalysis 2021, 11 (7) , 4239-4246.
    7. Jessica R. Lamb, Aran K. Hubbell, Samantha N. MacMillan, Geoffrey W. Coates. Carbonylative, Catalytic Deoxygenation of 2,3-Disubstituted Epoxides with Inversion of Stereochemistry: An Alternative Alkene Isomerization Method. Journal of the American Chemical Society 2020, 142 (17) , 8029-8035.
    8. Hongmei Liu, Man Xu, Cheng Cai, Jianhui Chen, Yugui Gu, Yuanzhi Xia. Cobalt-Catalyzed Z to E Isomerization of Alkenes: An Approach to (E)-β-Substituted Styrenes. Organic Letters 2020, 22 (3) , 1193-1198.
    9. Zhen Liu, Xiaohan Li, Tian Zeng, Keary M. Engle. Directed, Palladium(II)-Catalyzed Enantioselective anti-Carboboration of Alkenyl Carbonyl Compounds. ACS Catalysis 2019, 9 (4) , 3260-3265.
    10. Chuan-Qi Zhao, Yue-Gang Chen, Hui Qiu, Lei Wei, Ping Fang, Tian-Sheng Mei. Water as a Hydrogenating Agent: Stereodivergent Pd-Catalyzed Semihydrogenation of Alkynes. Organic Letters 2019, 21 (5) , 1412-1416.
    11. Megan K. Armstrong, Madison B. Goodstein, Gojko Lalic. Diastereodivergent Reductive Cross Coupling of Alkynes through Tandem Catalysis: Z- and E-Selective Hydroarylation of Terminal Alkynes. Journal of the American Chemical Society 2018, 140 (32) , 10233-10241.
    12. Abigail Feceu, Lauren E. Sangster, David B. C. Martin. Unexpected Alkene Isomerization during Iterative Cross-Coupling To Form Hindered, Electron-Deficient Trienes. Organic Letters 2018, 20 (11) , 3151-3155.
    13. Chao Zheng, Wan-Min Cheng, Hong-Lian Li, Ri-Song Na, Rui Shang. Cis-Selective Decarboxylative Alkenylation of Aliphatic Carboxylic Acids with Vinyl Arenes Enabled by Photoredox/Palladium/Uphill Triple Catalysis. Organic Letters 2018, 20 (9) , 2559-2563.
    14. Mingyu Liu, Pusu Yang, Malkanthi K. Karunananda, Yanyan Wang, Peng Liu, Keary M. Engle. C(alkenyl)–H Activation via Six-Membered Palladacycles: Catalytic 1,3-Diene Synthesis. Journal of the American Chemical Society 2018, 140 (17) , 5805-5813.
    15. Qun Zhao, Vincent Tognetti, Laurent Joubert, Tatiana Besset, Xavier Pannecoucke, Jean-Philippe Bouillon, and Thomas Poisson . Palladium-Catalyzed Synthesis of 3-Trifluoromethyl-Substituted 1,3-Butadienes by Means of Directed C–H Bond Functionalization. Organic Letters 2017, 19 (8) , 2106-2109.
    16. Jia Yuan, Lizhao Zhu, Jianying Zhang, Jianfeng Li, and Chunming Cui . Sequential Addition of Phosphine to Alkynes for the Selective Synthesis of 1,2-Diphosphinoethanes under Catalysis. Well-Defined NHC-Copper Phosphides vs in Situ CuCl2/NHC Catalyst. Organometallics 2017, 36 (2) , 455-459.
    17. Alexander W. Schuppe and Timothy R. Newhouse . Assembly of the Limonoid Architecture by a Divergent Approach: Total Synthesis of (±)-Andirolide N via (±)-8α-Hydroxycarapin. Journal of the American Chemical Society 2017, 139 (2) , 631-634.
    18. Michael Grigalunas, Olaf Wiest, and Paul Helquist . Single-Flask Multicomponent Synthesis of Highly Substituted α-Pyrones via a Sequential Enolate Arylation and Alkenylation Strategy. Organic Letters 2016, 18 (21) , 5724-5727.
