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Convenient Preparation of trans-Arylalkenes via Palladium(II)-Catalyzed Isomerization of cis-Arylalkenes

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University Chemical Laboratory, Lensfield Road, Cambridge CB2 1EW, U.K. [email protected]
Cite this: J. Org. Chem. 2002, 67, 13, 4627–4629
Publication Date (Web):June 7, 2002
https://doi.org/10.1021/jo015880u
Copyright © 2002 American Chemical Society

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    Abstract

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    A convenient method for the isomerization of cis-arylalkenes to their trans isomers using a palladium(II) catalyst is described. The reaction conditions are mild and general across a range of arylalkenes. The synthesis of a trans-resveratrol derivative from a mixture of alkene isomers was also completed.

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