    19. Christine M. Le, Theresa Sperger, Rui Fu, Xiao Hou, Yong Hwan Lim, Franziska Schoenebeck, and Mark Lautens . Stereoselective Synthesis of Methylene Oxindoles via Palladium(II)-Catalyzed Intramolecular Cross-Coupling of Carbamoyl Chlorides. Journal of the American Chemical Society 2016, 138 (43) , 14441-14448.
    20. Edward Richmond and Joseph Moran . Ligand Control of E/Z Selectivity in Nickel-Catalyzed Transfer Hydrogenative Alkyne Semireduction. The Journal of Organic Chemistry 2015, 80 (13) , 6922-6929.
    21. Mohammad Hassam, Abu Taher, Gareth E. Arnott, Ivan R. Green, and Willem A. L. van Otterlo . Isomerization of Allylbenzenes. Chemical Reviews 2015, 115 (11) , 5462-5569.
    22. Fong-Jiao Hong, Yun-Yee Low, Kam-Weng Chong, Noel F. Thomas, and Toh-Seok Kam . Biomimetic Oxidative Dimerization of Anodically Generated Stilbene Radical Cations: Effect of Aromatic Substitution on Product Distribution and Reaction Pathways. The Journal of Organic Chemistry 2014, 79 (10) , 4528-4543.
    23. Spring Melody M. Knapp, Sarah E. Shaner, Daniel Kim, Dimitar Y. Shopov, Jennifer A. Tendler, David M. Pudalov, and Anthony R. Chianese . Mechanistic Studies of Alkene Isomerization Catalyzed by CCC-Pincer Complexes of Iridium. Organometallics 2014, 33 (2) , 473-484.
    24. Govindra Singh, Rakesh Kumar, Jorge Swett, and Barbara Zajc . Modular Synthesis of N-Vinyl Benzotriazoles. Organic Letters 2013, 15 (16) , 4086-4089.
    25. David J. Del Valle and Michael J. Krische . Total Synthesis of (+)-Trienomycins A and F via C–C Bond-Forming Hydrogenation and Transfer Hydrogenation. Journal of the American Chemical Society 2013, 135 (30) , 10986-10989.
    26. Gary A. Molander, Thiago Barcellos, and Kaitlin M. Traister . Pd-Catalyzed Cross-Coupling of Potassium Alkenyltrifluoroborates with 2-Chloroacetates and 2-Chloroacetamides. Organic Letters 2013, 15 (13) , 3342-3345.
    27. Yilin Liu, Ziping Cao, and Haifeng Du . Asymmetric Allylic Alkylation of Pyrroles and 4,7-Dihydroindoles with Alkene–Phosphine Ligands. The Journal of Organic Chemistry 2012, 77 (9) , 4479-4483.
    28. Daniel A. Offermann, John E. McKendrick, Jimmy J. P. Sejberg, Bingli Mo, Mary D. Holdom, Birgit A. Helm, Robin J. Leatherbarrow, Andrew J. Beavil, Brian J. Sutton, and Alan C. Spivey . Synthesis and Incorporation into Cyclic Peptides of Tolan Amino Acids and Their Hydrogenated Congeners: Construction of an Array of A–B-loop Mimetics of the Cε3 Domain of Human IgE. The Journal of Organic Chemistry 2012, 77 (7) , 3197-3214.
    29. Iljung Lee, Yearn Seong Choe, Joon Young Choi, Kyung-Han Lee, and Byung-Tae Kim . Synthesis and Evaluation of 18F-Labeled Styryltriazole and Resveratrol Derivatives for β-Amyloid Plaque Imaging. Journal of Medicinal Chemistry 2012, 55 (2) , 883-892.
    30. Phil Ho Lee, Dongjin Kang, Subin Choi, and Sunggak Kim . Trifluoromethanesulfonic Acid Catalyzed Isomerization of Kinetic Enol Derivatives to the Thermodynamically Favored Isomers. Organic Letters 2011, 13 (13) , 3470-3473.
    31. Michael Rössle, David J. Del Valle, and Michael J. Krische . Synthesis of the Cytotrienin A Core via Metal Catalyzed C−C Coupling. Organic Letters 2011, 13 (6) , 1482-1485.
    32. Jean Le Bras and Jacques Muzart . Intermolecular Dehydrogenative Heck Reactions. Chemical Reviews 2011, 111 (3) , 1170-1214.
    33. Peng Zhou, Liangbin Huang, Huanfeng Jiang, Azhong Wang, and Xianwei Li . Highly Chemoselective Palladium-Catalyzed Cross-Trimerization between Alkyne and Alkenes Leading to 1,3,5-Trienes or 1,2,4,5-Tetrasubstituted Benzenes with Dioxygen. The Journal of Organic Chemistry 2010, 75 (23) , 8279-8282.
    34. Delphine Gauthier, Anders T. Lindhardt, Esben P. K. Olsen, Jacob Overgaard and Troels Skrydstrup. In Situ Generated Bulky Palladium Hydride Complexes as Catalysts for the Efficient Isomerization of Olefins. Selective Transformation of Terminal Alkenes to 2-Alkenes. Journal of the American Chemical Society 2010, 132 (23) , 7998-8009.
    35. Tao-Shan Jiang, Ri-Yuan Tang, Xing-Guo Zhang, Xin-Hua Li and Jin-Heng Li. Palladium-Catalyzed Intramolecular 5-exo-dig Hydroarylations of N-Arylpropiolamides: Thermodynamics-Controlled Stereoselective Synthesis of 3-Methyleneoxindoles. The Journal of Organic Chemistry 2009, 74 (22) , 8834-8837.
    36. Nobuyoshi Umeda, Koji Hirano, Tetsuya Satoh and Masahiro Miura. Rhodium-Catalyzed Mono- and Divinylation of 1-Phenylpyrazoles and Related Compounds via Regioselective C−H Bond Cleavage. The Journal of Organic Chemistry 2009, 74 (18) , 7094-7099.
    37. Hwan Jung Lim, Craig R. Smith and T. V. RajanBabu. Facile Pd(II)- and Ni(II)-Catalyzed Isomerization of Terminal Alkenes into 2-Alkenes. The Journal of Organic Chemistry 2009, 74 (12) , 4565-4572.
    38. Luciano Canovese, Claudio Santo and Fabiano Visentin. Palladium(0)-Catalyzed Cis−Trans Alkene Isomerizations. Organometallics 2008, 27 (14) , 3577-3581.
    39. S. B. Jennifer Kan and Edward A. Anderson. A Cascade Palladium-Mediated Cross-Coupling/Electrocyclization Approach to the Construction of Fused Bi- and Tricyclic Rings. Organic Letters 2008, 10 (11) , 2323-2326.
    40. In Su Kim,, Guang Ri Dong, and, Young Hoon Jung. Palladium(II)-Catalyzed Isomerization of Olefins with Tributyltin Hydride. The Journal of Organic Chemistry 2007, 72 (14) , 5424-5426.
    41. Mikkel F. Jacobsen,, John E. Moses,, Robert M. Adlington, and, Jack E. Baldwin. The Total Synthesis of Spectinabilin and Its Biomimetic Conversion to SNF4435C and SNF4435D. Organic Letters 2005, 7 (12) , 2473-2476.
    42. Varinder K. Aggarwal,, J. Robin Fulton,, Chris G. Sheldon, and, Javier de Vicente. Generation of Phosphoranes Derived from Phosphites. A New Class of Phosphorus Ylides Leading to High E Selectivity with Semi-stabilizing Groups in Wittig Olefinations. Journal of the American Chemical Society 2003, 125 (20) , 6034-6035.
    43. John E. Moses,, Jack E. Baldwin,, Rodolfo Marquez, and, Robert M. Adlington, , Andrew R. Cowley. Studies on the Biomimetic Synthesis of SNF4435 C and D. Organic Letters 2002, 4 (21) , 3731-3734.
    44. Marco Ballarotto, Bruno Cerra, Andrea Temperini. Multicomponent and Metal‐Free Diels–Alder/Aromatization Approach to the Stereospecific Synthesis of E ‐(Hetero)Stilbenes and Diarylacetylenes. European Journal of Organic Chemistry 2023, 26 (36)
    45. Xiaozheng Dou, Hui Guo, Terin D'Amico, Leah Abdallah, Chitra Subramanian, Bhargav A. Patel, Mark Cohen, John L. Rubinstein, Brian S. J. Blagg. CryoEM Structure with ATP Synthase Enables Late‐Stage Diversification of Cruentaren A. Chemistry – A European Journal 2023, 29 (29)
    46. Si‐Yu Tsai, Yu‐Wen Huang, Chih‐Ming Chou. Carboxylate‐Directed Palladium‐Catalyzed Regioselective Mizoroki‐Heck Alkenylation of γ , δ ‐Unsaturated Carboxylic Acids. Advanced Synthesis & Catalysis 2023, 365 (5) , 699-703.
    47. Liam H. Britt, Zhensheng Zhao, Graham K. Murphy. Hypervalent iodine-mediated oxidative alkene arylation: a thorough analysis. Canadian Journal of Chemistry 2022, 100 (8) , 606-621.
    48. Mingyu Liu, Juntao Sun, Tuğçe G. Erbay, Hui‐Qi Ni, Raúl Martín‐Montero, Peng Liu, Keary M. Engle. Pd II ‐Catalyzed C(alkenyl)−H Activation Facilitated by a Transient Directing Group**. Angewandte Chemie International Edition 2022, 61 (25)
    49. Mingyu Liu, Juntao Sun, Tuğçe G. Erbay, Hui‐Qi Ni, Raúl Martín‐Montero, Peng Liu, Keary M. Engle. Pd II ‐Catalyzed C(alkenyl)−H Activation Facilitated by a Transient Directing Group**. Angewandte Chemie 2022, 134 (25)
    50. Hong-Chao Chen, Yichen Wu, Yang Yu, Peng Wang. Pd-Catalyzed Isomerization of Alkenes. Chinese Journal of Organic Chemistry 2022, 42 (3) , 742.
    51. Shagufta, Irshad Ahmad. An Update on Pharmacological Relevance and Chemical Synthesis of Natural Products and Derivatives with Anti SARS‐CoV‐2 Activity. ChemistrySelect 2021, 6 (42) , 11502-11527.
    52. Ayon Sengupta, Piyali Sarkar, Suvendu Maity, Soumyadip Basu, Prasanta Ghosh, Sonali Rudra, Chhanda Mukhopadhyay. Synthesis of δ,δ‐Diaryl‐α‐cyanoacrylamides and δ,δ‐Diarylallylidiene Malononitriles by Pd(OAc) 2 Catalyzed Mizoroki‐Heck Reaction. ChemistrySelect 2021, 6 (40) , 11047-11053.
    53. Pan Xiao, Xavier Pannecoucke, Jean‐Philippe Bouillon, Samuel Couve‐Bonnaire. Palladium‐Catalysed Oxidative Decarboxylative Cross‐Coupling of Heteroarenes with CF 3 ‐Acrylic Acids. ChemistrySelect 2021, 6 (29) , 7367-7371.
    54. Lu Ran, Hongpeng Li, Ge Chao, Xiaodong Kang, Tian Lei, Wenling Li. Regioselective Biomimetic Synthesis of Dimeric Oxyresveratrol Derivatives. Synlett 2020, 31 (18) , 1809-1812.
    55. Ping Chen, Hao Wu, Yu Li, Yu Tang. Total syntheses of (+)-arisugacins F, G. Tetrahedron Letters 2020, 61 (33) , 152172.
    56. Alex Kelly, Jack B. Hoffman, Oskar Hoff, Johannes C.L. Walker, Simon Werrel, Timothy J. Donohoe. A Heck reaction/photochemical alkene isomerization sequence to prepare functionalized quinolines. Tetrahedron 2020, 76 (35) , 131396.
    57. Shaomin Fu, Bo Liu. Recent progress in the synthesis of limonoids and limonoid-like natural products. Organic Chemistry Frontiers 2020, 7 (14) , 1903-1947.
    58. Yusei Nakashima, Goki Hirata, Tom D. Sheppard, Takashi Nishikata. The Mizoroki‐Heck Reaction with Internal Olefins: Reactivities and Stereoselectivities. Asian Journal of Organic Chemistry 2020, 9 (4) , 480-491.
    59. Keke Meng, Tingyan Li, Chunbing Yu, Cong Shen, Jian Zhang, Guofu Zhong. Geminal group-directed olefinic C-H functionalization via four- to eight-membered exo-metallocycles. Nature Communications 2019, 10 (1)
    60. Liangliang Cai, Faming Kang, Qiang Sun, Wenze Gao, Xin Yu, Honghong Ma, Chunxue Yuan, Wei Xu. The Stereoselective Formation of trans ‐Cumulene through Dehalogenative Homocoupling of Alkenyl gem ‐Dibromides on Cu(110). ChemCatChem 2019, 11 (22) , 5417-5420.
    61. Cong Shen, Xiunan Lu, Jian Zhang, Liyuan Ding, Yaling Sun, Guofu Zhong. Bidentate auxiliary-directed alkenyl C–H allylation via exo -palladacycles: synthesis of branched 1,4-dienes. Chemical Communications 2019, 55 (90) , 13582-13585.
    62. John J. Molloy, Tobias Morack, Ryan Gilmour. Positional and Geometrical Isomerisation of Alkenes: The Pinnacle of Atom Economy. Angewandte Chemie International Edition 2019, 58 (39) , 13654-13664.
    63. John J. Molloy, Tobias Morack, Ryan Gilmour. Positionelle und geometrische Isomerisierung von Alkenen: der Gipfel der Atomökonomie. Angewandte Chemie 2019, 131 (39) , 13789-13800.
    64. Tse‐Lok Ho. Bis(acetonitrile)dichloropalladium( II ). 2019
    65. Chunngai Hui, Fang Chen, Fan Pu, Jing Xu. Innovation in protecting-group-free natural product synthesis. Nature Reviews Chemistry 2019, 3 (2) , 85-107.
    66. Ajoy Kapat, Theresa Sperger, Sinem Guven, Franziska Schoenebeck. E -Olefins through intramolecular radical relocation. Science 2019, 363 (6425) , 391-396.
    67. 智博 邵. Progress on Cis-Trans Isomerization Reactions of Stilbenes. Journal of Organic Chemistry Research 2019, 07 (01) , 11-17.
    68. S. A. Savel’eva, M. V. Leonova, M. R. Baimuratov, Yu. N. Klimochkin. Synthesis and Transformations of Aryl-Substituted Alkenes of the Adamantane Series. Russian Journal of Organic Chemistry 2018, 54 (7) , 996-1002.
    69. Richard C. Larock, Gilson Zeni. Isomerization of Alkenes. 2018, 1-49.
    70. С.А. Савельева, М.В. Леонова, М.Р. Баймуратов, Ю.Н. Климочкин. СИНТЕЗ И ПРЕВРАЩЕНИЯ АРИЛЗАМЕЩЕННЫХ АЛКЕНОВ АДАМАНТАНОВОГО РЯДА, "Журнал органической химии". Журнал органической химии 2018, (7) , 994-1000.
    71. Hiu C. Lam, Henry P. Pepper, Christopher J. Sumby, Jonathan H. George. Biomimetic Total Synthesis of (±)‐Verrubenzospirolactone. Angewandte Chemie 2017, 129 (29) , 8652-8655.
    72. Hiu C. Lam, Henry P. Pepper, Christopher J. Sumby, Jonathan H. George. Biomimetic Total Synthesis of (±)‐Verrubenzospirolactone. Angewandte Chemie International Edition 2017, 56 (29) , 8532-8535.
    73. Hyojung Ahn, Inyoung Son, Jinyong Lee, Hwan Jung Lim. Palladium−Hydride-Catalyzed Regiodivergent Isomerization of 1-Alkenes. Asian Journal of Organic Chemistry 2017, 6 (3) , 335-341.
    74. Tse‐Lok Ho. Bis(acetonitrile)dichloropalladium( II ). 2017
    75. A. V. Smarun, F. Duzhin, M. Petković, D. Vidović. Alkene-assisted cis -to- trans isomerization of non-conjugated polyunsaturated alkenes. Dalton Transactions 2017, 46 (41) , 14244-14250.
    76. Henry P. Pepper, Hiu C. Lam, Jonathan H. George. Biosynthetically-inspired oxidations of capillobenzopyranol. Organic & Biomolecular Chemistry 2017, 15 (22) , 4811-4815.
    77. M. S. R. Murty, Raju Penthala, Sowjanya Polepalli, N. Jain. Synthesis and biological evaluation of novel resveratrol-oxadiazole hybrid heterocycles as potential antiproliferative agents. Medicinal Chemistry Research 2016, 25 (4) , 627-643.
    78. Francisco Lara-Ochoa, Leticia C. Sandoval-Minero, Georgina Espinosa-Pérez. A new synthesis of resveratrol. Tetrahedron Letters 2015, 56 (44) , 5977-5979.
    79. Fong‐Jiao Hong, Kam‐Weng Chong, Yun‐Yee Low, Noel F. Thomas, Toh‐Seok Kam. Transformations of Ferric Chloride‐Generated Stilbene Cation Radicals. The Effect of Aromatic Substitution and a Comparison with Anodic Oxidation. Chemistry – An Asian Journal 2015, 10 (10) , 2207-2220.
    80. Anastasia Schmidt, Alexander R. Nödling, Gerhard Hilt. Ein alternativer Mechanismus für die Cobalt-katalysierte Isomerisierung von terminalen Alkenen zu ( Z )-2-Alkenen. Angewandte Chemie 2015, 127 (3) , 814-818.
    81. Anastasia Schmidt, Alexander R. Nödling, Gerhard Hilt. An Alternative Mechanism for the Cobalt-Catalyzed Isomerization of Terminal Alkenes to ( Z )-2-Alkenes. Angewandte Chemie International Edition 2015, 54 (3) , 801-804.
    82. Xu-Heng Yang, Kai Li, Ren-Jie Song, Jin-Heng Li. Room-Temperature Palladium-Catalyzed Intramolecular Oxidative Aminocarbonylation of Vinylic C(sp 2 )-H Bonds with Amines and CO. European Journal of Organic Chemistry 2014, 2014 (3) , 616-623.
    83. Qiang Sun, Chi Zhang, Likun Wang, Zhiwen Li, Aiguo Hu, Qinggang Tan, Wei Xu. Surface-assisted cis–trans isomerization of an alkene molecule on Cu(110). Chem. Commun. 2014, 50 (14) , 1728-1730.
    84. Sebastián O. Simonetti, Enrique L. Larghi, Teodoro S. Kaufman. A facile and convenient sequential homobimetallic catalytic approach towards β-methylstyrenes. A one-pot Stille cross-coupling/isomerization strategy. Org. Biomol. Chem. 2014, 12 (22) , 3735-3743.
    85. Marie-Caroline A. Cordonnier, S. B. Jennifer Kan, Birgit Gockel, Shermin S. Goh, Edward A. Anderson. Carbopalladation of bromoene-alkynylsilanes: mechanistic insights and synthesis of fused-ring bicyclic silanes and phenols. Org. Chem. Front. 2014, 1 (6) , 661-673.
    86. Tse-Lok Ho, Mary Fieser, Louis Fieser, Rick Danheiser, William Roush, Janice Smith. Bis(Acetonitrile)Dichloropalladium(II). 2013, 39-40.
    87. Xing-Feng Bai, Li-Wen Xu, Long-Sheng Zheng, Jian-Xiong Jiang, Guo-Qiao Lai, Jun-Yan Shang. Aromatic-Amide-Derived Olefins as a Springboard: Isomerization-Initiated Palladium-Catalyzed Hydrogenation of Olefins and Reductive Decarbonylation of Acyl Chlorides with Hydrosilane. Chemistry - A European Journal 2012, 18 (26) , 8174-8179.
    88. Markus J. Spallek, Skrollan Stockinger, Richard Goddard, Oliver Trapp. Modular Palladium Bipyrazoles for the Isomerization of Allylbenzenes - Mechanistic Considerations and Insights into Catalyst Design and Activity, Role of Solvent, and Additive Effects. Advanced Synthesis & Catalysis 2012, 354 (8) , 1466-1480.
    89. Xingyi Zhu, Jun Liu, Tao Chen, Weike Su. Mechanically activated synthesis of ( E )‐stilbene derivatives by high‐speed ball milling. Applied Organometallic Chemistry 2012, 26 (3) , 145-147.
    90. Tamás Kálai, Erzsébet Borza, Csenge Antus, Balázs Radnai, Gergely Gulyás-Fekete, Andrea Fehér, Balázs Sümegi, Kálmán Hideg. Synthesis and study of new paramagnetic resveratrol analogues. Bioorganic & Medicinal Chemistry 2011, 19 (24) , 7311-7317.
    91. Erin E. Gray, Lake E. Rabenold, Brian C. Goess. E-selective isomerization of stilbenes and stilbenoids through reversible hydroboration. Tetrahedron Letters 2011, 52 (46) , 6177-6179.
    92. Emily H. P. Tan, Guy C. Lloyd-Jones, Jeremy N. Harvey, Alastair J. J. Lennox, Benjamin M. Mills. [(RCN)2PdCl2]-Catalyzed E/Z Isomerization of Alkenes: A Non-Hydride Binuclear Addition-Elimination Pathway. Angewandte Chemie 2011, 123 (41) , 9776-9780.
    93. Emily H. P. Tan, Guy C. Lloyd-Jones, Jeremy N. Harvey, Alastair J. J. Lennox, Benjamin M. Mills. [(RCN)2PdCl2]-Catalyzed E/Z Isomerization of Alkenes: A Non-Hydride Binuclear Addition-Elimination Pathway. Angewandte Chemie International Edition 2011, 50 (41) , 9602-9606.
    94. Jean Le Bras, Jacques Muzart. On the PdCl2-catalyzed synthesis of allylic azides and allylic sulfonamides from homoallylic alcohols. Tetrahedron Letters 2011, 52 (41) , 5217-5219.
    95. Tse-Lok Ho, Mary Fieser, Louis Fieser, Rick Danheiser, William Roush, Janice Smith. Bis(Acetonitrile)Dichloropalladium(II). 2011, 48-50.
    96. B. Sreedhar, V. Ravi, Deepthi Yada. PdCl2-catalyzed hydrosulfonamidation of homo allylic alcohols: an efficient synthesis of allylic sulfonamides. Tetrahedron Letters 2011, 52 (11) , 1208-1212.
    97. Elisabet Öberg, Xue-Li Geng, Marie-Pierre Santoni, Sascha Ott. C,C-Diacetylenic phosphaalkenes in palladium-catalyzed cross-coupling reactions. Organic & Biomolecular Chemistry 2011, 9 (18) , 6246.
    98. Tetsuya Satoh, Masahiro Miura. Oxidative Coupling of Aromatic Substrates with Alkynes and Alkenes under Rhodium Catalysis. Chemistry – A European Journal 2010, 16 (37) , 11212-11222.
    99. Jong-Wha Jung, Jaebong Jang, Seung-Yong Seo, Jae-Kyung Jung, Young-Ger Suh. Total synthesis of rodgersinol: a survey of the Cu(II)-mediated coupling of ortho-substituted phenols. Tetrahedron 2010, 66 (34) , 6826-6831.
    100. P. Surendra Reddy, V. Ravi, B. Sreedhar. Efficient synthesis of allylic azides and one-pot regioselective synthesis of 1,4-disubstituted 1,2,3-triazoles from homoallyl alcohols. Tetrahedron Letters 2010, 51 (31) , 4037-4041.
    Load all citations

    Pair your accounts.

    Export articles to Mendeley

    Get article recommendations from ACS based on references in your Mendeley library.

    Pair your accounts.

    Export articles to Mendeley

    Get article recommendations from ACS based on references in your Mendeley library.

    You’ve supercharged your research process with ACS and Mendeley!

    STEP 1:
    Click to create an ACS ID

    Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

    Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

    Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

    Your Mendeley pairing has expired. Please reconnect